Top

Cellulose

Published in:

03-01-2020 | Original Research

Preparation of cellulose nanofibrils from okara by high pressure homogenization method using deep eutectic solvents

Authors: Peiyi Li, Yumeng Wang, Qingqing Hou, Hezhen Liu, Haozhe Lei, Boxing Jian, Xinping Li

Published in: Cellulose | Issue 5/2020

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The interest in the application of deep eutectic solvents (DES) as a green solvent has increased rapidly. The application of DES in agro-industrial okara treatment can be developed into industrialization. In order to simplify the degreasing, deproteinization and cellulose extraction steps in the process of pretreating okara cellulose, a new approach to cellulose extraction from okara via one-pot DES treatment is established. Three different complexing agents, choline salts in oxalic acid, in glycerol and in urea are studied in this work. The structure and properties of cellulose nanofibers (CNFs) prepared by high pressure homogenization following pretreatment of okara with anionic systhesized DES are investigated. The effects of different systems on the degree of microfibrillation of okara are analyzed using techniques such as SEM, FTIR, TD and DTG. The results indicate that by pretreating okara with choline chloride–oxalic acid type solvent, CNFs with average diameter of 27 nm are obtained using high pressure homogenization.

previous article Enhanced production of bacterial cellulose by Komactobacter intermedius using statistical modeling

next article Geometric structure modification in cellulose acetate nanofibers and its impact on liquid resistance/repellency

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Abbott AP, Capper G, Davies DL, Munro HL, Rasheed RK, Tambyrajah V (2001) Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains. Chem Commun. https://doi.org/10.1039/b106357j CrossRef

Barth A (2007) Infrared spectroscopy of proteins. Biochim Biophys Acta (BBA) Bioenerg 1767:1073–1101. https://doi.org/10.1016/j.bbabio.2007.06.004 CrossRef

Faradilla RF, Lee G, Arns J-Y, Roberts J, Martens P, Stenzel MH, Arcot J (2017) Characteristics of a free-standing film from banana pseudostem nanocellulose generated from TEMPO-mediated oxidation. Carbohydr Polym 174:1156–1163. https://doi.org/10.1016/j.carbpol.2017.07.025 CrossRefPubMed

Galvis-Sánchez AC, Castro MCR, Biernacki K, Gonçalves MP, Souza HK (2018) Natural deep eutectic solvents as green plasticizers for chitosan thermoplastic production with controlled/desired mechanical and barrier properties. Food Hydrocolloids 82:478–489. https://doi.org/10.1016/j.foodhyd.2018.04.026 CrossRef

Huang Y, Feng F, Chen Z-G, Wu T, Wang Z-H (2018) Green and efficient removal of cadmium from rice flour using natural deep eutectic solvents. Food Chem 244:260–265. https://doi.org/10.1016/j.foodchem.2017.10.060 CrossRefPubMed

Kaushik A, Singh M (2011) Isolation and characterization of cellulose nanofibrils from wheat straw using steam explosion coupled with high shear homogenization. Carbohydr Res 346:76–85. https://doi.org/10.1016/j.carres.2010.10.020 CrossRefPubMed

Khawas P, Deka SC (2016) Isolation and characterization of cellulose nanofibers from culinary banana peel using high-intensity ultrasonication combined with chemical treatment. Carbohydr Polym 137:608–616. https://doi.org/10.1016/j.carbpol.2015.11.020 CrossRefPubMed

Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466. https://doi.org/10.1007/s10570-014-0478-x CrossRef

Laitinen O, Suopajärvi T, Österberg M, Liimatainen H (2017) Hydrophobic, superabsorbing aerogels from choline chloride-based deep eutectic solvent pretreated and silylated cellulose nanofibrils for selective oil removal. ACS Appl Mater Interfaces 9:25029–25037. https://doi.org/10.1021/acsami.7b06304 CrossRefPubMed

Li P, Sirviö JA, Haapala A, Liimatainen H (2017) Cellulose nanofibrils from nonderivatizing urea-based deep eutectic solvent pretreatments. ACS Appl Mater Interfaces 9:2846–2855. https://doi.org/10.1021/acsami.6b13625 CrossRefPubMed

Li P, Wang Y, Hou Q, Li X (2018a) Isolation and characterization of microfibrillated cellulose from agro-industrial soybean residue (okara). BioResources 13:7944–7956. https://doi.org/10.15376/biores.13.4.7944-7956 CrossRef

Li P, Wang Y, Hou Q, Liu H, Liang C, Li X (2018b) Effect of pretreatment on the structure and properties of nanofibrillated cellulose from soybean residues. BioResources 14:554–560. https://doi.org/10.15376/biores.14.1.554-560 CrossRef

Lü H, Wang S, Deng C, Ren W, Guo B (2014) Oxidative desulfurization of model diesel via dual activation by a protic ionic liquid. J Hazard Mater 279:220–225. https://doi.org/10.1016/j.jhazmat.2014.07.005 CrossRefPubMed

Martelli-Tosi M, Masson MM, Silva NC, Esposto BS, Barros TT, Assis OB, Tapia-Blácido DR (2018) Soybean straw nanocellulose produced by enzymatic or acid treatment as a reinforcing filler in soy protein isolate films. Carbohydr Polym 198:61–68. https://doi.org/10.1016/j.carbpol.2018.06.053 CrossRefPubMed

Orfão JJ, Antunes FJ, Figueiredo JL (1999) Pyrolysis kinetics of lignocellulosic materials—three independent reactions model. Fuel 78:349–358. https://doi.org/10.1016/S0016-2361(98)00156-2 CrossRef

Sirviö JA, Visanko M, Liimatainen H (2015) Deep eutectic solvent system based on choline chloride–urea as a pre-treatment for nanofibrillation of wood cellulose. Green Chem 17:3401–3406. https://doi.org/10.1039/c5gc00398a CrossRef

Sirviö JA, Visanko M, Liimatainen H (2016) Acidic deep eutectic solvents as hydrolytic media for cellulose nanocrystal production. Biomacromolecules 17:3025–3032. https://doi.org/10.1021/acs.biomac.6b00910 CrossRefPubMed

Sundari MT, Ramesh A (2012) Isolation and characterization of cellulose nanofibers from the aquatic weed water hyacinth—Eichhornia crassipes. Carbohydr Polym 87:1701–1705. https://doi.org/10.1016/j.carbpol.2011.09.076 CrossRef

Suopajärvi T, Sirviö JA, Liimatainen H (2017) Nanofibrillation of deep eutectic solvent-treated paper and board cellulose pulps. Carbohydr Polym 169:167–175. https://doi.org/10.1016/j.carbpol.2017.04.009 CrossRefPubMed

Yang H, Yan R, Chin T, Liang DT, Chen H, Zheng C (2004) Thermogravimetric analysis—Fourier transform infrared analysis of palm oil waste pyrolysis. Energy Fuels 18:1814–1821. https://doi.org/10.1021/ef030193m CrossRef

Zhang Y, Lu X, Feng X, Shi Y, Ji X (2013) Properties and applications of choline-based deep eutectic solvents. Huaxue jinzhan 25:881–892. https://doi.org/10.7536/PC121044 CrossRef

Zhao Z, Chen X, Ali MF, Abdeltawab AA, Yakout SM, Yu G (2018) Pretreatment of wheat straw using basic ethanolamine-based deep eutectic solvents for improving enzymatic hydrolysis. Bioresour Technol 263:325–333. https://doi.org/10.1016/j.biortech.2018.05.016 CrossRefPubMed

Title: Preparation of cellulose nanofibrils from okara by high pressure homogenization method using deep eutectic solvents
Authors: Peiyi Li
Yumeng Wang
Qingqing Hou
Hezhen Liu
Haozhe Lei
Boxing Jian
Xinping Li
Publication date: 03-01-2020
Publisher: Springer Netherlands
Published in: Cellulose / Issue 5/2020
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02929-5

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 5/2020

Geometric structure modification in cellulose acetate nanofibers and its impact on liquid resistance/repellency

Electrocatalytic oxygen reduction over Co@Co3O4/N-doped porous carbon derived from pyrolysis of ZIF-8/67 on cellulose nanofibers

Energy grass/polylactic acid composites and pretreatments for additive manufacturing

Layer-by-layer assembly of PDMS-coated nickel ferrite/multiwalled carbon nanotubes/cotton fabrics for robust and durable electromagnetic interference shielding

Synthesis of polyamide-6@cellulose microfilms grafted with N-vinylcaprolactam using gamma-rays and loading of antimicrobial drugs

Low consistency refined ligno-cellulose microfibre: an MFC alternative for high bulk, tear and tensile mechanical pulp papers