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Published in: Colloid and Polymer Science 3/2004

01-12-2004 | Short Communication

Preparation of poly(methyl methacrylate) films containing silica particle array structure from colloidal crystals

Authors: Kohji Yoshinaga, Emiko Mouri, Junya Ogawa, Akemi Nakai, Masahiko Ishii, Hiroshi Nakamura

Published in: Colloid and Polymer Science | Issue 3/2004

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Abstract

The incorporation of monodisperse, polymer-modified silica into poly(methyl metharylate) to prepare polymer films containing particle array structure was investigated. The preparation was carried out by a two-step radical polymerization for gelation and solidification. The colloidal crystallization of poly(methyl metharylate)-modified silica, in 78 nm size, in acetonitrile and successive copolymerization of methyl methacrylate and 1,2-dimethacryloylethane by UV light irradiation gave the polymer gel containing the colloidal crystal structure. The exchange of acetonitrile in the gel with methyl methacrylate and further photo-radical polymerization gave the durable polymer film composed of silica particle array.

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Metadata
Title
Preparation of poly(methyl methacrylate) films containing silica particle array structure from colloidal crystals
Authors
Kohji Yoshinaga
Emiko Mouri
Junya Ogawa
Akemi Nakai
Masahiko Ishii
Hiroshi Nakamura
Publication date
01-12-2004
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 3/2004
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-004-1202-4

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