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Journal of Sol-Gel Science and Technology

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01-09-2013 | Original Paper

Preparation of nodular carbon cryogel from simple and inexpensive polycondensation reaction of commercial modified black wattle tannin

Authors: Liana Alvares Rodrigues, Julien Parmentier, José Bernardo Parra, Gilmar Patrocínio Thim

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2013

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Abstract

Tannin–formaldehyde cryogels (TFC) were synthesized by sol–gel polycondensation of low molecular weight and highly reactive modified tannin with formaldehyde using HCl as a catalyst. Carbon cryogels (CC) were obtained by the TFC pyrolysis at an inert atmosphere at 800 °C. Pyrolysis caused significant changes in the physical and chemical properties of the material. The pyrolysis induced the decomposition of acid superficial groups and the development of basic ones. Pyrolysis also provoked significant change in the pore volume, forming a great amount of micropores. TFC and CC showed amorphous and turbostratic structures, respectively. Unpurified samples had inorganic impurities in their compositions.

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Title: Preparation of nodular carbon cryogel from simple and inexpensive polycondensation reaction of commercial modified black wattle tannin
Authors: Liana Alvares Rodrigues
Julien Parmentier
José Bernardo Parra
Gilmar Patrocínio Thim
Publication date: 01-09-2013
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 3/2013
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-013-3109-3

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