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Published in: Journal of Nanoparticle Research 5/2022

01-05-2022 | Research paper

Preparation of rod-like CuSbS2 particles by soft-template synthesis and electrochemical performance toward lithium storage

Authors: Wei Wang, Guowei Zhi, Liu Liu, Lihui Cao, Jing Xie, Luanhong Sun, Lingyun Hao, Hanyu Yao

Published in: Journal of Nanoparticle Research | Issue 5/2022

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Abstract

CuSbS2 particles could be rapidly prepared by the microwave-assisted liquid phase method. Polyethylene glycol (PEG) was used as the directing agent for morphology and structure of CuSbS2 particles. Microwave irradiation could induce Cu2+, adsorbed on PEG chain structure, to reduce as Cu+. In the further reaction, the rod-like structure of CuSbS2 was formed. The results showed that the CuSbS2 particles prepared by the PEG400 structure directing agent had a higher first discharge specific capacity (~1499.6 mAh g−1) and excellent electronic and ionic conductivity. This method provides a new idea for the morphology control of anode materials for high energy density lithium batteries.

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Literature
go back to reference Beaucage PA, Susca EM, Gruner SM et al (2017) Discovering synthesis routes to hexagonally ordered mesoporous niobium nitrides using poloxamer/pluronics block copolymers. Chem Mater 29(21):8973–8977CrossRef Beaucage PA, Susca EM, Gruner SM et al (2017) Discovering synthesis routes to hexagonally ordered mesoporous niobium nitrides using poloxamer/pluronics block copolymers. Chem Mater 29(21):8973–8977CrossRef
go back to reference Behera C, Samal R, Rout CS et al (2019) Synthesis of CuSbS2 nanoplates and CuSbS2-Cu3SbS4 nanocomposite: effect of sulfur source on different phase formation. Inorg Chem 58(22):15291–15302CrossRef Behera C, Samal R, Rout CS et al (2019) Synthesis of CuSbS2 nanoplates and CuSbS2-Cu3SbS4 nanocomposite: effect of sulfur source on different phase formation. Inorg Chem 58(22):15291–15302CrossRef
go back to reference Dufton JT, Walsh A, Panchmatia PM et al (2012) Structural and electronic properties of CuSbS2 and CuBiS2: potential absorber materials for thin-film solar cells. Phys Chem Chem Phys 14(20):7229–7233CrossRef Dufton JT, Walsh A, Panchmatia PM et al (2012) Structural and electronic properties of CuSbS2 and CuBiS2: potential absorber materials for thin-film solar cells. Phys Chem Chem Phys 14(20):7229–7233CrossRef
go back to reference Fan Z, Yan J, Ning G et al (2013) Porous graphene networks as high performance anode materials for lithium ion batteries. Carbon 60:558–561CrossRef Fan Z, Yan J, Ning G et al (2013) Porous graphene networks as high performance anode materials for lithium ion batteries. Carbon 60:558–561CrossRef
go back to reference García RGA, Cerdán-Pasarán A, Perez EAR et al (2020) Phase pure CuSbS2 thin films by heat treatment of electrodeposited Sb2S3/Cu layers. J Solid State Electrochem 24(1):185–194CrossRef García RGA, Cerdán-Pasarán A, Perez EAR et al (2020) Phase pure CuSbS2 thin films by heat treatment of electrodeposited Sb2S3/Cu layers. J Solid State Electrochem 24(1):185–194CrossRef
go back to reference Ghorpade Uma V, Suryawanshi MP, Shin SW et al (2018) Unassisted visible solar water splitting with efficient photoelectrodes sensitized by quantum dots synthesized via an environmentally friendly eutectic solvent-mediated approach. J Mater Chem A 6(45):22566–22579CrossRef Ghorpade Uma V, Suryawanshi MP, Shin SW et al (2018) Unassisted visible solar water splitting with efficient photoelectrodes sensitized by quantum dots synthesized via an environmentally friendly eutectic solvent-mediated approach. J Mater Chem A 6(45):22566–22579CrossRef
go back to reference Han M, Jia J, Wang W (2017) A novel CuSbS2 hexagonal nanobricks@TiO2 nanorods heterostructure for enhanced photoelectrochemical characteristics. J Alloys Comp 705:356–362CrossRef Han M, Jia J, Wang W (2017) A novel CuSbS2 hexagonal nanobricks@TiO2 nanorods heterostructure for enhanced photoelectrochemical characteristics. J Alloys Comp 705:356–362CrossRef
go back to reference Li X, Liang H, Liu X et al (2021) Ion-exchange strategy of CoS2/Sb2S3 hetero-structured nanocrystals encapsulated into 3D interpenetrating dual-carbon framework for high-performance Na+/K+ batteries. Chem Eng J 425:130657CrossRef Li X, Liang H, Liu X et al (2021) Ion-exchange strategy of CoS2/Sb2S3 hetero-structured nanocrystals encapsulated into 3D interpenetrating dual-carbon framework for high-performance Na+/K+ batteries. Chem Eng J 425:130657CrossRef
go back to reference Liu H, He Y, Cao K et al (2021) Stimulating the reversibility of Sb2S3 anode for high-performance potassium-ion batteries. Small 17(10):2008133CrossRef Liu H, He Y, Cao K et al (2021) Stimulating the reversibility of Sb2S3 anode for high-performance potassium-ion batteries. Small 17(10):2008133CrossRef
go back to reference Ma J, Duan X, Lian J et al (2010) Sb2S3 with various nanostructures: controllable synthesis, formation mechanism, and electrochemical performance toward lithium storage. Chemistry 16(44):13210–13217CrossRef Ma J, Duan X, Lian J et al (2010) Sb2S3 with various nanostructures: controllable synthesis, formation mechanism, and electrochemical performance toward lithium storage. Chemistry 16(44):13210–13217CrossRef
go back to reference Mahmoud MA, O’Neil D, El-Sayed MA (2013) Hollow and solid metallic nanoparticles in sensing and in nanocatalysis. Chem Mater 26(1):44–58CrossRef Mahmoud MA, O’Neil D, El-Sayed MA (2013) Hollow and solid metallic nanoparticles in sensing and in nanocatalysis. Chem Mater 26(1):44–58CrossRef
go back to reference Malho J-M, Morits M, Löbling TI et al (2016) Rod-like nanoparticles with striped and helical topography. ACS Macro Letters 5(10):1185–1190CrossRef Malho J-M, Morits M, Löbling TI et al (2016) Rod-like nanoparticles with striped and helical topography. ACS Macro Letters 5(10):1185–1190CrossRef
go back to reference Mane GP, Talapaneni SN, Lakhi KS et al (2017) Highly ordered nitrogen-rich mesoporous carbon nitrides and their superior performance for sensing and photocatalytic hydrogen generation. Angew Chem Int Ed Engl 56(29):8481–8485CrossRef Mane GP, Talapaneni SN, Lakhi KS et al (2017) Highly ordered nitrogen-rich mesoporous carbon nitrides and their superior performance for sensing and photocatalytic hydrogen generation. Angew Chem Int Ed Engl 56(29):8481–8485CrossRef
go back to reference Manimozhi T, Archana J, Navaneethan M et al (2019) Morphology and phase controlled synthesis of PVP-assisted copper antimony sulfide microstructures using solvothermal method and their properties. Mater Sci Semiconductor Process 103:104606CrossRef Manimozhi T, Archana J, Navaneethan M et al (2019) Morphology and phase controlled synthesis of PVP-assisted copper antimony sulfide microstructures using solvothermal method and their properties. Mater Sci Semiconductor Process 103:104606CrossRef
go back to reference Marino C, Block T, Pöttgen R et al (2017) CuSbS2 as a negative electrode material for sodium ion batteries. J Power Sources 342:616–622CrossRef Marino C, Block T, Pöttgen R et al (2017) CuSbS2 as a negative electrode material for sodium ion batteries. J Power Sources 342:616–622CrossRef
go back to reference McCarthy CL, Cottingham P, Abuyen K et al (2016) Earth abundant CuSbS2 thin films solution processed from thiol–amine mixtures. J Mater Chem C 4(26):6230–6233CrossRef McCarthy CL, Cottingham P, Abuyen K et al (2016) Earth abundant CuSbS2 thin films solution processed from thiol–amine mixtures. J Mater Chem C 4(26):6230–6233CrossRef
go back to reference Qu B, Zhang M, Lei D et al (2011) Facile solvothermal synthesis of mesoporous Cu2SnS3 spheres and their application in lithium-ion batteries. Nanoscale 3(9):3646–3651CrossRef Qu B, Zhang M, Lei D et al (2011) Facile solvothermal synthesis of mesoporous Cu2SnS3 spheres and their application in lithium-ion batteries. Nanoscale 3(9):3646–3651CrossRef
go back to reference Roberts AD, Li X, Zhang H (2014) Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials. Chem Soc Rev 43(13):4341–4356CrossRef Roberts AD, Li X, Zhang H (2014) Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials. Chem Soc Rev 43(13):4341–4356CrossRef
go back to reference Shu B, Han Q (2016) Studies on structural, optical and electrical properties of CuSbS2 nanoparticles. Chalcogenide Lett 13:46–53 Shu B, Han Q (2016) Studies on structural, optical and electrical properties of CuSbS2 nanoparticles. Chalcogenide Lett 13:46–53
go back to reference Shulga Y M, Rubtsov V, Vasilets V, et al. EELS, XPS and IR study of C60·2S8 compound. Synthetic Metals, 1995, 70(1-3): 1381-2. Shulga Y M, Rubtsov V, Vasilets V, et al. EELS, XPS and IR study of C60·2S8 compound. Synthetic Metals, 1995, 70(1-3): 1381-2.
go back to reference Takafuji Y, Jo J-i, Tabata Y (2011) Simple PEG modification of DNA aptamer based on copper ion coordination for tumor targeting. J Biomater Sci Polymer Edition 22(9):1179–1195 Takafuji Y, Jo J-i, Tabata Y (2011) Simple PEG modification of DNA aptamer based on copper ion coordination for tumor targeting. J Biomater Sci Polymer Edition 22(9):1179–1195
go back to reference Tian H, Tan X, Xin F et al (2015) Micro-sized nano-porous Si/C anodes for lithium ion batteries. Nano Energy 11:490–499CrossRef Tian H, Tan X, Xin F et al (2015) Micro-sized nano-porous Si/C anodes for lithium ion batteries. Nano Energy 11:490–499CrossRef
go back to reference Wu P, Liu Z, Ruan M et al (2019) Cobalt-phosphate modified Fe-Zn0.2Cd0.8S/CuSbS2 heterojunction photoanode with multiple synergistic effect for enhancing photoelectrochemical water splitting. Appl Surf Sci 476:716–723CrossRef Wu P, Liu Z, Ruan M et al (2019) Cobalt-phosphate modified Fe-Zn0.2Cd0.8S/CuSbS2 heterojunction photoanode with multiple synergistic effect for enhancing photoelectrochemical water splitting. Appl Surf Sci 476:716–723CrossRef
go back to reference Xie J, Xia J, Yuan Y et al (2019) Sb2S3 embedded in carbon–silicon oxide nanofibers as high-performance anode materials for lithium-ion and sodium-ion batteries. J Power Sources 435:226762CrossRef Xie J, Xia J, Yuan Y et al (2019) Sb2S3 embedded in carbon–silicon oxide nanofibers as high-performance anode materials for lithium-ion and sodium-ion batteries. J Power Sources 435:226762CrossRef
go back to reference Yang B, Wang L, Han J et al (2014) CuSbS2 as a promising earth-abundant photovoltaic absorber material: a combined theoretical and experimental study. Chem Mater 26(10):3135–3143CrossRef Yang B, Wang L, Han J et al (2014) CuSbS2 as a promising earth-abundant photovoltaic absorber material: a combined theoretical and experimental study. Chem Mater 26(10):3135–3143CrossRef
go back to reference Yin H, Hui KS, Zhao X et al (2020) Eco-friendly synthesis of self-supported N-doped Sb2S3-carbon fibers with high atom utilization and zero discharge for commercial full lithium-ion batteries. ACS Appl Energy Mater 3(7):6897–6906CrossRef Yin H, Hui KS, Zhao X et al (2020) Eco-friendly synthesis of self-supported N-doped Sb2S3-carbon fibers with high atom utilization and zero discharge for commercial full lithium-ion batteries. ACS Appl Energy Mater 3(7):6897–6906CrossRef
go back to reference Zakaznova-Herzog VP, Harmer SL, Nesbitt HW et al (2006) High resolution XPS study of the large-band-gap semiconductor stibnite (Sb2S3): structural contributions and surface reconstruction. Surf Sci 600(2):348–356CrossRef Zakaznova-Herzog VP, Harmer SL, Nesbitt HW et al (2006) High resolution XPS study of the large-band-gap semiconductor stibnite (Sb2S3): structural contributions and surface reconstruction. Surf Sci 600(2):348–356CrossRef
go back to reference Zhang Z, Zhou C, Liu Y et al (2013) CuSbS2 nanobricks as electrode materials for lithium ion batteries. Int J Electrochem Sci 8(10059):10067 Zhang Z, Zhou C, Liu Y et al (2013) CuSbS2 nanobricks as electrode materials for lithium ion batteries. Int J Electrochem Sci 8(10059):10067
go back to reference Zhang Z, Fu Y, Zhou C et al (2014) Facile synthesis of CuSbS2 blocks, and their lithium ion storage performance. J Electron Mater 44(1):252–257CrossRef Zhang Z, Fu Y, Zhou C et al (2014) Facile synthesis of CuSbS2 blocks, and their lithium ion storage performance. J Electron Mater 44(1):252–257CrossRef
go back to reference Zhang J, Li W, Li Y et al (2017) Self-optimizing bifunctional CdS/Cu2S with coexistence of light-reduced Cu0 for highly efficient photocatalytic H2 generation under visible-light irradiation. Appl Catal B: Environ 217:30–36CrossRef Zhang J, Li W, Li Y et al (2017) Self-optimizing bifunctional CdS/Cu2S with coexistence of light-reduced Cu0 for highly efficient photocatalytic H2 generation under visible-light irradiation. Appl Catal B: Environ 217:30–36CrossRef
go back to reference Zhang Y, Huang J, Yan C et al (2019) High open-circuit voltage CuSbS2 solar cells achieved through the formation of epitaxial growth of CdS/CuSbS2 hetero-interface by post-annealing treatment. Prog Photovoltaics: Res Appl 27(1):37–43CrossRef Zhang Y, Huang J, Yan C et al (2019) High open-circuit voltage CuSbS2 solar cells achieved through the formation of epitaxial growth of CdS/CuSbS2 hetero-interface by post-annealing treatment. Prog Photovoltaics: Res Appl 27(1):37–43CrossRef
go back to reference Zhang Q, Zeng Y, Wang X et al (2021) Sb2S3 nanoparticles anchored on N-doped 3D carbon nanofibers as anode material for sodium ion batteries with improved electrochemical performance. J Alloys Comp 881:160594CrossRef Zhang Q, Zeng Y, Wang X et al (2021) Sb2S3 nanoparticles anchored on N-doped 3D carbon nanofibers as anode material for sodium ion batteries with improved electrochemical performance. J Alloys Comp 881:160594CrossRef
go back to reference Zhou J, Dou Q, Zhang L et al (2020) A novel and fast method to prepare a Cu-supported α-Sb2S3@CuSbS2 binder-free electrode for sodium-ion batteries. RSC Advances 10(49):29567–29574CrossRef Zhou J, Dou Q, Zhang L et al (2020) A novel and fast method to prepare a Cu-supported α-Sb2S3@CuSbS2 binder-free electrode for sodium-ion batteries. RSC Advances 10(49):29567–29574CrossRef
go back to reference Zou Y, Zhou X, Ma J et al (2020) Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications. Chem Soc Rev 49(4):1173–1208CrossRef Zou Y, Zhou X, Ma J et al (2020) Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications. Chem Soc Rev 49(4):1173–1208CrossRef
Metadata
Title
Preparation of rod-like CuSbS2 particles by soft-template synthesis and electrochemical performance toward lithium storage
Authors
Wei Wang
Guowei Zhi
Liu Liu
Lihui Cao
Jing Xie
Luanhong Sun
Lingyun Hao
Hanyu Yao
Publication date
01-05-2022
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 5/2022
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-022-05481-9

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