Top

Polymer Bulletin

Published in:

22-01-2020 | Original Paper

Preparation of PVA-PFSA-Si pervaporative hybrid membrane and its dehydration performance

Authors: Haikuan Yuan, Chengchong Wang, Xiaodi Liu, Jie Lu

Published in: Polymer Bulletin | Issue 1/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In order to ameliorate the trade-off effect in pervaporation process and to reduce the micro-phase separation of hybrid membrane, polyvinyl alcohol (PVA)-perfluorosulfonic acid (PFSA) blending materials were modified by two inorganic components to prepare PVA-PFSA-Si hybrid membrane. PVA-PFSA-Si membrane was characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), contact angle measurements, scanning electron microscopy (SEM), positron annihilation lifetime spectrometer (PALS) and swelling measurements. As a second inorganic modifier, the effect of γ-glycidyloxypropyl trimethoxysilane (GPTMS) on the morphology of hybrid membrane was better than that of γ-aminopropyl triethoxysilane (APTEOS). PVA-PFSA-Si/polyacrylonitrile (PAN) composite membrane was used to pervaporatively dehydrate ethyl acetate (EAc)/H₂O binary, EAc/ethanol (EtOH)/H₂O ternary EAc/acetic acid (HAc)/EtOH/H₂O quaternary solutions. At feed temperature of 40 °C, M8 membrane had the permeation fluxes (J) of 262.7, 215.2 and 182.6 g m⁻² h⁻¹ and the separation factors (α) of 6673, 3453 and 5374 for pervaporative dehydration of EAc/H₂O (98/2, wt%) binary, EAc/EtOH/H₂O (96/2/2, wt%) ternary and EAc/HAc/EtOH/H₂O (96/1/1/2, wt%) quaternary solutions, respectively. The pervaporative results showed that PVA-PFSA-Si membrane had the excellent dehydration performances for EAc binary or multicomponent aqueous solutions.

previous article Cross-linking network structures and mechanical properties of novel HTPE/PCL binder for solid propellant

next article Physicochemical inspection and in vitro bioactivity behavior of bio-nanocomposite alginate hydrogels filled by magnesium fluoro-hydroxyapatite

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Uragami T, Kishimoto J, Miyata T (2012) Membrane reactor for acceleration of esterification using a special ionic liquid with reaction and separation and microwave heating. Catal Today 193:57–63

Chapman PD, Oliveira T, Livingston AG, Li K (2008) Membranes for the dehydration of solvents by pervaporation. J Membr Sci 318:5–37

Bolto B, Hoang M, Xie Z (2011) A review of membrane selection for the dehydration of aqueous ethanol by pervaporation. Chem Eng Process 50:227–235

Xu S, Wang Y (2018) A prospective study on thermally-cyclodehydrated poly(imide-oxadiazole) membranes for pervaporation dehydration. J Membr Sci 549:184–191

Shameli A, Ameri E (2017) Synthesis of cross-linked PVA membranes embedded with multi-wall carbon nanotubes and their application to esterification of acetic acid with methanol. Chem Eng J 309:381–396

Rao PS, Smitha B, Sridhar S, Krishnaiah A (2006) Preparation and performance of poly(vinyl alcohol)/polyethyleneimine blend membranes for the dehydration of 1,4-dioxane by pervaporation: comparison with glutaraldehyde cross-linked membranes. Sep Purif Technol 48:244–254

Dmitrenko ME, Penkova AV, Kuzminova AI, Morshed M, Larionov MI, Alem H, Zolotarev AA, Ermakov SS, Roizard D (2018) Investigation of new modification strategies for PVA membranes to improve their dehydration properties by pervaporation. Appl Surf Sci 450:527–537

Bolto B, Tran T, Hoang M, Xie Z (2009) Crosslinked poly(vinyl alcohol) membranes. Prog Polym Sci 34:969–981

Cheng PI, Tsai YL, Lee KR, Lai JY, Hong PD (2018) High permselectivity of networked PVA/GA/CS Ag+-Membrane for Dehydration of Isopropanol. J Membr Sci. https://doi.org/10.1016/j.memsci.2018.06.019CrossRef

10.

Kubo S, Kadla JF (2003) The formation of strong intermolecular interactions in immiscible blends of poly(vinyl alcohol) (PVA) and lignin. Biomacromol 4:561–567

11.

Zhang SY, Zou Y, Wei TY, Mu CX, Liu XJ, Tong ZF (2017) Pervaporation dehydration of binary and ternary mixtures of n-butylacetate, n-butanol and water using PVA-CS blended membranes. Sep Purif Technol 173:314–322

12.

Guo RL, Ma XC, Hu CL, Jiang ZY (2007) Novel hybrid PVA-silica pervaporation membrane for dehydration of ethylene glycol aqueous solution. Polymer 48:2939–2945

13.

Torabi B, Ameri E (2016) Methyl acetate production by coupled esterification-reaction process using synthesized cross-linked PVA/silica nanocomposite membranes. Chem Eng J 288:461–472

14.

Suhas DP, Aminabhavi TM, Raghu AV (2014) Mixed matrix membranes of HZSM5-loaded poly(vinyl alcohol) used in pervaporation dehydration of alcohols: influence of silica/alumina ratio. Polym Eng Sci 54:1774–1782

15.

Malekpour A, Mostajeran B, Koohmareh GA (2017) Pervaporation dehydration of binary and ternary mixtures of acetone, isopropanol and water using polyvinyl alcohol/zeolite membranes. Chem Eng Process 118:47–53

16.

Deng YH, Chen JT, Chang CH, Liao KS, Tung KL, Price WE, Yamauchi Y, Wu KCW (2016) A drying-free, water-based process for fabricating mixed-matrix membranes with outstanding pervaporation performance. Angew Chem Int Ed 55:12793–12796

17.

Amirilargani M, Tofighy MA, Mohammadi T, Sadatnia B (2014) Novel poly(vinyl alcohol)/multiwalled carbon nanotube nanocomposite membranes for pervaporation dehydration of isopropanol: poly(sodium 4-styrenesulfonate) as a functionalization agent. Ind Eng Chem Res 53:12819–12829

18.

Hua D, Rai RK, Zhang Y, Chung TS (2017) Aldehyde functionalized graphene oxide frameworks as robust membrane materials for pervaporative alcohol dehydration. Chem Eng Sci 161:341–349

19.

Wang J, Li MS, Zhou SY, Xue AL, Zhang Y, Zhao YJ, Zhong J, Zhang Q (2017) Graphitic carbon nitride nanosheets embedded in poly(vinyl alcohol) nanocomposite membranes for ethanol dehydration via pervaporation. Sep Purif Technol 188:24–37

20.

Wang J, Li MS, Zhou SY, Xue AL, Zhang Y, Zhao YJ, Zhong J (2018) Controllable construction of polymer/inorganic interface for poly(vinyl alcohol)/graphitic carbon nitride hybrid pervaporation membranes. Chem Eng Sci 181:237–250

21.

Zhang H, Wang Y (2016) Poly(vinylalcohol)/ZIF-8-NH₂ mixed matrix membranes for ethanol dehydration via pervaporation. AIChE J 62:1728–1739

22.

Denny MS, Cohen SM (2015) In situ modification of metal-organic frameworks in mixed-matrix membranes. Angew Chem Int Ed Engl 54:9029–9032PubMed

23.

Vinu M, Raja DS, Jiang YC, Liu TY, Xie YY, Lin YF, Yang CC, Lin CH, Alshehri SM, Ahamad T, Salunkhe RR, Yamauchi Y, Deng YH, Wu KCW (2018) Effects of structural crystallinity and defects in microporous Al-MOF filled chitosan mixed matrix membranes for pervaporation of water/ethanol mixtures. J Taiwan Inst Chem Eng 83:143–151

24.

Penkova AV, Acquah SFA, Dmitrenko ME, Sokolova MP, Mikhailova ME, Polyakov ES, Ermakov SS, Markelov DA, Roizard D (2016) Improvement of pervaporation PVA membranes by the controlled incorporation of fullerenol nanoparticles. Mater Des 96:416–423

25.

Liu YC, Chen CY, Lin GS, Chen CH, Wu KCW, Lin CH, Tung KL (2019) Characterization and molecular simulation of Pebax-1657-based mixed matrix membranes incorporating MoS₂ nanosheets for carbon dioxide capture enhancement. J Membr Sci 582:358–366

26.

Hoang VT, Kaliaguine S (2013) Predictive models for mixed-matrix membrane performance: a review. Chem Rev 113:4980–5028

27.

Cheng XX, Pan FS, Wang MR, Li WD, Song YM, Liu GH, Yang H, Gao BX, Wu H, Jiang ZY (2017) Hybrid membranes for pervaporation separations. J Membr Sci 541:329–346

28.

Ma J, Zhang M, Lu LY, Yin X, Chen J, Jiang ZY (2009) Intensifying esterification reaction between lactic acid and ethanol by pervaporation dehydration using chitosan TEOS hybrid membranes. Chem Eng J 155:800–809

29.

Kulkarni SS, Kittur AA, Aralaguppi MI, Kariduraganavar MY (2004) Synthesis and characterization of hybrid membranes using poly(vinyl alcohol) and tetraethylorthosilicate for the pervaporation separation of water–isopropanol mixtures. J Appl Polym Sci 94:1304–1315

30.

Kariduraganavar MY, Kulkarni SS, Kittur AA (2005) Pervaporation separation of water-acetic acid mixtures through poly(vinyl alcohol)-silicone based hybrid membranes. J Membr Sci 246:83–93

31.

Uragami T, Okazaki K, Matsugi H, Miyata T (2002) Structure and permeation characteristics of an aqueous ethanol solution of organic-inorganic hybrid membranes composed of poly(vinyl alcohol) and tetraethoxysilane. Macromolecules 35:9156–9163

32.

Chen JH, Liu QL, Zhang XH, Zhang QG (2007) Pervaporation and characterization of chitosan membranes cross-linked by 3-aminopropyltriethoxysilane. J Membr Sci 292:125–132

33.

Zhang QG, Liu QL, Jiang ZY, Chen Y (2007) Anti-trade-off in dehydration of ethanol by novel PVA/APTEOS hybrid membranes. J Membr Sci 287:237–245

34.

Peng FB, Lu LY, Sun HL, Wang YQ, Wu H, Jiang ZY (2006) Correlations between free volume characteristics and pervaporation permeability of novel PVA-GPTMS hybrid membranes. J Membr Sci 275:97–104

35.

Yuan HK, Zhou Y, Ren J (2014) Pervaporation dehydration of ethyl acetate aqueous solution using the doubly modified polyvinyl alcohol (PVA) composite membrane. Polym Bull 71:2571–2590

36.

Guo RL, Hu CL, Pan FS, Wu H, Jiang ZY (2006) PVA-GPTMS/TEOS hybrid pervaporation membrane for dehydration of ethylene glycol aqueous solution. J Membr Sci 281:454–462

37.

Eldrup M, Lightbody D, Sherwood JN (1981) The temperature dependence of positron lifetimes in solid pivalic acid. J Chem Phys 63:51–58

38.

Khoonsap S, Rugmai S, Hung WS, Lee KR, Klinsrisuk S, Amnuaypanich S (2017) Promoting permeability-selectivity anti-trade-off behavior in polyvinyl alcohol (PVA) nanocomposite membranes. J Membr Sci 544:287–296

39.

Shao P, Huang RYM (2007) Polymeric membrane pervaporation. J Membr Sci 287:162–179

40.

Baker RW, Wijmans JG, Huang Y (2010) Permeability, permeance and selectivity: a preferred way of reporting pervaporation performance data. J Membr Sci 348:346–352

41.

Liu L, Kentish SE (2018) Pervaporation performance of crosslinked PVA membranes in the vicinity of the glass transition temperature. J Membr Sci 553:63–69

42.

Foust AS, Wenzel LA, Clump CW, Maus L, Andersen LB (1980) Principles of unit operations, 2nd edn. Wiley, New York

43.

Razavi S, Sabetghadam A, Mohammadi T (2011) Dehydration of isopropanol by PVA-APTEOS/TEOS nanocomposite membranes. Chem Eng Res Des 89:148–155

44.

Xia LL, Li CL, Wang Y (2016) In-situ crosslinked PVA/organosilica hybrid membranes for pervaporation separations. J Membr Sci 498:263–275

45.

Zhang Y, Ye L (2014) Structure and property of polyvinyl alcohol/precipitated silica composite hydrogels for microorganism immobilization. Compos Part B Eng 56:749–755

46.

Qiao X, Chung TS, Guo WF, Matsuura T, Teoh MM (2005) Dehydration of isopropanol and its comparison with dehydration of butanol isomers from thermodynamic and molecular aspects. J Membr Sci 252:37–49

47.

Liu Q, Wang HY, Wu CL, Wei Z, Wang H (2017) In-situ generation of iron-dopamine nanoparticles with hybridization and cross-linking dual-functions in poly(vinyl alcohol) membranes for ethanol dehydration via pervaporation. Sep Purif Technol 188:282–292

48.

Baker RW (2004) Membrane technology and applications (Chapter 9), 2nd edn. Wiley, Chichester

49.

Yamasaki A, Iwatsubo T, Masuoka T, Mizoguchi K (1994) Pervaporation of ethanol/water through a poly(vinyl alcohol)/cyclodextrin (PVA/CD) membrane. J Membr Sci 89:111–117

50.

Lecaros RG, Deseo KM, Hung WS, Tayo LL, Hu CC, An QF, Tsai HA, Lee KR, Lai JY (2019) Influence of integrating graphene oxide quantum dots on the fine structure characterization and alcohol dehydration performance of pervaporation composite membrane. J Membr Sci 576:36–47

51.

Liu GH, Jiang ZY, Li CD, Hou LP, Chen C, Yang H, Pan FS, Wu H, Zhang P, Cao XZ (2019) Layer-by-layer self-assembled nanocomposite membranes via bio-inspired mineralization for pervaporation dehydration. J Membr Sci 570–571:44–52

52.

Wang Y, Chung TS, Neo BW, Gruender M (2011) Processing and engineering of pervaporation dehydration of ethylene glycol via dual-layer polybenzimidazole (PBI)/polyetherimide (PEI) membranes. J Membr Sci 378:339–350

53.

Li WQ, Luis P (2018) Understanding coupling effects in pervaporation of multi-component mixtures. Sep Purif Technol 197:95–106

54.

Salt Y, Hasanoğlu A, Salt İ, Keleşer S, Őzkan S, Dinçer S (2005) Pervaporation separation of ethylacetate–water mixtures through a crosslinked poly(vinyl alcohol) membrane. Vacuum 79:215–220

55.

Hu WW, Zhang XH, Zhang QG, Liu QL, Zhu AM (2012) Pervaporation dehydration of water/ethanol/ethyl acetate mixtures using poly(vinyl alcohol)–silica hybrid membranes. J Appl Polym Sci 126:778–787

56.

Zhang XH, Liu QL, Xiong Y, Zhu AM, Chen Y, Zhang QG (2009) Pervaporation dehydration of ethyl acetate/ethanol/water azeotrope usingchitosan/poly(vinyl pyrrolidone) blend membranes. J Membr Sci 327:274–280

57.

Ong YT, Tan SH (2016) Pervaporation separation of a ternary azeotrope containing ethyl acetate, ethanol and water using abuckypaper supported ionic liquid membrane. Chem Eng Res Des 109:116–126

58.

Xia SS, Dong XL, Zhu YX, Wei W, Xiangli FJ, Jin WQ (2011) Dehydration of ethyl acetate–water mixtures using PVA/ceramic composite pervaporation membrane. Sep Purif Technol 77:53–59

59.

Lv BD, Liu GP, Dong XL, Wei W, Jin WQ (2012) Novel reactive distillation–pervaporation coupled process for ethyl acetate production with water removal from reboiler and acetic acid recycle. Ind. Eng. Chem. Res. 51:8079–8086

60.

Zhu YX, Xia SS, Liu GP, Jin WQ (2010) Preparation of ceramic-supported poly(vinyl alcohol)–chitosan composite membranes and their applications in pervaporation dehydration of organic/water mixtures. J Membr Sci 349:341–348

Title: Preparation of PVA-PFSA-Si pervaporative hybrid membrane and its dehydration performance
Authors: Haikuan Yuan
Chengchong Wang
Xiaodi Liu
Jie Lu
Publication date: 22-01-2020
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2021
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-020-03107-5

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 1/2021

Size-controlled, single-crystal CuO nanosheets and the resulting polyethylene–carbon nanotube nanocomposite as antimicrobial materials

Study on the effect of Kankara zeolite-Y-based catalyst on the chemical properties of liquid fuel from mixed waste plastics (MWPs) pyrolysis

Effect of boron methacrylate monomer on the thermal and pressure-sensitive adhesive properties of 2-EHA-based copolymer latexes synthesized via mini-emulsion polymerization procedure

Enhancing the adhesion strength of polyurethane coatings by dispersing layered silicates via sonication and high-shear mixing method

Study of polydiacetylenes and rhodamine-800 mixed film at air–water interface and onto solid support: Trace of fluorescence resonance energy transfer (FRET)

Synthesis and characterization of neem (Azadirachta indica) seed oil-based alkyd resins for efficient anticorrosive coating application

Premium Partners