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Polymer Bulletin
Published in: Polymer Bulletin 6/2012

01-09-2012 | Original Paper

Preparation of hierarchical polyimide hollow spheres via a gas bubble templated transimidization induced crystallization process

Authors: Yuzhi Yan, Lu Chen, Xiang Li, Zihua Chen, Xikui Liu

Published in: Polymer Bulletin | Issue 6/2012

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Abstract

Hierarchical polyimide hollow spheres consisting of crystalline nanoparticles were synthesized by a novel gas bubble templated transimidization induced crystallization process. The morphologies of the hollow spheres can be fine-tuned by changing the concentrations and the chemical structure of the monomers. Based on the experimental results, a possible formation mechanism of these polyimide hollow spheres was proposed based on the aggregation of the primary crystalline polyimide nanoparticles on the in situ formed gas bubbles as soft templates to minimize the interfacial energy.
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Metadata
Title
Preparation of hierarchical polyimide hollow spheres via a gas bubble templated transimidization induced crystallization process
Authors
Yuzhi Yan
Lu Chen
Xiang Li
Zihua Chen
Xikui Liu
Publication date
01-09-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 6/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-012-0754-6

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