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Journal of Coatings Technology and Research
Published in: Journal of Coatings Technology and Research 3/2019

29-10-2018

Preparation of amphiphobically modified poly(vinyl alcohol) film by fluoroalkyl end-capped vinyltrimethoxysilane oligomer

Authors: Yuta Aomi, Hideo Sawada

Published in: Journal of Coatings Technology and Research | Issue 3/2019

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Abstract

Hydrophilic poly(vinyl alcohol) (PVA) was chemically modified by using fluoroalkyl end-capped vinyltrimethoxysilane oligomer [RF-(VM)n-RF] to lead the PVA/RF-(VM)n-RF composite films. The PVA/RF-(VM)n-RF composite film obtained under non-catalytic conditions was found to provide the water-soluble property; however, the acidic conditions enabled the composite film to afford no solubility toward water, giving an amphiphobic property on both the surface and reverse sides just after the deposit of an oil or water droplet. RF-(VM)n-RF oligomer was also applied to the fabrication of the PVA/RF-(VM)n-RF/B(OH)3 composite film by using the RF-(VM)n-RF/B(OH)3 nanocomposites, which were prepared by the composite reaction of RF-(VM)n-RF oligomer with boric acid. It was demonstrated that the PVA/RF-(VM)n-RF/B(OH)3 composite film obtained by the interaction of the corresponding nanocomposites with PVA under acidic conditions can afford the perfect water-resistance ability even after immersion of this film into water for 30 min to give the amphiphobic property on both the surface and reverse sides, although the corresponding PVA/RF-(VM)n-RF composite film and the pristine PVA film provided the swelling behavior toward water, respectively. Thermal gravimetric analyses (TGA) and differential thermal analyses (DTA) measurements showed that the PVA/RF-(VM)n-RF/B(OH)3 composite film can give a higher thermal stability than that of the RF-(VM)n-RF/PVA composite film and the pristine PVA film.

Graphical abstract

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Literature
1.
Cao, M, Wang, C, Xia, R, Chen, P, Miao, J, Yang, B, Qian, J, Tang, Y, “Preparation and performance of the modified high-strength/high-modulus polyvinyl alcohol fiber/polyurethane grouting materials.” Constr. Build. Mater., 168 482–489 (2018)CrossRef
2.
Shao, C, Kim, H-Y, Gong, J, Ding, B, Lee, D-R, Park, S-J, “Fiber mats of poly(vinyl alcohol)/silica composite via electrospinning.” Mater. Lett., 57 1579–1584 (2003)CrossRef
3.
Nishimura, M, Higa, M, “Ion transport properties of anion exchange membranes prepared from poly(vinyl alcohol) and poly(allylamine).” Bull. Soc. Sea Water Sci. Jpn., 63 381–386 (2009)
4.
Qua, EH, Hornsby, PR, Sharma, HSS, Lyons, G, McCall, RD, “Preparation and characterization of poly(vinyl alcohol) nanocomposites made from cellulose nanofibers.” J. Appl. Polym. Sci., 113 2238–2247 (2009)CrossRef
5.
Moreno, G, de Paz, MV, Valenda, C, Franco, JM, “Synthesis and characterization of isocyanate—functionalized PVA—based polymers with applications as new additives in lubricant formulations.” J. Appl. Polym. Sci., 125 3267–3299 (2012)CrossRef
6.
Zhang, W, Chen, M, Diao, G, “Electrospinning β-cyclodextrin/poly(vinyl alcohol) nanofibrous membrane for molecular capture.” Carbohydr. Polym., 86 1410–1416 (2011)CrossRef
7.
Harun-or-Rashid, MD, Saifur Rahaman, MD, Kabir, SE, Khan, MA, “Effect of hydrochloric acid on the properties of biodegradable packaging materials of carboxymethylcellulose/poly(vinyl alcohol) blends.” J. Appl. Polym. Sci. (2016). https://​doi.​org/​10.​1002/​APP.​42870
8.
Kobayashi, M, Toguchida, J, Oka, M, “Preliminary study of polyvinyl alcohol-hydrogel (PVA-H) artificial meniscus.” Biomaterials, 24 639–647 (2003)CrossRef
9.
Uragami, T, Okazaki, K, Matsugi, H, Miyata, T, “Structure and permeation characteristics of an aqueous ethanol solution of organic−inorganic hybrid membranes composed of poly(vinyl alcohol) and tetraethoxysilane.” Macromolecules, 35 9156–9163 (2002)CrossRef
10.
Zhang, R, Wan, W, Qiu, L, Wang, Y, Zhou, Y, “Preparation of hydrophobic polyvinyl alcohol aerogel via the surface modification of boron nitride for environmental remediation.” Appl. Surf. Sci., 419 342–347 (2017)CrossRef
11.
Wang, Q, Dong, Z, Yan, X, Chang, Y, Ren, L, Zhou, J, “Biomimetic hydrophobic surfaces with low or high adhesion based on poly(vinyl alcohol) and SiO2 nanoparticles.” J. Bionic Eng., 14 476–485 (2017)CrossRef
12.
Bandyopadhyay, A, De Sarkar, M, Bhowmick, AK, “Poly(vinyl alcohol)/silica hybrid nanocomposites by sol–gel technique: synthesis and properties.” J. Mater. Sci., 40 5233–5241 (2005)CrossRef
13.
Yoon, DY, Kim, J-C, “Hydrophobically modified poly(vinyl alcohol) and boric acid-containing monoolein cubic phase as a glucose-responsive vehicle.” Colloids Surf. A Physicochem. Eng. Aspects, 506 678–685 (2016)CrossRef
14.
Lim, M, Kwon, H, Kim, D, Seo, J, Han, H, Khan, SB, “Highly-enhanced water resistant and oxygen barrier properties of cross-linked poly(vinyl alcohol) hybrid films for packaging applications.” Prog. Org. Coat., 85 68–75 (2015)CrossRef
15.
Wang, J, Wang, X, Xu, C, Zhang, M, Shang, X, “Preparation of graphene/poly(vinyl alcohol) nanocomposites with enhanced mechanical properties and water resistance.” Polym. Int., 60 816–822 (2011)CrossRef
16.
Xu, S, Yu, W, Yao, X, Zhang, Q, Fu, Q, “Nanocellulose-assisted dispersion of graphene to fabricate poly(vinyl alcohol)/graphene nanocomposite for humidity sensing.” Compos. Sci. Technol., 131 67–76 (2016)CrossRef
17.
Guzman-Puyol, S, Ceseracciu, L, Heredia-Guerrero, JA, Anyfantis, GC, Cingolani, R, Athanassiou, A, Bayer, IS, “Effect of trifluoroacetic acid on the properties of polyvinyl alcohol and polyvinyl alcohol–cellulose composites.” Chem. Eng. J., 277 242–251 (2015)CrossRef
18.
Ogino, K, Ohtsuka, T, Ishikawa, N, “Surface improvement of poly(vinyl alcohol) film by perfluorocarbonyl chlorides.” Kobunshi Ronbunshu, 43 377–383 (1983)CrossRef
19.
Nishino, T, Nakahara, S, Nakamae, K, “Poly(vinyl alcohol) with low surface free energy by fluorinated agent.” J. Adhes. Soc. Jpn., 35 138–143 (1999)
20.
Nishino, T, Meguro, M, Nakamae, K, “Poly(vinyl alcohol) with low surface free energy by fluorination.” Int. J. Adhes. Adhes., 19 399–403 (1999)CrossRef
21.
Ameduri, B, Sawada, H. (Eds.), Fluorinated Polymers: Volume 1, “Synthesis, Properties, Processing and Simulation.” Cambridge, RSC (2016)
22.
Ameduri, B, Sawada, H (Eds.), Fluorinated Polymers: Volume 2, “Applications,” Cambridge, RSC (2016)
23.
24.
Sawada, H, “Synthesis of self-assembled fluoroalkyl end-capped oligomeric aggregates—Applications of these aggregates to fluorinated oligomeric nanocomposites.” Prog. Polym. Sci., 32 509–533 (2007)CrossRef
25.
Sawada, H, “Preparation and applications of novel fluoroalkyl end-capped oligomeric nanocomposites.” Polym. Chem., 3 46–65 (2012)CrossRef
26.
Oikawa, Y, Saito, T, Yamada, S, Sugiya, M, Sawada, H, “Preparation and surface property of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/talc composite-encapsulated organic compounds: Application for the separation of oil and water.” ACS Appl. Mater. Interfaces, 7 13782–13793 (2015)CrossRef
27.
Suzuki, J, Takegahara, Y, Oikawa, Y, Chiba, M, Yamada, S, Sugiya, M, Sawada, H, “Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/poly(tetrafluoroethylene) nanocomposites possessing a superoleophilic/superhydrophobic characteristic: Application to the separation of oil and water.” J. Sol-Gel Sci. Technol., 81 611–622 (2017)CrossRef
28.
Sawada, H, Suto, Y, Saito, T, Oikawa, Y, Yamashita, K, Yamada, S, Sugiya, M, Suzuki, J, “Preparation of RF–(VM–SiO2)n–RF/AM-cellu nanocomposites, and use thereof for the modification of glass and filter paper surfaces: creation of a glass thermoresponsive switching behavior and an efficient separation paper membrane.” Polymers, 9 (1–14) (2017). https://​doi.​org/​10.​3390/​polym9030092
29.
Katayama, S, Fujii, S, Saito, T, Yamazaki, S, Sawada, H, “Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica nanocomposites containing gluconamide units possessing highly oleophobic/superhydrophobic, highly oleophobic/superhydrophilic, and superoleophilic/superhydrophobic characteristics on the modified surfaces.” Polymers, 9 292 (1–17) (2017). https://​doi.​org/​10.​3390/​polym9070292.
30.
Sawada, H, Suzuki, T, Takashima, H, Takishita, K, “Preparation and properties of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanoparticles—A new approach to facile creation of a completely superhydrophobic coating surface with these nanoparticles.” Colloid Polym. Sci., 286 1569–1574 (2008)CrossRef
31.
Sawada, H, Nakayama, M “Synthesis of fluorine-containing organosilicon oligomers.” J. Chem. Soc., Chem. Commun. 677–678 (1991)
32.
Aomi, Y, Nishida, M, Sawada, H, “Preparation and thermal stability of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/boric acid nanocomposites-encapsulated a variety of low molecular weight organic compounds.” J. Polym. Sci. Part A Polym. Chem., 54 3835–3845 (2016)CrossRef
33.
Aomi, Y, Oishi, Y, Shibasaki, Y, Aikawa, Y, Jikei, M, Nishida, M, Yamazaki, S, Sawada, H, “Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/boric acid/poly(N-methyl benzamide)-b-poly(propylene oxide) block copolymer nanocomposites—No weight loss behavior of the block copolymer in the nanocomposites even after calcination at 800°C.” J. Sol-Gel Sci. Technol., 85 318–329 (2018)CrossRef
34.
Zhang, QG, Liu, QL, Zhu, AM, Xiong, Y, Zhang, XH, “Characterization and permeation performance of novel organic−inorganic hybrid membranes of poly(vinyl alcohol)/1,2-bis(triethoxysilyl)ethane”, J. Phys. Chem. B, 112, 16559–16565 (2008)
35.
Mondal, S, Banthia, AK, “Low-temperature synthetic route for boron carbide.” J. Eur. Ceramic Soc., 25 287–291 (2005)CrossRef
36.
Zhang, QG, Liu, QL, Jiang, ZY, Chen, Y, “Anti-trade-off in dehydration of ethanol by novel PVA/APTEOS hybrid membranes.” J. Membr. Sci., 287 237–245 (2007)CrossRef
37.
Zhang, QG, Liu, QL, Meng, XJ, Broadwell, I, “Structure and pervaporation performance of novel quaternized poly (vinyl alcohol)/γ-aminopropyltriethoxysilane hybrid membranes.” J. Appl. Polym. Sci., 118 1121–1126 (2010)
38.
Hu, WW, Zhang, XH, Zhang, QG, Liu, QL, Zhu, AM, “Pervaporation dehydration of water/ethanol/ethyl acetate mixtures using poly(vinyl alcohol)—Silica hybrid membranes.” J. Appl. Polym. Sci., 126 778–787 (2012)CrossRef
39.
Lim, M, Kim, D, Seo, J, Han, H, “Highly-enhanced water resistant and oxygen barrier properties of cross-linked poly(vinyl alcohol) hybrid films for packaging applications.” Macromol. Res., 22 1096–1103 (2014)CrossRef
Metadata
Title
Preparation of amphiphobically modified poly(vinyl alcohol) film by fluoroalkyl end-capped vinyltrimethoxysilane oligomer
Authors
Yuta Aomi
Hideo Sawada
Publication date
29-10-2018
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 3/2019
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-018-0148-2

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