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Cellulose

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24-08-2018 | Original Paper

Polyacrylic acid supported TEMPO for selective catalytic oxidation of cellulose: recovered by its pH sensitivity

Authors: Shaojie Liu, Tingting Sun, Desheng Yang, Meng Cao, Huazhe Liang

Published in: Cellulose | Issue 10/2018

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Abstract

Water-soluble polyacrylic acid was prepared by solution polymerization, and then partially acylated by SOCl₂ to give a random copolymer of poly(acrylic acid-co-acryloyl chloride) (P(AA-co-AC)). Through the reaction of acyl chloride groups in P(AA-co-AC) with hydroxyl groups in 4-hydroxy-2,2,6,6-tetramethyl-piperidinooxy (4-OH-TEMPO), the water-soluble TEMPO immobilized copolymer of poly(acrylic acid-co-2,2,6,6-tetramethylpiperidinyloxy-4-yl-acrylate) (P(AA-co-TA)) with different TEMPO loadings were prepared and characterized by Fourier transform infrared spectroscopy and conductometric titration. P(AA-co-TA) was used as a recoverable catalyst instead of free TEMPO for selective catalytic oxidation of cellulose in water. The carboxyl content of oxidized cellulose with P(AA-co-TA) as catalyst was up to 60% of the free TEMPO level. Furthermore, P(AA-co-TA) was easy to recycle by its pH-sensitivity and the activity did not decrease after 4 cycles.

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next article Nano crystalline cellulose sulfuric acid (s-NCC): a novel green nanocatalyst for the synthesis of polyhydroxy pyrimidine-fused heterocyclic compounds (PPFHs)

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Title: Polyacrylic acid supported TEMPO for selective catalytic oxidation of cellulose: recovered by its pH sensitivity
Authors: Shaojie Liu
Tingting Sun
Desheng Yang
Meng Cao
Huazhe Liang
Publication date: 24-08-2018
Publisher: Springer Netherlands
Published in: Cellulose / Issue 10/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-2012-z

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