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26-09-2021 | Original Research

Preparation of cotton fibers modified with aromatic heterocyclic compounds and study of Cr(VI) adsorption performance

Authors: Zhiyu Huang, Peng Wu, Yankun Yin, Xiang Zhou, Lu Fu, Luoxin Wang, Shaohua Chen, Xu Tang

Published in: Cellulose | Issue 17/2021

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Abstract

In order to prepare low-cost, biodegradable and processable adsorbent materials for adsorption of heavy metal ion, two kinds of novel modified cottons (C-4-APD and C-2-APZ) were obtained by introducing 4-aminopyridin and 2-aminopyrazine into the surface of degreasing cotton, respectively, and used for the removal of Cr(VI) ions from aqueous solution. The two modified cottons were characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS), which confirmed the amino groups, pyridine groups and pyrazine groups grafted onto the surface of modified cottons. The maximum adsorption capacities of C-4-APD and C-2-APZ were 89.66 mg/g and 54.92 mg/g, respectively, at the optimum pH of 2 and an initial concentration of 300 mg/g. Kinetic, isotherm and thermodynamic studies were carried out to investigate the adsorption behavior of the modified cottons on Cr(VI) ions. The results showed that the adsorption of Cr(VI) ions by modified cottons followed a pseudo-second-order kinetic model, the equilibrium data were in good agreement with the Langmuir isotherm model, and the thermodynamic analysis indicates that the adsorption proceeds spontaneously. The recovery and reuse of modified cotton were achieved by washing with 2 wt% thiourea-hydrochloric acid solution (0.5 mol/L concentration of HCl), and the adsorption capacities of C-4-APD and C-2-APZ were maintained above 90% and 85%, respectively, after six cycles.

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Bao S, Liu H, Liu Y, Yang W, Wang Y, Yu Y, Sun Y, Li K (2020) Amino-functionalized graphene oxide-supported networked Pd-Ag nanowires as highly efficient catalyst for reducing Cr(VI) in industrial effluent by formic acid. Chemosphere 257:127245. https://doi.org/10.1016/j.chemosphere.2020.127245CrossRefPubMed

Bayramoglu G, Akbulut A, Arica MY (2016) Aminopyridine modified Spirulina platensis biomass for chromium(VI) adsorption in aqueous solution. Water Sci Technol 74:914–926. https://doi.org/10.2166/wst.2016.281CrossRefPubMed

Bayramoglu G, Arica MY (2011) Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: its adsorption propensity to Cr(VI). J Hazard Mater 187:213–221. https://doi.org/10.1016/j.jhazmat.2011.01.022CrossRefPubMed

Bayramoglu G, Yakup Arica M, Bektas S (2007) Removal of Cd(II), Hg(II), and Pb(II) ions from aqueous solution using p(HEMA/chitosan) membranes. J Appl Polym Sci 106:169–177. https://doi.org/10.1002/app.26704CrossRef

Bayramoglu G, Yakuparica M (2008) Adsorption of Cr(VI) onto PEI immobilized acrylate-based magnetic beads: Isotherms, kinetics and thermodynamics study. Chem Eng J 139:20–28. https://doi.org/10.1016/j.cej.2007.07.068CrossRef

Eliodorio KP, Andolfatto VS, Martins MRG, De Sá BP, Umeki ER, De Araújo M-G (2017) Treatment of chromium effluent by adsorption on chitosan activated with ionic liquids. Cellulose 24:2559–2570. https://doi.org/10.1007/s10570-017-1264-3CrossRef

Fenti A, Chianese S, Iovino P, Musmarra D, Salvestrini S (2020) Cr(VI) sorption from aqueous solution: a review. Appl Sci 10:6477. https://doi.org/10.3390/app10186477CrossRef

Geng T, Ma L, Chen G, Zhang C, Zhang W, Niu Q (2020) Fluorescent conjugated microporous polymers containing pyrazine moieties for adsorbing and fluorescent sensing of iodine. Environ Sci Pollut Res Int 27:20235–20245. https://doi.org/10.1007/s11356-019-06534-8CrossRefPubMed

Ghiaci M, Kia R, Abbaspur A, Seyedeyn-Azad F (2004) Adsorption of chromate by surfactant-modified zeolites and MCM-41 molecular sieve. Sep Purif Technol 40:285–295. https://doi.org/10.1016/j.seppur.2004.03.009CrossRef

Hu Y, Zhang J, Yu C, Li Q, Dong F, Wang G, Guo Z (2014) Synthesis, characterization, and antioxidant properties of novel inulin derivatives with amino-pyridine group. Int J Biol Macromol 70:44–49. https://doi.org/10.1016/j.ijbiomac.2014.06.024CrossRefPubMed

Kimbrough DE, Cohen Y, Winer AM, Creelman L, Mabuni C (1999) A critical assessment of chromium in the environment. Crit Rev Environ Sci Technol 29:1–46. https://doi.org/10.1080/10643389991259164CrossRef

Kooshki F, Tutunchi H, Vajdi M, Karimi A, Niazkar HR, Shoorei H, Pourghassem Gargari B (2021) A Comprehensive insight into the effect of chromium supplementation on oxidative stress indices in diabetes mellitus: a systematic review. Clin Exp Pharmacol Physiol 48:291–309. https://doi.org/10.1111/1440-1681.13462CrossRefPubMed

Li LL, Feng XQ, Han RP, Zang SQ, Yang G (2017) Cr(VI) removal via anion exchange on a silver-triazolate MOF. J Hazard Mater 321:622–628. https://doi.org/10.1016/j.jhazmat.2016.09.029CrossRefPubMed

Li Y, Zhu H, Zhang C, Cheng M, He H (2018) PEI-grafted magnetic cellulose for Cr(VI) removal from aqueous solution. Cellulose 25:4757–4769. https://doi.org/10.1007/s10570-018-1868-2CrossRef

Liang X, Liang B, Wei J, Zhong S, Zhang R, Yin Y, Zhang Y, Hu H, Huang Z (2020) A cellulose-based adsorbent with pendant groups of quaternary ammonium and amino for enhanced capture of aqueous Cr(VI). Int J Biol Macromol 148:802–810. https://doi.org/10.1016/j.ijbiomac.2020.01.184CrossRefPubMed

Long B, Ye J, Ye Z, He J, Luo Y, Zhao Y, Shi J (2020) Cr(VI) removal by Penicillium oxalicum SL2: reduction with acidic metabolites and form transformation in the mycelium. Chemosphere 253:126731. https://doi.org/10.1016/j.chemosphere.2020.126731CrossRefPubMed

Lu H, Wu F, Yang Y, Li S, Hua Y, Zhu L (2020) Hole transport materials based on a twisted molecular structure with a single aromatic heterocyclic core to boost the performance of conventional perovskite solar cells. J Mater Chem C 8:13415–13421. https://doi.org/10.1039/d0tc03404eCrossRef

Manzoor Q, Sajid A, Hussain T, Iqbal M, Abbas M, Nisar J (2019) Efficiency of immobilized Zea mays biomass for the adsorption of chromium from simulated media and tannery wastewater. J Mater Res Technol 8:75–86. https://doi.org/10.1016/j.jmrt.2017.05.016CrossRef

Mohan D, Singh KP, Singh VK (2005) Removal of hexavalent chromium from aqueous solution using low-cost activated carbons derived from agricultural waste materials and activated carbon fabric cloth. Ind Eng Chem Res 44:1027–1042. https://doi.org/10.1021/ie0400898CrossRef

Moradi F, Maleki V, Saleh-Ghadimi S, Kooshki F, Pourghassem Gargari B (2019) Potential roles of chromium on inflammatory biomarkers in diabetes: a systematic. Clin Exp Pharmacol Physiol 46:975–983. https://doi.org/10.1111/1440-1681.13144CrossRefPubMed

Muxel AA, Gimenez SMN, De Souza Almeida FA, Da Silva Alfaya RV, Da Silva Alfaya AA (2011) Cotton Fiber/ZrO2, a new material for adsorption of Cr(VI) Ions in water. CLEAN - Soil, Air, Water 39:289–295. https://doi.org/10.1002/clen.201000165CrossRef

Park SH, Shin SS, Park CH, Jeon S, Gwon J, Lee SY, Kim SJ, Kim HJ, Lee JH (2020) Poly(acryloyl hydrazide)-grafted cellulose nanocrystal adsorbents with an excellent Cr(VI) adsorption capacity. J Hazard Mater 394:122512. https://doi.org/10.1016/j.jhazmat.2020.122512CrossRefPubMed

Peng X, Yan Z, Hu L, Zhang R, Liu S, Wang A, Yu X, Chen L (2020) Adsorption behavior of hexavalent chromium in aqueous solution by polyvinylimidazole modified cellulose. Int J Biol Macromol 155:1184–1193. https://doi.org/10.1016/j.ijbiomac.2019.11.086CrossRefPubMed

Qiu B, Guo J, Zhang X, Sun D, Gu H, Wang Q, Wang H, Wang X, Zhang X, Weeks BL, Guo Z, Wei S (2014) Polyethylenimine facilitated ethyl cellulose for hexavalent chromium removal with a wide pH range. ACS Appl Mater Inter 6:19816–19824. https://doi.org/10.1021/am505170jCrossRef

Rangabhashiyam S, Nakkeeran E, Anu N, Selvaraju N (2014) Biosorption potential of a novel powder, prepared from Ficus auriculata leaves, for sequestration of hexavalent chromium from aqueous solutions. Res Chem Intermed 41:8405–8424. https://doi.org/10.1007/s11164-014-1900-6CrossRef

Rojas SI, Duarte DC, Mosquera SD, Salcedo F, Hinestroza JP, Husserl J (2018) Enhanced biosorption of Cr(VI) using cotton fibers coated with chitosan - role of ester bonds. Water Sci Technol 78:476–486. https://doi.org/10.2166/wst.2018.284CrossRefPubMed

Sharma AK, Devan RS, Arora M, Kumar R, Ma Y-R, Babu JN (2018) Reductive-co-precipitated cellulose immobilized zerovalent iron nanoparticles in ionic liquid/water for Cr(VI) adsorption. Cellulose 25:5259–5275. https://doi.org/10.1007/s10570-018-1932-yCrossRef

Shi X, Qiao Y, An X, Tian Y, Zhou H (2020) High-capacity adsorption of Cr(VI) by lignin-based composite: Characterization, performance and mechanism. Int J Biol Macromol 159:839–849. https://doi.org/10.1016/j.ijbiomac.2020.05.130CrossRefPubMed

Simonin J-P (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chem Eng J 300:254–263. https://doi.org/10.1016/j.cej.2016.04.079CrossRef

Singh P, Chowdhuri DK (2017) Environmental presence of hexavalent but not trivalent chromium causes neurotoxicity in exposed drosophila melanogaster. Mol Neurobiol 54:3368–3387. https://doi.org/10.1007/s12035-016-9909-zCrossRefPubMed

Song W, Gao B, Xu X, Xing L, Han S, Duan P, Song W, Jia R (2016) Adsorption-desorption behavior of magnetic amine/Fe3O4 functionalized biopolymer resin towards anionic dyes from wastewater. Bioresour Technol 210:123–130. https://doi.org/10.1016/j.biortech.2016.01.078CrossRefPubMed

Sun Y, Liu X, Lv X, Wang T, Xue B (2021) Synthesis of novel lignosulfonate-modified graphene hydrogel for ultrahigh adsorption capacity of Cr(VI) from wastewater. J Clean Prod 295:126406. https://doi.org/10.1016/j.jclepro.2021.126406CrossRef

Tariq MA, Nadeem M, Iqbal MM, Imran M, Siddique MH, Iqbal Z, Amjad M, Rizwan M, Ali S (2020) Effective sequestration of Cr (VI) from wastewater using nanocomposite of ZnO with cotton stalks biochar: modeling, kinetics, and reusability. Environ Sci Pollut Res Int 27:33821–33834. https://doi.org/10.1007/s11356-020-09481-xCrossRefPubMed

Vakili M, Deng S, Li T, Wang W, Wang W, Yu G (2018) Novel crosslinked chitosan for enhanced adsorption of hexavalent chromium in acidic solution. Chem Eng J 347:782–790. https://doi.org/10.1016/j.cej.2018.04.181CrossRef

Wang P, Yin Y, Xu J, Chen S, Wang H (2019) Facile synthesis of Cu2+-immobilized imprinted cotton for the selective adsorption of bovine hemoglobin. Cellulose 27:867–877. https://doi.org/10.1007/s10570-019-02816-zCrossRef

Wei Y, Chen W, Liu C, Wang H (2021) Facial synthesis of adsorbent from hemicelluloses for Cr(VI) adsorption. Molecules 26:1443. https://doi.org/10.3390/molecules26051443CrossRefPubMedPubMedCentral

Wu Y, Zhang S, Guo X, Huang H (2008) Adsorption of chromium(III) on lignin. Bioresour Technol 99:7709–7715. https://doi.org/10.1016/j.biortech.2008.01.069CrossRefPubMed

Xie B, Shan C, Xu Z, Li X, Zhang X, Chen J, Pan B (2017) One-step removal of Cr(VI) at alkaline pH by UV/sulfite process: reduction to Cr(III) and in situ Cr(III) precipitation. Chem Eng J 308:791–797. https://doi.org/10.1016/j.cej.2016.09.123CrossRef

Xu X, Gao B, Jin B, Yue Q (2016) Removal of anionic pollutants from liquids by biomass materials: a review. J Mol Liq 215:565–595. https://doi.org/10.1016/j.molliq.2015.12.101CrossRef

Yao F, Jia M, Yang Q, Luo K, Chen F, Zhong Y, He L, Pi Z, Hou K, Wang D, Li X (2020) Electrochemical Cr(VI) removal from aqueous media using titanium as anode: simultaneous indirect electrochemical reduction of Cr(VI) and in-situ precipitation of Cr(III). Chemosphere 260:127537. https://doi.org/10.1016/j.chemosphere.2020.127537CrossRefPubMed

Zhang S, Chen H, Zhang S, Kai C, Jiang M, Wang Q, Zhou Z (2019) Polyethylenimine grafted H2O2-oxidized cellulose membrane as a novel biosorbent for Cr(VI) adsorption and detoxification from aqueous solution. Cellulose 26:3437–3453. https://doi.org/10.1007/s10570-019-02325-zCrossRef

Zhao J, Boada R, Cibin G, Palet C (2021) Enhancement of selective adsorption of Cr species via modification of pine biomass. Sci Total Environ 756:143816. https://doi.org/10.1016/j.scitotenv.2020.143816CrossRefPubMed

Zhao J, Zhang X, He X, Xiao M, Zhang W, Lu C (2015) A super biosorbent from dendrimer poly(amidoamine)-grafted cellulose nanofibril aerogels for effective removal of Cr(vi). J Mater Chem A 3:14703–14711. https://doi.org/10.1039/c5ta03089gCrossRef

Zheng C, Zheng H, Sun Y, Xu B, Wang Y, Zheng X, Wang Y (2019) Simultaneous adsorption and reduction of hexavalent chromium on the poly(4-vinyl pyridine) decorated magnetic chitosan biopolymer in aqueous solution. Bioresour Technol 293:122038. https://doi.org/10.1016/j.biortech.2019.122038CrossRefPubMed

Title: Preparation of cotton fibers modified with aromatic heterocyclic compounds and study of Cr(VI) adsorption performance
Authors: Zhiyu Huang
Peng Wu
Yankun Yin
Xiang Zhou
Lu Fu
Luoxin Wang
Shaohua Chen
Xu Tang
Publication date: 26-09-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 17/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04217-7

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