Skip to main content
Top
Published in: Cellulose 8/2017

26-05-2017 | Communication

Preparation of disk-like cellulose particles

Authors: Kaori Imagawa, Taro Omura, Yasuhito Ihara, Kyosuke Kono, Toyoko Suzuki, Hideto Minami

Published in: Cellulose | Issue 8/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Disk-like cellulose particles were facilely prepared by stirring a dispersion of spongy cellulose particles that were prepared with a solvent-releasing method (SRM) with a magnetic stir bar. The obtained particles were thick and disk-like and retained their spongy structure in the wet state. The thick, disk-like particles became thinner in a specific direction upon drying because of capillary force. In contrast, when the same procedure was conducted using cellulose particles with dense structures, the particle shapes were not deformed, and disk-like shapes did not appear. Moreover, when the stirring was carried out using a shaking bath or a touch mixer, the shape transformation was not observed. These results suggest that the spongy structure of the cellulose particles would be a pseudo-plasticization state, which can cause the cellulose particles to deform. The disk-like particles formed as a result of the grinding of spongy cellulose particles between the stir bar and the vial. The number of disk-like particles and the degree of deformation increased with increasing of the stirring time, the speed and the contact area.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Breier A, Gemeiner P, Hagarova D (1994) Partition mechanism of protein adsorption onto bead 3-phenoxy-2-hydroxypropyl cellulose role of external surface of cellulose particles. Chem Pap Chem Zvesti 48:141–145 Breier A, Gemeiner P, Hagarova D (1994) Partition mechanism of protein adsorption onto bead 3-phenoxy-2-hydroxypropyl cellulose role of external surface of cellulose particles. Chem Pap Chem Zvesti 48:141–145
go back to reference Fredlake CP, Crosthwaite JM, Hert DG, Aki S, Brennecke JF (2004) Thermophysical properties of imidazolium-based ionic liquids. J Chem Eng Data 49:954–964. doi:10.1021/je034261a CrossRef Fredlake CP, Crosthwaite JM, Hert DG, Aki S, Brennecke JF (2004) Thermophysical properties of imidazolium-based ionic liquids. J Chem Eng Data 49:954–964. doi:10.​1021/​je034261a CrossRef
go back to reference Glasser WG, Atalla RH, Blackwell J, Brown RM Jr, Burchard W, French AD, Klemm DO, Nishiyama Y (2012) About the structure of cellulose: debating the Lindman hypothesis. Cellulose 19:589–598. doi:10.1007/s10570-012-9691-7 CrossRef Glasser WG, Atalla RH, Blackwell J, Brown RM Jr, Burchard W, French AD, Klemm DO, Nishiyama Y (2012) About the structure of cellulose: debating the Lindman hypothesis. Cellulose 19:589–598. doi:10.​1007/​s10570-012-9691-7 CrossRef
go back to reference Liu B, Wang DY (2012) High-throughput transformation of colloidal polymer spheres to discs simply via magnetic stirring of their dispersions. Langmuir 28:6436–6440. doi:10.1021/la300042q CrossRef Liu B, Wang DY (2012) High-throughput transformation of colloidal polymer spheres to discs simply via magnetic stirring of their dispersions. Langmuir 28:6436–6440. doi:10.​1021/​la300042q CrossRef
go back to reference Nagaoka S, Ihara H, Honbo J, Hirayama C, Kurisaki H, Ikegami S (1994) Spherical carbon packings prepared from spherical cellulose particles for high-performance liquid-chromatography. Anal Sci 10:543–551. doi:10.2116/analsci.10.543 CrossRef Nagaoka S, Ihara H, Honbo J, Hirayama C, Kurisaki H, Ikegami S (1994) Spherical carbon packings prepared from spherical cellulose particles for high-performance liquid-chromatography. Anal Sci 10:543–551. doi:10.​2116/​analsci.​10.​543 CrossRef
go back to reference Nagaoka S, Arinaga K, Kubo H, Hamaoka S, Sakurai T, Takafuji M, Ihara H (2005) Cellulose/TiO2 hybrid spherical microbeads prepared by a viscose phase separation method: control of the distribution of TiO2 particles in a sphering system. Polym J 37:186–191. doi:10.1295/polymj.37.186 CrossRef Nagaoka S, Arinaga K, Kubo H, Hamaoka S, Sakurai T, Takafuji M, Ihara H (2005) Cellulose/TiO2 hybrid spherical microbeads prepared by a viscose phase separation method: control of the distribution of TiO2 particles in a sphering system. Polym J 37:186–191. doi:10.​1295/​polymj.​37.​186 CrossRef
go back to reference Nagaoka S, Nagata M, Arinaga K, Shigemori K, Takafuji M, Ihara H (2007) Environmentally friendly coloured materials: cellulose/titanium dioxide/inorganic pigment composite spherical microbeads prepared by viscose phase-separation method. Color Technol 123:344–350. doi:10.1111/j.1478-4408.2007.00107.x CrossRef Nagaoka S, Nagata M, Arinaga K, Shigemori K, Takafuji M, Ihara H (2007) Environmentally friendly coloured materials: cellulose/titanium dioxide/inorganic pigment composite spherical microbeads prepared by viscose phase-separation method. Color Technol 123:344–350. doi:10.​1111/​j.​1478-4408.​2007.​00107.​x CrossRef
go back to reference Omura T, Imagawa K, Kono K, Suzuki T, Minami H (2017) Encapsulation of either hydrophilic or hydrophobic substances in spongy cellulose particles. ACS Appl Mater Interfaces 9:944–949. doi:10.1021/acsami.6b13261 CrossRef Omura T, Imagawa K, Kono K, Suzuki T, Minami H (2017) Encapsulation of either hydrophilic or hydrophobic substances in spongy cellulose particles. ACS Appl Mater Interfaces 9:944–949. doi:10.​1021/​acsami.​6b13261 CrossRef
go back to reference Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a C-13 and Cl-35/37 NMR relaxation study on model systems. Chem Commun 1271–1273. doi:10.1039/b600586c Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a C-13 and Cl-35/37 NMR relaxation study on model systems. Chem Commun 1271–1273. doi:10.​1039/​b600586c
go back to reference Zhang L, Liu HQ, Zheng LS, Zhang JY, Du YM, Feng HQ (1996a) Biodegradability of regenerated cellulose films in soil. Ind Eng Chem Res 35:4682–4685. doi:10.1021/ie950624r CrossRef Zhang L, Liu HQ, Zheng LS, Zhang JY, Du YM, Feng HQ (1996a) Biodegradability of regenerated cellulose films in soil. Ind Eng Chem Res 35:4682–4685. doi:10.​1021/​ie950624r CrossRef
go back to reference Zhang LN, Liu HQ, Zheng LS, Zhang JY, Du YM, Liu WL (1996b) Biodegradation of regenerated cellulose films by fungi. Chin J Polym Sci 14:338–345 Zhang LN, Liu HQ, Zheng LS, Zhang JY, Du YM, Liu WL (1996b) Biodegradation of regenerated cellulose films by fungi. Chin J Polym Sci 14:338–345
Metadata
Title
Preparation of disk-like cellulose particles
Authors
Kaori Imagawa
Taro Omura
Yasuhito Ihara
Kyosuke Kono
Toyoko Suzuki
Hideto Minami
Publication date
26-05-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 8/2017
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1342-6

Other articles of this Issue 8/2017

Cellulose 8/2017 Go to the issue