Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 14/2019

24-06-2019

Polyaniline nanoparticle coated graphene oxide composite nanoflakes for bifunctional multicolor electrochromic and supercapacitor applications

Authors: Sihang Zhang, Sheng Chen, Ya Cao, Feng Yang, Hongchao Peng, Bin Yan, Hao Jiang, Yingchun Gu, Ming Xiang

Published in: Journal of Materials Science: Materials in Electronics | Issue 14/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Graphene oxide (GO)/polyaniline (PANI) composite nanoflakes were fabricated by chemical oxidative polymerization of aniline onto GO nanoflakes. The electrochromic properties and the electrochemical capacitive behaviors of the GO/PANI composite nanoflake film were investigated. The GO/PANI nanocomposite film exhibits excellent electrochromic and supercapacitive performances. In comparison with neat PANI film, the GO/PANI composite nanoflake film shows larger optical modulation, faster response speed, larger coloration efficiency and better cycling stability. Moreover, an areal capacitance of (137 mF/cm2) is obtained for GO/PANI nanoflake film at a scanning rate of 5 mV/s, higher than that of neat PANI film (36 mF/cm2). The GO/PANI composite nanoflake film also shows enhanced electrochromic and supercapacitive durability. And the electrochromism also could be utilized as an indicator for the capacitance. The high-performance GO/PANI nanocomposite film shows promising features for multifunctional devices combining energy storage and electrochromism.
previous article Development of constructed nanoporous graphene-modified electrode for electrical detection of folic acid
next article Study of tungsten oxide effect on the performance of BaTiO3 ceramics

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
D. Yu, K. Goh, H. Wang, L. Wei, W. Jiang, Q. Zhang, L. Dai, Y. Chen, Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage. Nat. Nanotechnol. 9(7), 555–562 (2014)CrossRef
2.
P. Deshmukh, S. Patil, R. Bulakhe, S. Pusawale, J.-J. Shim, C. Lokhande, Chemical synthesis of PANI–TiO2 composite thin film for supercapacitor application. RSC Adv. 5(84), 68939–68946 (2015)CrossRef
3.
S.Y. Hong, J. Yoon, S.W. Jin, Y. Lim, S.-J. Lee, G. Zi, J.S. Ha, High-density, stretchable, all-solid-state microsupercapacitor arrays. ACS Nano 8(9), 8844–8855 (2014)CrossRef
4.
Z. Wang, M. Zhu, S. Gou, Z. Pang, Y. Wang, Y. Su, Y. Huang, Q. Weng, O.G. Schmidt, J. Xu, Pairing of luminescent switch with electrochromism for quasi-solid-state dual-function smart windows. ACS Appl. Mater. Interfaces 10(37), 31697–31703 (2018)CrossRef
5.
R. Lakshmanan, P. Raja, N. Shivaprakash, S. Sindhu, Fabrication of fast switching electrochromic window based on poly (3, 4-(2, 2-dimethylpropylenedioxy) thiophene) thin film. J. Mater. Sci. 27(6), 6035–6042 (2016)
6.
G.F. Cai, P. Darmawan, X. Cheng, P.S. Lee, Inkjet printed large area multifunctional smart windows. Adv. Energy Mater. 7(14), 1602598 (2017)CrossRef
7.
L. Shen, L. Du, S. Tan, Z. Zang, C. Zhao, W. Mai, Flexible electrochromic supercapacitor hybrid electrodes based on tungsten oxide films and silver nanowires. Chem. Commun. 52(37), 6296–6299 (2016)CrossRef
8.
W.Q. Wang, X.L. Wang, X.H. Xia, Z.J. Yao, Y. Zhong, J.P. Tu, Enhanced electrochromic and energy storage performance in mesoporous WO3 film and its application in a bi-functional smart window. Nanoscale 10(17), 8162–8169 (2018)CrossRef
9.
J. Chu, D. Lu, B. Wu, X. Wang, M. Gong, R. Zhang, S. Xiong, Synthesis and electrochromic properties of conducting polymers: polyaniline directly grown on fluorine-doped tin oxide substrate via hydrothermal techniques. Sol. Energy Mater. Sol. Cells 177, 70–74 (2018)CrossRef
10.
L.J. Ma, Y.X. Li, X.F. Yu, Q.B. Yang, C.H. Noh, Using room temperature ionic liquid to fabricate PEDOT/TiO2 nanocomposite electrode-based electrochromic devices with enhanced long-term stability. Sol. Energy Mater. Sol. Cells 92(10), 1253–1259 (2008)CrossRef
11.
S. Bhadra, D. Khastgir, N.K. Singha, J.H. Lee, Progress in preparation, processing and applications of polyaniline. Prog. Polym. Sci. 34(8), 783–810 (2009)CrossRef
12.
J.H. Kang, Y.J. Oh, S.M. Paek, S.J. Hwang, J.H. Choy, Electrochromic device of PEDOT-PANI hybrid system for fast response and high optical contrast. Sol. Energy Mater. Sol. Cells 93(12), 2040–2044 (2009)CrossRef
13.
S. Bhadra, N.K. Singha, D. Khastgir, Effect of aromatic substitution in aniline on the properties of polyaniline. Eur. Polym. J. 44(6), 1763–1770 (2008)CrossRef
14.
S.H. Zhang, R.F. Fu, S. Wang, Y.C. Gu, S. Chen, Novel nanocellulose/conducting polymer composite nanorod films with improved electrochromic performances. Mater. Lett. 202, 127–130 (2017)CrossRef
15.
H. Wei, X. Yan, S. Wu, Z. Luo, S. Wei, Z. Guo, Electropolymerized polyaniline stabilized tungsten oxide nanocomposite films: electrochromic behavior and electrochemical energy storage. J. Phys. Chem. C 116(47), 25052–25064 (2012)CrossRef
16.
D. Zhou, B. Che, X. Lu, Rapid one-pot electrodeposition of polyaniline/manganese dioxide hybrids: a facile approach to stable high-performance anodic electrochromic materials. J. Mater. Chem. C 5(7), 1758–1766 (2017)CrossRef
17.
S.A. Ansari, H. Fouad, S. Ansari, M.P. Sk, M.H. Cho, Mechanically exfoliated MoS2 sheet coupled with conductive polyaniline as a superior supercapacitor electrode material. J. Colloid Interface Sci. 504, 276–282 (2017)CrossRef
18.
M. Hirata, T. Gotou, S. Horiuchi, M. Fujiwara, M. Ohba, Thin-film particles of graphite oxide: high-yield synthesis and flexibility of the particles. Carbon 42(14), 2929–2937 (2004)
19.
Y.D. Shi, Y. Zhang, K. Tang, Y.B. Song, J.W. Cui, X. Shu, Y. Wang, J.Q. Liu, Y.C. Wu, In situ growth of PEDOT/graphene oxide nanostructures with enhanced electrochromic performance. RSC Adv. 8(25), 13679–13685 (2018)CrossRef
20.
Y. Liu, R. Deng, Z. Wang, H. Liu, Carboxyl-functionalized graphene oxide–polyaniline composite as a promising supercapacitor material. J. Mater. Chem. 22(27), 13619–13624 (2012)CrossRef
21.
W.S. Hummers Jr., R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339–1339 (1958)CrossRef
22.
D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L.B. Alemany, W. Lu, J.M. Tour, Improved synthesis of graphene oxide. ACS Nano 4(8), 4806–4814 (2010)CrossRef
23.
X. Chang, S. Sun, L. Dong, X. Hu, Y. Yin, Tungsten oxide nanowires grown on graphene oxide sheets as high-performance electrochromic material. Electrochim. Acta 129, 40–46 (2014)CrossRef
24.
G.L. Chen, S.M. Shau, T.Y. Juang, R.H. Lee, C.P. Chen, S.Y. Suen, R.J. Jeng, Single-layered graphene oxide nanosheet/polyaniline hybrids fabricated through direct molecular exfoliation. Langmuir 27(23), 14563–14569 (2011)CrossRef
25.
W.L. Zhang, B.J. Park, H.J. Choi, Colloidal graphene oxide/polyaniline nanocomposite and its electrorheology. Chem. Commun. 46(30), 5596–5598 (2010)CrossRef
26.
L.L. Zhang, S. Zhao, X.N. Tian, X. Zhao, Layered graphene oxide nanostructures with sandwiched conducting polymers as supercapacitor electrodes. Langmuir 26(22), 17624–17628 (2010)CrossRef
27.
X.M. Feng, R.M. Li, Y.W. Ma, R.F. Chen, N.E. Shi, Q.L. Fan, W. Huang, One-step electrochemical synthesis of graphene/polyaniline composite film and its applications. Adv. Funct. Mater. 21(15), 2989–2996 (2011)CrossRef
28.
M.V. Kulkarni, A.K. Viswanath, R. Marimuthu, T. Seth, Spectroscopic, transport, and morphological studies of polyaniline doped with inorganic acids. Polym. Eng. Sci. 44(9), 1676–1681 (2004)CrossRef
29.
D.Y. Liu, G.X. Sui, D. Bhattacharyya, Synthesis and characterisation of nanocellulose-based polyaniline conducting films. Comp. Sci. Tech. 99(4), 31–36 (2014)CrossRef
30.
N.D. Luong, J.T. Korhonen, A.J. Soininen, J. Ruokolainen, L.S. Johansson, J. Seppala, Processable polyaniline suspensions through in situ polymerization onto nanocellulose. Eur. Polym. J. 49(2), 335–344 (2013)CrossRef
31.
H. Wang, Q. Hao, X. Yang, L. Lu, X. Wang, Graphene oxide doped polyaniline for supercapacitors. Electrochem. Commun. 11(6), 1158–1161 (2009)CrossRef
32.
N.A. Kotov, I. Dékány, J.H. Fendler, Ultrathin graphite oxide–polyelectrolyte composites prepared by self-assembly: transition between conductive and non-conductive states. Adv. Mater. 8(8), 637–641 (1996)CrossRef
33.
D. Bandgar, S. Navale, S. Nalage, R. Mane, F. Stadler, D. Aswal, S. Gupta, V. Patil, Simple and low-temperature polyaniline-based flexible ammonia sensor: a step towards laboratory synthesis to economical device design. J. Mater. Chem. C 3(36), 9461–9468 (2015)CrossRef
34.
M.E. Jozefowicz, A.J. Epstein, J.P. Pouget, J.G. Masters, A. Ray, Y. Sun, X. Tang, A.G. Macdiarmid, X-ray structure of polyanilines. Synth. Met. 41(1–2), 723–726 (1991)CrossRef
35.
B. Yuan, C. Bao, L. Song, N. Hong, K.M. Liew, Y. Hu, Preparation of functionalized graphene oxide/polypropylene nanocomposite with significantly improved thermal stability and studies on the crystallization behavior and mechanical properties. Chem. Eng. J. 237, 411–420 (2014)CrossRef
36.
N.A. Kumar, H.-J. Choi, Y.R. Shin, D.W. Chang, L. Dai, J.-B. Baek, Polyaniline-grafted reduced graphene oxide for efficient electrochemical supercapacitors. ACS Nano 6(2), 1715–1723 (2012)CrossRef
37.
Y. Wei, G.W. Jang, K.F. Hsueh, E.M. Scherr, A.G. Macdiarmid, A.J. Epstein, Thermal transitions and mechanical properties of films of chemically prepared polyaniline. Polymer 33(2), 314–322 (1992)CrossRef
38.
W.K. Chen, C.W. Hu, C.Y. Hsu, K.C. Ho, A study on the electrochromic properties of polyaniline/silica composite films with an enhanced optical contrast. Electrochim. Acta 54(18), 4408–4415 (2009)CrossRef
39.
U. León-Silva, M. Nicho, H. Hu, R. Cruz-Silva, Effect of modified ITO substrate on electrochromic properties of polyaniline films. Sol. Energy Mater. Sol. Cells 91(15–16), 1444–1448 (2007)CrossRef
40.
D.E. Stilwell, S.M. Park, Electrochemistry of conductive polymers IV electrochemical studies on polyaniline degradation—Product identification and coulometric studies. J. Electrochem. Soc. 135(10), 2497–2502 (1988)CrossRef
41.
P.M. Beaujuge, J.R. Reynolds, Color control in π-conjugated organic polymers for use in electrochromic devices. Chem. Rev. 110(1), 268–320 (2010)CrossRef
42.
L. Zhao, L. Zhao, Y. Xu, T. Qiu, L. Zhi, G. Shi, Polyaniline electrochromic devices with transparent graphene electrodes. Electrochim. Acta 55(2), 491–497 (2010)CrossRef
43.
G. Cai, M. Cui, V. Kumar, P. Darmawan, J. Wang, X. Wang, A. Lee-Sie Eh, K. Qian, P.S. Lee, Ultra-large optical modulation of electrochromic porous WO3 film and the local monitoring of redox activity. Chem. Sci. 7(2), 1373–1382 (2016)CrossRef
44.
X. Xia, J. Tu, J. Zhang, X. Huang, X. Wang, W. Zhang, H. Huang, Multicolor and fast electrochromism of nanoporous NiO/poly(3,4-ethylenedioxythiophene) composite thin film. Electrochem. Commun. 11(3), 702–705 (2009)CrossRef
45.
Y. Chen, Z. Bi, X. Li, X. Xu, S. Zhang, X. Hu, High-coloration efficiency electrochromic device based on novel porous TiO2@prussian blue core–shell nanostructures. Electrochim. Acta 224, 534–540 (2017)CrossRef
46.
X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, A highly porous NiO/polyaniline composite film prepared by combining chemical bath deposition and electro-polymerization and its electrochromic performance. Nanotechnology 19(46), 465701 (2008)CrossRef
47.
B.G. Choi, M. Yang, W.H. Hong, J.W. Choi, Y.S. Huh, 3D macroporous graphene frameworks for supercapacitors with high energy and power densities. ACS Nano 6(5), 4020–4028 (2012)CrossRef
48.
K. Wang, H. Wu, Y. Meng, Y. Zhang, Z. Wei, Integrated energy storage and electrochromic function in one flexible device: an energy storage smart window. Energ. Environ. Sci. 5(8), 8384–8389 (2012)CrossRef
49.
Y.G. Wang, H.Q. Li, Y.Y. Xia, Ordered whiskerlike polyaniline grown on the surface of mesoporous carbon and its electrochemical capacitance performance. Adv. Mater. 18(19), 2619–2623 (2006)CrossRef
50.
Z.L. Wang, R. Guo, G.R. Li, H.L. Lu, Z.Q. Liu, F.M. Xiao, M. Zhang, Y.X. Tong, Polyaniline nanotube arrays as high-performance flexible electrodes for electrochemical energy storage devices. J. Mater. Chem. 22(6), 2401–2404 (2012)CrossRef
51.
H. Zhang, G. Cao, W. Wang, K. Yuan, B. Xu, W. Zhang, J. Cheng, Y. Yang, Influence of microstructure on the capacitive performance of polyaniline/carbon nanotube array composite electrodes. Electrochim. Acta 54(4), 1153–1159 (2009)CrossRef
52.
Q. Wu, Y. Xu, Z. Yao, A. Liu, G. Shi, Supercapacitors based on flexible graphene/polyaniline nanofiber composite films. ACS Nano 4(4), 1963–1970 (2010)CrossRef
53.
Q. Zhang, Y. Li, Y. Feng, W. Feng, Electropolymerization of graphene oxide/polyaniline composite for high-performance supercapacitor. Electrochim. Acta 90, 95–100 (2013)CrossRef
54.
F. Hu, J.L. Xu, S.H. Zhang, J. Jiang, B. Yan, Y.C. Gu, M.J. Jiang, S.J. Lin, S. Chen, Core/shell structured halloysite/polyaniline nanotubes with enhanced electrochromic properties. J. Mater. Chem. C 6(21), 5707–5715 (2018)CrossRef
Metadata
Title
Polyaniline nanoparticle coated graphene oxide composite nanoflakes for bifunctional multicolor electrochromic and supercapacitor applications
Authors
Sihang Zhang
Sheng Chen
Ya Cao
Feng Yang
Hongchao Peng
Bin Yan
Hao Jiang
Yingchun Gu
Ming Xiang
Publication date
24-06-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 14/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01717-y

Other articles of this Issue 14/2019

Journal of Materials Science: Materials in Electronics 14/2019 Go to the issue

OriginalPaper

Resistive switching modification by ultraviolet illumination in amorphous SrO-based resistive random access memory

OriginalPaper

The effect of planar atomic configuration in the enhancement of AC conductivity and dielectric characterization of bisbenzimidazo[2,1-a:2′,1′-a′]anthra[2,1,9-def:6,5,10-d′e′f′]diisoquinoline-10,21-dione7 (BI-diisoQ) thin film

OriginalPaper

In situ deposition of α-Co nanoparticles on three-dimensional nitrogen-doped porous graphene foams as microwave absorbers

Review

Perovskite solar cells: short lifetime and hysteresis behaviour of current–voltage characteristics

OriginalPaper

Synthesis and characterization of Cr2S3–Bi2O3 nanocomposites: photocatalytic, quenching, repeatability, and antibacterial performances

OriginalPaper

Microwave assisted synthesis of polythiophene–molybdenum sulfide counter electrode in dye sensitized solar cell