Skip to main content
Top
Published in: Journal of Materials Science 1/2019

29-08-2018 | Composites

Preparation of graphene/copper composites using solution-combusted porous sheet-like cuprous oxide

Authors: Zefu Fan, Tangsheng Chen, Xiaohua Chen, Longshan Xu

Published in: Journal of Materials Science | Issue 1/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Porous sheet-like structure of cuprous oxide powder composed of nano-size particles was successfully fabricated by solution combustion method and used as the precursors of copper to prepare the reduced graphene oxide/copper (rGO/Cu) composites. Graphene oxide (GO)/Cu2O hybrids were fabricated by mixing the as-prepared positively charged cuprous oxide colloid with negatively charged GO colloid with uniform distribution of GO by assistance of electrostatic interaction. The hybrids was reduced to rGO/Cu composite in H2 atmosphere and followed by powder metallurgy to form rGO/Cu composite bulk. Microstructure studies indicated that the large-size rGO with 1 wt% content were well and orderly distributed in copper matrix. Microhardness measurements and compression test showed considerable improvements in Vickers hardness from 48 to 58.3 Hv accompanied by retaining the high conductivity of 90.63% IACS due to the addition of graphene. This method offers a new effective approach to fabricate rGO-reinforced copper composites.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Boden A, Boerner B, Kusch P, Firkowska I, Reich S (2014) Nanoplatelet size to control the alignment and thermal conductivity in copper-graphite composites. Nano Lett 14(6):3640–3644CrossRef Boden A, Boerner B, Kusch P, Firkowska I, Reich S (2014) Nanoplatelet size to control the alignment and thermal conductivity in copper-graphite composites. Nano Lett 14(6):3640–3644CrossRef
2.
go back to reference Kim WJ, Lee TJ, Han SH (2014) Multi-layer graphene/copper composites: preparation using high-ratio differential speed rolling, microstructure and mechanical properties. Carbon 69(1):55–65CrossRef Kim WJ, Lee TJ, Han SH (2014) Multi-layer graphene/copper composites: preparation using high-ratio differential speed rolling, microstructure and mechanical properties. Carbon 69(1):55–65CrossRef
3.
go back to reference Zhang X, Wu K, He M, Ye Z, Tang S, Jiang Z (2016) Facile synthesis and characterization of reduced graphene oxide/copper composites using freeze-drying and spark plasma sintering. Mater Lett 166(1):67–70 Zhang X, Wu K, He M, Ye Z, Tang S, Jiang Z (2016) Facile synthesis and characterization of reduced graphene oxide/copper composites using freeze-drying and spark plasma sintering. Mater Lett 166(1):67–70
4.
go back to reference Zhang D, Zhan Z (2016) Preparation of graphene nanoplatelets-copper composites by a modified semi-powder method and their mechanical properties. J. Alloys Compd 658(1):663–671CrossRef Zhang D, Zhan Z (2016) Preparation of graphene nanoplatelets-copper composites by a modified semi-powder method and their mechanical properties. J. Alloys Compd 658(1):663–671CrossRef
5.
go back to reference Chen F, Ying J, Wang Y, Du S, Liu Z, Huang Q (2016) Effects of graphene content on the microstructure and properties of copper matrix composites. Carbon 96:836–842CrossRef Chen F, Ying J, Wang Y, Du S, Liu Z, Huang Q (2016) Effects of graphene content on the microstructure and properties of copper matrix composites. Carbon 96:836–842CrossRef
6.
go back to reference Yue H, Yao L, Gao X, Zhang S, Guo E, Zhang H, Lin X, Wang B (2017) Effect of ball-milling and graphene contents on the mechanical properties and fracture mechanisms of graphene nanosheets reinforced copper matrix composites. J Alloys Compd 691(1):755–762CrossRef Yue H, Yao L, Gao X, Zhang S, Guo E, Zhang H, Lin X, Wang B (2017) Effect of ball-milling and graphene contents on the mechanical properties and fracture mechanisms of graphene nanosheets reinforced copper matrix composites. J Alloys Compd 691(1):755–762CrossRef
7.
go back to reference Kim Y, Lee J, Yeom MS, Shin JW, Kim H, Cui Y, Kysar JW, Hone J, Jung Y, Jeon S, Han SM (2013) Strengthening effect of single-atomic-layer graphene in metal-graphene nanolayered composites. Nat Commun 4:2114–2120CrossRef Kim Y, Lee J, Yeom MS, Shin JW, Kim H, Cui Y, Kysar JW, Hone J, Jung Y, Jeon S, Han SM (2013) Strengthening effect of single-atomic-layer graphene in metal-graphene nanolayered composites. Nat Commun 4:2114–2120CrossRef
8.
go back to reference Tang Y, Yang X, Wang R, Li M (2014) Enhancement of the mechanical properties of graphene–copper composites with graphene–nickel hybrids. Mater Sci Eng A 599(1):247–254CrossRef Tang Y, Yang X, Wang R, Li M (2014) Enhancement of the mechanical properties of graphene–copper composites with graphene–nickel hybrids. Mater Sci Eng A 599(1):247–254CrossRef
9.
go back to reference Hwang J, Yoon T, Jin SH, Lee J, Kim T-S, Hong SH, Jeon S (2013) Enhanced mechanical properties of graphene/copper nanocomposites using a molecular-level mixing process. Adv Mater 25(46):6724–6729CrossRef Hwang J, Yoon T, Jin SH, Lee J, Kim T-S, Hong SH, Jeon S (2013) Enhanced mechanical properties of graphene/copper nanocomposites using a molecular-level mixing process. Adv Mater 25(46):6724–6729CrossRef
10.
go back to reference Zhang D, Zhan Z (2016) Experimental investigation of interfaces in graphene materials/copper composites from a new perspective. RSC Adv 6(57):52219–52226CrossRef Zhang D, Zhan Z (2016) Experimental investigation of interfaces in graphene materials/copper composites from a new perspective. RSC Adv 6(57):52219–52226CrossRef
11.
go back to reference Zhang D, Zhan Z (2016) Strengthening effect of graphene derivatives in copper matrix composites. J Alloys Compd 654(1):226–233CrossRef Zhang D, Zhan Z (2016) Strengthening effect of graphene derivatives in copper matrix composites. J Alloys Compd 654(1):226–233CrossRef
12.
go back to reference Jiang R, Zhou X, Fang Q, Liu Z (2016) Copper–graphene bulk composites with homogeneous graphene dispersion and enhanced mechanical properties. Mater Sci Eng A 654(1):124–130CrossRef Jiang R, Zhou X, Fang Q, Liu Z (2016) Copper–graphene bulk composites with homogeneous graphene dispersion and enhanced mechanical properties. Mater Sci Eng A 654(1):124–130CrossRef
13.
go back to reference Gao X, Yue H, Guo E, Zhang H, Lin X, Yao L, Wang B (2016) Mechanical properties and thermal conductivity of graphene reinforced copper matrix composites. Powder Technol 301(1):601–607CrossRef Gao X, Yue H, Guo E, Zhang H, Lin X, Yao L, Wang B (2016) Mechanical properties and thermal conductivity of graphene reinforced copper matrix composites. Powder Technol 301(1):601–607CrossRef
14.
go back to reference Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502CrossRef Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502CrossRef
15.
go back to reference Balandin AS, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau CN (2008) Nano Lett. 8(3):902–907CrossRef Balandin AS, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau CN (2008) Nano Lett. 8(3):902–907CrossRef
16.
go back to reference Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn J-H, Kim P, Choi J-Y, Hong BH (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457:706–710CrossRef Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn J-H, Kim P, Choi J-Y, Hong BH (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457:706–710CrossRef
17.
go back to reference Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRef Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRef
18.
go back to reference Fan X, Peng W, Li Y, Li X, Wang S, Zhang G, Zhang F (2008) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20(23):4490–4493CrossRef Fan X, Peng W, Li Y, Li X, Wang S, Zhang G, Zhang F (2008) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20(23):4490–4493CrossRef
19.
go back to reference Huang X, Qi X, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41(2):666–686CrossRef Huang X, Qi X, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41(2):666–686CrossRef
20.
go back to reference Mimani T, Patil KC (2001) Solution combustion synthesis of nanoscale oxides and their composites. Mater Phys Mech (Russia) 4(2):134–137 Mimani T, Patil KC (2001) Solution combustion synthesis of nanoscale oxides and their composites. Mater Phys Mech (Russia) 4(2):134–137
21.
go back to reference Jagannatha Reddy A, Kokila MK, Nagabhushana H, Chakradhar RPS, Shivakumara C, Rao JL, Nagabhushana BM (2011) Structural, optical and EPR studies on ZnO: Cu nanopowders prepared via low temperature solution combustion synthesis. J Alloys Compd 509(17):5349–5355CrossRef Jagannatha Reddy A, Kokila MK, Nagabhushana H, Chakradhar RPS, Shivakumara C, Rao JL, Nagabhushana BM (2011) Structural, optical and EPR studies on ZnO: Cu nanopowders prepared via low temperature solution combustion synthesis. J Alloys Compd 509(17):5349–5355CrossRef
22.
go back to reference Mukasyan AS, Epstein P, Dinka P (2007) Solution combustion synthesis of nanomaterials. Solut Combust Inst 31(2):1789–1795CrossRef Mukasyan AS, Epstein P, Dinka P (2007) Solution combustion synthesis of nanomaterials. Solut Combust Inst 31(2):1789–1795CrossRef
23.
go back to reference Varma A, Mukasyan AS, Rogachev AS, Manukyan KV (2016) Solution combustion synthesis of nanoscale materials. Chem Rev 116(23):14493–14586CrossRef Varma A, Mukasyan AS, Rogachev AS, Manukyan KV (2016) Solution combustion synthesis of nanoscale materials. Chem Rev 116(23):14493–14586CrossRef
24.
go back to reference Cao Z, Qin M, Jia B, Yueru G, Chen P, Volinsky AA, Xuanhui Q (2015) One pot solution combustion synthesis of highly mesoporous hematite for photocatalysis. Ceram Int 41(2):2806–2812CrossRef Cao Z, Qin M, Jia B, Yueru G, Chen P, Volinsky AA, Xuanhui Q (2015) One pot solution combustion synthesis of highly mesoporous hematite for photocatalysis. Ceram Int 41(2):2806–2812CrossRef
25.
go back to reference Li X, Xiao Q, Liu B, Lin H, Zhao J (2015) One-step solution-combustion synthesis of complex spinel titanate flake particles with enhanced lithium-storage properties. J Power Sources 273(1):128–135 Li X, Xiao Q, Liu B, Lin H, Zhao J (2015) One-step solution-combustion synthesis of complex spinel titanate flake particles with enhanced lithium-storage properties. J Power Sources 273(1):128–135
26.
go back to reference Tai Z, Chen Y, An Y, Yan X, Xue Q (2012) Tribological behavior of UHMWPE reinforced with graphene oxide nanosheets. Tribol Lett 46(1):55–63CrossRef Tai Z, Chen Y, An Y, Yan X, Xue Q (2012) Tribological behavior of UHMWPE reinforced with graphene oxide nanosheets. Tribol Lett 46(1):55–63CrossRef
27.
go back to reference Zhang L, Hou G, Zhai W, Ai Q, Feng J, Zhang L, Si P, Ci L (2018) Aluminum/graphene composites with enhanced heat-dissipation properties by in situ reduction of graphene oxide on aluminum particles. J Alloys Compd 748(5):854–860CrossRef Zhang L, Hou G, Zhai W, Ai Q, Feng J, Zhang L, Si P, Ci L (2018) Aluminum/graphene composites with enhanced heat-dissipation properties by in situ reduction of graphene oxide on aluminum particles. J Alloys Compd 748(5):854–860CrossRef
Metadata
Title
Preparation of graphene/copper composites using solution-combusted porous sheet-like cuprous oxide
Authors
Zefu Fan
Tangsheng Chen
Xiaohua Chen
Longshan Xu
Publication date
29-08-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 1/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2850-y

Other articles of this Issue 1/2019

Journal of Materials Science 1/2019 Go to the issue

Premium Partners