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Colloid and Polymer Science
Published in: Colloid and Polymer Science 3/2004

01-12-2004 | Original Contribution

Two-dimensional correlation gel permeation chromatography (2D GPC) study of the CH3SO3H-catalyzed polymerization of triethoxysilyl-terminated polystyrene. Molecular weight effect on the aggregate–aggregate interactions

Authors: Keita Suzuki, Jun-ichi Oku, Kenichi Izawa, Hiro-Fumi Okabayashi, Isao Noda, Charmian J. O’Connor

Published in: Colloid and Polymer Science | Issue 3/2004

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Abstract

The two-step polymerization process of two well-defined polymeric silane coupling agents, triethoxysilyl-terminated polystyrene with molecular weights equal to 2400 [TESi-PS (2400)] and 8000 [TESi-PS (8000)], catalyzed by 0.1 mol/kg CH3SO3H, was traced as a function of reaction time using gel-permeation chromatography (GPC). Two sets of GPC traces, collected during the condensation, were then converted to two-dimensional (2D) correlation spectra by using generalized 2D correlation theory. The 2D correlation spectra elucidated details of the aggregate–aggregate correlations [in particular, the difference between the correlations of TESi-PS (2400) and TESi-PS (8000)], thus demonstrating the effect of aggregation on the polymerization.
previous article Kinetics of silver nanoparticle growth in aqueous polymer solutions
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Metadata
Title
Two-dimensional correlation gel permeation chromatography (2D GPC) study of the CH3SO3H-catalyzed polymerization of triethoxysilyl-terminated polystyrene. Molecular weight effect on the aggregate–aggregate interactions
Authors
Keita Suzuki
Jun-ichi Oku
Kenichi Izawa
Hiro-Fumi Okabayashi
Isao Noda
Charmian J. O’Connor
Publication date
01-12-2004
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 3/2004
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-004-1144-x

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