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Journal of Sol-Gel Science and Technology

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20-05-2022 | Invited Paper: Functional coatings, thin films and membranes (including deposition techniques)

Preparation of transparent and mechanically hard inorganic-organic hybrid thick films from 3-glycidoxypropyltrimethoxysilane and zirconium propoxide

Authors: Takuto Toide, Nataly Carolina Rosero-Navarro, Akira Miura, Hiromitsu Kozuka, Kiyoharu Tadanaga

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2022

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Abstract

In order to lower the heating temperature, inorganic-organic hybrid films prepared by a sol-gel process are attractive candidates for glaze. Here, we prepared the inorganic-organic hybrid thick films on glass substrates by the sol-gel process at 100 °C. The precursor sol was prepared by hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and zirconium propoxide chemically modified with acetylacetone. The obtained GPTMS-ZrO₂-based thick films had a transmittance higher than 80% in the visible light of 390–800 nm. Thick films with a pencil hardness of 5H and a thickness of more than 100 µm were obtained.

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Title: Preparation of transparent and mechanically hard inorganic-organic hybrid thick films from 3-glycidoxypropyltrimethoxysilane and zirconium propoxide
Authors: Takuto Toide
Nataly Carolina Rosero-Navarro
Akira Miura
Hiromitsu Kozuka
Kiyoharu Tadanaga
Publication date: 20-05-2022
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 3/2022
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-022-05836-7

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