Skip to main content
Erschienen in: Cellulose 8/2017

26.05.2017 | Communication

Preparation of disk-like cellulose particles

verfasst von: Kaori Imagawa, Taro Omura, Yasuhito Ihara, Kyosuke Kono, Toyoko Suzuki, Hideto Minami

Erschienen in: Cellulose | Ausgabe 8/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Disk-like cellulose particles were facilely prepared by stirring a dispersion of spongy cellulose particles that were prepared with a solvent-releasing method (SRM) with a magnetic stir bar. The obtained particles were thick and disk-like and retained their spongy structure in the wet state. The thick, disk-like particles became thinner in a specific direction upon drying because of capillary force. In contrast, when the same procedure was conducted using cellulose particles with dense structures, the particle shapes were not deformed, and disk-like shapes did not appear. Moreover, when the stirring was carried out using a shaking bath or a touch mixer, the shape transformation was not observed. These results suggest that the spongy structure of the cellulose particles would be a pseudo-plasticization state, which can cause the cellulose particles to deform. The disk-like particles formed as a result of the grinding of spongy cellulose particles between the stir bar and the vial. The number of disk-like particles and the degree of deformation increased with increasing of the stirring time, the speed and the contact area.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Breier A, Gemeiner P, Hagarova D (1994) Partition mechanism of protein adsorption onto bead 3-phenoxy-2-hydroxypropyl cellulose role of external surface of cellulose particles. Chem Pap Chem Zvesti 48:141–145 Breier A, Gemeiner P, Hagarova D (1994) Partition mechanism of protein adsorption onto bead 3-phenoxy-2-hydroxypropyl cellulose role of external surface of cellulose particles. Chem Pap Chem Zvesti 48:141–145
Zurück zum Zitat Fredlake CP, Crosthwaite JM, Hert DG, Aki S, Brennecke JF (2004) Thermophysical properties of imidazolium-based ionic liquids. J Chem Eng Data 49:954–964. doi:10.1021/je034261a CrossRef Fredlake CP, Crosthwaite JM, Hert DG, Aki S, Brennecke JF (2004) Thermophysical properties of imidazolium-based ionic liquids. J Chem Eng Data 49:954–964. doi:10.​1021/​je034261a CrossRef
Zurück zum Zitat Glasser WG, Atalla RH, Blackwell J, Brown RM Jr, Burchard W, French AD, Klemm DO, Nishiyama Y (2012) About the structure of cellulose: debating the Lindman hypothesis. Cellulose 19:589–598. doi:10.1007/s10570-012-9691-7 CrossRef Glasser WG, Atalla RH, Blackwell J, Brown RM Jr, Burchard W, French AD, Klemm DO, Nishiyama Y (2012) About the structure of cellulose: debating the Lindman hypothesis. Cellulose 19:589–598. doi:10.​1007/​s10570-012-9691-7 CrossRef
Zurück zum Zitat Liu B, Wang DY (2012) High-throughput transformation of colloidal polymer spheres to discs simply via magnetic stirring of their dispersions. Langmuir 28:6436–6440. doi:10.1021/la300042q CrossRef Liu B, Wang DY (2012) High-throughput transformation of colloidal polymer spheres to discs simply via magnetic stirring of their dispersions. Langmuir 28:6436–6440. doi:10.​1021/​la300042q CrossRef
Zurück zum Zitat Nagaoka S, Ihara H, Honbo J, Hirayama C, Kurisaki H, Ikegami S (1994) Spherical carbon packings prepared from spherical cellulose particles for high-performance liquid-chromatography. Anal Sci 10:543–551. doi:10.2116/analsci.10.543 CrossRef Nagaoka S, Ihara H, Honbo J, Hirayama C, Kurisaki H, Ikegami S (1994) Spherical carbon packings prepared from spherical cellulose particles for high-performance liquid-chromatography. Anal Sci 10:543–551. doi:10.​2116/​analsci.​10.​543 CrossRef
Zurück zum Zitat Nagaoka S, Arinaga K, Kubo H, Hamaoka S, Sakurai T, Takafuji M, Ihara H (2005) Cellulose/TiO2 hybrid spherical microbeads prepared by a viscose phase separation method: control of the distribution of TiO2 particles in a sphering system. Polym J 37:186–191. doi:10.1295/polymj.37.186 CrossRef Nagaoka S, Arinaga K, Kubo H, Hamaoka S, Sakurai T, Takafuji M, Ihara H (2005) Cellulose/TiO2 hybrid spherical microbeads prepared by a viscose phase separation method: control of the distribution of TiO2 particles in a sphering system. Polym J 37:186–191. doi:10.​1295/​polymj.​37.​186 CrossRef
Zurück zum Zitat Nagaoka S, Nagata M, Arinaga K, Shigemori K, Takafuji M, Ihara H (2007) Environmentally friendly coloured materials: cellulose/titanium dioxide/inorganic pigment composite spherical microbeads prepared by viscose phase-separation method. Color Technol 123:344–350. doi:10.1111/j.1478-4408.2007.00107.x CrossRef Nagaoka S, Nagata M, Arinaga K, Shigemori K, Takafuji M, Ihara H (2007) Environmentally friendly coloured materials: cellulose/titanium dioxide/inorganic pigment composite spherical microbeads prepared by viscose phase-separation method. Color Technol 123:344–350. doi:10.​1111/​j.​1478-4408.​2007.​00107.​x CrossRef
Zurück zum Zitat Omura T, Imagawa K, Kono K, Suzuki T, Minami H (2017) Encapsulation of either hydrophilic or hydrophobic substances in spongy cellulose particles. ACS Appl Mater Interfaces 9:944–949. doi:10.1021/acsami.6b13261 CrossRef Omura T, Imagawa K, Kono K, Suzuki T, Minami H (2017) Encapsulation of either hydrophilic or hydrophobic substances in spongy cellulose particles. ACS Appl Mater Interfaces 9:944–949. doi:10.​1021/​acsami.​6b13261 CrossRef
Zurück zum Zitat Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a C-13 and Cl-35/37 NMR relaxation study on model systems. Chem Commun 1271–1273. doi:10.1039/b600586c Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a C-13 and Cl-35/37 NMR relaxation study on model systems. Chem Commun 1271–1273. doi:10.​1039/​b600586c
Zurück zum Zitat Zhang L, Liu HQ, Zheng LS, Zhang JY, Du YM, Feng HQ (1996a) Biodegradability of regenerated cellulose films in soil. Ind Eng Chem Res 35:4682–4685. doi:10.1021/ie950624r CrossRef Zhang L, Liu HQ, Zheng LS, Zhang JY, Du YM, Feng HQ (1996a) Biodegradability of regenerated cellulose films in soil. Ind Eng Chem Res 35:4682–4685. doi:10.​1021/​ie950624r CrossRef
Zurück zum Zitat Zhang LN, Liu HQ, Zheng LS, Zhang JY, Du YM, Liu WL (1996b) Biodegradation of regenerated cellulose films by fungi. Chin J Polym Sci 14:338–345 Zhang LN, Liu HQ, Zheng LS, Zhang JY, Du YM, Liu WL (1996b) Biodegradation of regenerated cellulose films by fungi. Chin J Polym Sci 14:338–345
Metadaten
Titel
Preparation of disk-like cellulose particles
verfasst von
Kaori Imagawa
Taro Omura
Yasuhito Ihara
Kyosuke Kono
Toyoko Suzuki
Hideto Minami
Publikationsdatum
26.05.2017
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 8/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1342-6

Weitere Artikel der Ausgabe 8/2017

Cellulose 8/2017 Zur Ausgabe