Top

Journal of Coatings Technology and Research

Published in:

01-03-2010

Preparation of titanium dioxide compound pigments based on kaolin substrates

Authors: Quanxiang Yan, Yun Lei, Jizu Yuan

Published in: Journal of Coatings Technology and Research | Issue 2/2010

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Titanium dioxide compound pigments were prepared by hydrolysis of tetrabutyl titanate on the surface of kaolin substrates. The coating processes were investigated by various factors in single-factor tests, and the products were tested by oil absorption value and whiteness. The results show that the optimum compound pigments reach a whiteness of 94.0% and an oil absorption value of 35.5 mL/100 g. The products were further characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and zeta potential analyzer. The XRD analysis indicates that the microstructure of the coating on a kaolin substrate is mainly anatase. Transmission electron microscopy images clearly reveal that the layer of TiO₂ consists of randomly oriented small particles with no agglomeration outside the kaolin surface.

previous article The influence of nanoadditives on surface, permeability and mechanical properties of self-organized organic–inorganic nanocomposite coatings

next article The utilization of specific interactions to enhance the mechanical properties of polysiloxane coatings

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Kociolek-Balawejder, E., and Szymczyk, M., “Titanium dioxide as pigment and photocatalyst,” Przemysl Chemiczny, 86, 1179-1188 (2007)

Kim, K. D., Lee, T. J., Kim, H. T., “Optimal conditions for synthesis of TiO₂ nanoparticles in semi-batch reactor,” Colloids and Surfaces A: Physicochem. Eng. Aspects, 224, 1-3 (2003). doi:10.1016/S0927-7757(03)00256-5 CrossRef

[3] Taruta, S., Watanabe, K., Kitajima, K., and Takusagawa, N., “Effect of titania addition on crystallization process and some properties of calcium mica-apatite glass-ceramics,” J. Non-Cryst. Solids, 321, 96-102 (2003). doi:10.1016/S0022-3093(03)00105-4 CrossRefADS

Hu, M. Z. C., Kurian, V., Payzant, E. A., Rawn, C. J., and Hunt, R. D., “Wet-chemical synthesis of monodispersed barium titanate particles - hydrothermal conversion of TiO₂ microspheres to nanocrystalline BaTiO₃,” Powder Technol., 110, 2-14 (2000). doi:10.1016/S0032-5910(99)00262-4 CrossRef

Kim, MK, Kim, CA, Ahn, SD, Kang, SR, Suh, KS, “Density Compatibility of Encapsulation of White Inorganic TiO₂ Particles Using Dispersion Polymerization Technique for Electrophoretic Display.” Synthetic Met., 146 197–199 (2004). doi:10.1016/j.synthmet.2004.07.002 CrossRef

Rentschler, T., “New approaches in papermaking with small particles,” Wochenblatt Fur Papierfabrikation, 133, 1385-1393 (2005)

Freeman, GM, Moller, KH, Carter, RD, “Structure Pigment Compositions, Methods for Preparation and Use.” US Patent 5,551,975, 1996

Touru, N, Akira, U, Kazuyoshi, M, “Process for Producing Titanium Dioxide Pigment for Photograph and Photographic Support Comprising Same.” US Patent 5,264,033, 1993

Kerker, M., Cooke, D. D., Ross, W. D., “Pigmented Microvoid Coatings Theoretical Study of Three Models,” J. Paint Technology, 47, 33-42 (1975)

10.

Kerker, M., Cooke, D. D., “Pigmented Microvoid Coatings. 2. Luminance and Color of the Concentric Sphere Model,” J. Coat. Technol., 48, 35-41 (1976)

11.

Johnson, R. W., Thiele, E. S., French, R. H., “Light-Scattering Efficiency of White Pigments: an Analysis of Model Core - Shell Pigments vs. Optimized Rutile TiO₂,” Tappi Journl, 80, 233-239 (1997)

12.

Matijevic, E, Hsu, P, Kuehnle, MR, “Synthetic Whitener Pigment.” US Patent 5,248,556, 1993

13.

Kohlschutter, H, Getrost, H, Reich, W, Rossler, H, Horl, W, “Process for Coating Titanium Dioxide on Solid Materials.” US Patent 3,553,001, 1971

14.

Bujard, P, “Method of Forming a (Rutile) Titanium Dioxide-Coated Platelet-Like Pigmen.” WO2008104467 (A1), 2008

15.

Deluca, CV, Miller, HA, Waitkins, GR, “Rutile-Coated Mica Nacreous Pigments and Process for the Preparation thereof.” US Patent 4,038,099, 1977

16.

Klenke, EF, Lewis, GL, “Nacreous Mica Pigment Compositions.” US Patent 3,650,790, 1972

17.

Linton, HR, “Nacreous Pigment Compositions.” US Patent 3,087,828, 1963

18.

Rieger, CJ, Armanini, L, “Exterior Grade Titanium Dioxide Coated Mica.” US Patent 4,134,776, 1979

19.

Iwasa, K, Nitta, K, Noguchi, T, “Anti-Discoloring Pearly Luster Pigment and Method of Preparing the Same”. US Patent 5,456,749, 1995

20.

Ren, M., Yin, H. B., Wang, A. L., Jiang, T. S., Wada, Y. J., “Mica coated by direct depositionof rutile TiO₂ nanoparticles and the optical properties” Mater. Chem. Phys., 103, 230-234 (2007). doi:10.1016/j.matchemphys.2007.02.019 CrossRef

21.

Zhao, FZ, Wang, B, Cui, XF, Pan, N, Wang, HQ, Hou, JG, Thin Solid Films, 489 221–228 (2005). doi:10.1016/j.tsf.2005.04.075

22.

Cho, J. H., Lim, S. H., “Internal structure analysis of mica particles coated with metal oxide by transmission electron microscopy,” Dyes and Pigments, 69, 192-195 (2006). doi:10.1016/j.dyepig.2005.03.002 CrossRef

23.

Ninness, B.J., Bousfield, D.W., Tripp, C.P., “Formation of a thin TiO₂ layer on the surfaces of silica and kaolin pigments through atomic layer deposition,” Colloids and Surfaces A: Physicochem. Eng. Aspects 214, 195-204 (2003). doi:10.1016/S0927-7757(02)00390-4 CrossRef

Title: Preparation of titanium dioxide compound pigments based on kaolin substrates
Authors: Quanxiang Yan
Yun Lei
Jizu Yuan
Publication date: 01-03-2010
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 2/2010
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-009-9172-6

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 2/2010

Hygienic coatings by UV curing of diacrylic oligomers with added triclosan

Dry abrasion property of TiN-matrix coating deposited by reactive High Velocity Oxygen Fuel (HVOF) spraying

Occupational exposure to airborne isocyanates during brush/roller application of 2-pack polyurethane paints in a tropical climate

The influence of nanoadditives on surface, permeability and mechanical properties of self-organized organic–inorganic nanocomposite coatings

High-resolution X-ray imaging and analysis of coatings on and in wood

A structural and morphological comparative study between chemically synthesized and photopolymerized poly(pyrrole)

Premium Partners