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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 1/2017

06-01-2017 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Preparation and electrochemical properties of Ba0.8La0.2FeO3-δ cathode for intermediate-temperature solid oxide fuel cells

Authors: Peng Liu, Hongze Zhu, Jiangrong Kong, Ning Wei, Can Wang, Xianfeng Yang, Qicheng Liu

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2017

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Abstract

Perovskite Ba0.8La0.2FeO3-δ was synthesized via a glycine–nitrate process as the cathode material for intermediate-temperature solid oxide fuel cells. Ultra-fine pure phase Ba0.8La0.2FeO3-δ powder was obtained after the self-propagating combustion of a complex xerogel precursor. The Ba0.8La0.2FeO3-δ cathode showed good compatibility and an enhanced phase interface with a samarium-doped ceria electrolyte. Electrochemical measurements showed that the Ba0.8La0.2FeO3-δ cathode achieved a low polarization resistance of 0.58 Ω cm2 at 800 °C in an air atmosphere. The porous nanostructure guaranteed the catalytic activity for the oxygen reduction reaction, even if the cathode material possessed a cobalt-free and low rare earth composition.

Graphical abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4300-0/MediaObjects/10971_2016_4300_Figa_HTML.gif
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Literature
1.
Shaikh SPS, Muchtar A, Somalu MR (2015) A review on the selection of anode materials for solid-oxide fuel cells. Renew Sust Energ Rev 51:1–8CrossRef
2.
Li P, Zhao YC, Yu BL, Li J, Li YD (2015) Improve electrical conductivity of reduced La2Ni0.9Fe0.1O4+δ as the anode of a solid oxide fuel cell by carbon deposition. Int J Hydrog Energy 40:9783–9789CrossRef
3.
Samat AA, Somalu MR, Muchtar A, Hassan OH, Osman N (2016) LSC cathode prepared by polymeric complexation method for proton-conducting SOFC application. J Sol Gel Technol 78:382–393CrossRef
4.
Simner SP, Bonnett JF, Canfield NL, Meinhardt KD, Shelton JP, Sprenkle VL, Stevenson JW (2003) Development of lanthanum ferrite SOFC cathodes. J Power Sources 113:1–10CrossRef
5.
Xiao J, Han D, Yu FY, Zhang L, Liu J, Zhan ZL, Zhang YJ, Dong P (2016) Characterization of symmetrical SrFe0.75Mo0.25O3-δ electrodes indirect carbon solid oxide fuel cells. J Alloy Compd 688:939–945CrossRef
6.
Yu XL, Long W, Jin FJ, He TM (2014) Cobalt-free perovskite cathode materials SrFe1-x Ti x O3-δ and performance optimization for intermediate-temperature solid oxide fuel cells. Electrochim Acta 123:426–434CrossRef
7.
Wang SL, Feng Y, Wang DS (2014) Electrochemical comparison of cobalt-free La0.5Sr0.5Fe0.9Mo0.1O3-δ based cathode materials for intermediate-temperature solid oxide fuel cells. Ceram Int 40:6359–6363CrossRef
8.
Zhou QJ, Xu L, Guo YJ, Jia D, Li Y, Wei WCJ (2012) La0.6Sr0.4Fe0.8Cu0.2O3-δ perovskite oxide as cathode for IT-SOFC. Int J Hydrog Energy 37:11963–11968CrossRef
9.
Zhu GY, Fang XH, Xia CR, Liu XQ (2005) Preparation and electrical properties of La0.4Sr0.6Ni0.2Fe0.8O3 using a glycine nitrate process. Ceram Int 31:115–119CrossRef
10.
Guo XZ, Zhang QL, Ding XG, Shen QH, Wu CC, Zhang LJ, Yang H (2016) Synthesis and application of several sol–gel-derived materials via sol–gel process combining with other technologies: a review. J Sol Gel Technol 79:328–358CrossRef
11.
Roldán-Carmona C, Gratia P, Zimmermann I, Grancini G, Gao P, Graetzel M, Nazeeruddin MK (2015) High efficiency methylammonium lead triiodide perovskite solar cells: the relevance of non-stoichiometric precursors. Energy Environ Sci 8:3550–3556CrossRef
12.
Chen DJ, Chen C, Dong FF, Shao ZP, Ciucci F (2014) Cobalt-free polycrystalline Ba0.95La0.05FeO3-δ thin films as cathodes for intermediate-temperature solid oxide fuel cells. J Power Sources 250:188–195CrossRef
13.
Mahato N, Banerjee A, Gupta A, Omar S, Balani K (2015) Progress in material selection for solid oxide fuel cell technology: a review. Prog Mater Sci 72:141–337CrossRef
14.
Long T, Cui XY, Li L, Li SM, Xu LY (2015) Synthesis of hierarchically porous ZrO2 monolith by a template method. Mater Manuf Process 30:571–575CrossRef
15.
Oh EO, Whang CM, Lee YR, Park SY, Prasad DH, Yoon KJ, Son JW, Lee JH, Lee HW (2012) Extremely thin bilayer electrolyte for solid oxide fuel cells (SOFCs) fabricated by chemical solution deposition (CSD). Adv Mater 24:3373–3377CrossRef
16.
Karpinsky DV, Troyanchuk IO, Bushinsky MV, Gavrilov SA, Silibin MV, Franz A (2016) Crystal structure and magnetic properties of Bi1−x Ca x Fe1−x Mn(Ti) x O3 ceramics across the phase boundary. J Mater Sci 51:10506–10514CrossRef
17.
Mori T, Buchanan R, Ou DR, Ye F, Kobayashi T, Kim JD, Zou J, Drennan J (2008) Design of nanostructured ceria-based solid electrolytes for development of IT-SOFC. J Solid State Electrochem 12:841–849CrossRef
18.
Pereira FJ, Díez MT, Aller AJ (2015) Effect of temperature on the crystallinity, size and fluorescent properties of zirconia-based nanoparticles. Mater Chem Phys 152:135–146CrossRef
19.
Lee KT, Manthiram A (2006) Comparison of Ln0.6Sr0.4CoO3-δ (Ln=La, Pr, Nd, Sm, and Gd) as cathode materials for intermediate temperature solid oxide fuel cells. J Electrochem Soc 153:A794–A798CrossRef
20.
Navarrete L, Solís C, Serra JM (2015) Boosting the oxygen reduction reaction mechanisms in IT-SOFC cathodes by catalytic functionalization. J Mater Chem A 3:16440–16444CrossRef
21.
Zhou W, Sunarso J, Chen ZG, Ge L, Motuzas J, Zou J, Wang GX, Julbe A, Zhu ZH (2011) Novel B-site ordered double perovskite Ba2Bi0.1Sc0.2Co1.7O6-x for highly efficient oxygen reduction reaction. Energy Environ Sci 4:872–875CrossRef
22.
Park K, Kim J, Bae J (2015) Electrochemical analysis of Pr0.3Sr0.7Co x B(1−x)O3-δ (B = Fe, Mn; x = 0, 0.3, 0.5, 0.7, and 1) as cathode materials for intermediate temperature SOFCs. Solid State Ionics 272:45–52CrossRef
23.
Wang J, Lam KY, Saccoccio M, Gao Y, Chen DJ, Ciucci F (2016) Ca and In co-doped BaFeO3-δ as a cobalt-free cathode material for intermediate-temperature solid oxide fuel cells. J Power Sources 324:224–232CrossRef
24.
Chen YH, Gu QW, Tian D, Ding YZ, Lu XY, Yu WL, Isimjan TT, Lin B (2014) (La, Pr)0.8Sr0.2FeO3-δ –Sm0.2Ce0.8O2-δ composite cathode for proton-conducting solid oxide fuel cells. Int J Hydrog Energy 39:13665–13670CrossRef
Metadata
Title
Preparation and electrochemical properties of Ba0.8La0.2FeO3-δ cathode for intermediate-temperature solid oxide fuel cells
Authors
Peng Liu
Hongze Zhu
Jiangrong Kong
Ning Wei
Can Wang
Xianfeng Yang
Qicheng Liu
Publication date
06-01-2017
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 1/2017
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4300-0

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