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2024 | OriginalPaper | Chapter

Preparation, Structure, and Characterization of SFCA-I

Authors : Yongda Li, Junjie Zeng, Ningyu Zhang, Yuxiao Xue, Yong Hou, Xuewei Lv

Published in: TMS 2024 153rd Annual Meeting & Exhibition Supplemental Proceedings

Publisher: Springer Nature Switzerland

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Abstract

SFCA-I, which is the most ideal binder phase in iron ore sintering, was prepared via a solid-state reaction with analytical reagents. The crystal structure, cold strength, and reduction behavior were individually characterized. The results indicate that SFCA-I crystallizes with lattice parameters of a = 10.62 Å, b = 13.38 Å, c = 11.79 Å, and V = 1122.18 Å3 and SFCA-I has good mechanical strength. The non-isothermal reduction results reveal that the SFCA-I reduction is basically completed when the temperature reaches 962 °C. The results of isothermal reduction test show that the reduction degree of SFCA-I is 97% when it was reduced at 900 °C for 90 min. The order of reduction performance is Fe2O3 > Fe3O4 > SFCA-I > CaO · 2Fe2O3 > CaO · Fe2O3 > 2CaO · Fe2O3 > Ca3Fe2Si1.58Ti1.42O12. In addition, the high-temperature heat capacity of SFCA-I was measured and its function with temperature was modeled.

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Literature
1.
go back to reference Harano T, Nemoto Y, Murao R (2020) Accuracy improvement of the XRD-Rietveld method for the quantification of crystalline phases in iron sintered ores through the correction of micro-absorption effects. ISIJ Int 60(12):2851–2858CrossRef Harano T, Nemoto Y, Murao R (2020) Accuracy improvement of the XRD-Rietveld method for the quantification of crystalline phases in iron sintered ores through the correction of micro-absorption effects. ISIJ Int 60(12):2851–2858CrossRef
2.
go back to reference Nicol S, Chen J, Powceby M (2018) A review of the chemistry, structure and formation conditions of silico-ferrite of calcium and aluminum (‘SFCA’) phases. ISIJ Int 58(12):2157–2172CrossRef Nicol S, Chen J, Powceby M (2018) A review of the chemistry, structure and formation conditions of silico-ferrite of calcium and aluminum (‘SFCA’) phases. ISIJ Int 58(12):2157–2172CrossRef
3.
go back to reference Patrick T, Powceby M (2002) Stability of silico-ferrite of calcium and aluminum (SFCA) in air-solid solution limits between 1240 °C and 1390 °C and phase relationships within the Fe2O3-CaO-Al2O3-SiO2 (FCAS) system. Metall Mater Trans B 33(1):79–89CrossRef Patrick T, Powceby M (2002) Stability of silico-ferrite of calcium and aluminum (SFCA) in air-solid solution limits between 1240 °C and 1390 °C and phase relationships within the Fe2O3-CaO-Al2O3-SiO2 (FCAS) system. Metall Mater Trans B 33(1):79–89CrossRef
4.
go back to reference Mumme WG, Clout JMF, Gable RW (1998) The crystal structure of SFCA-I, Ca3.18Fe14.663+Al1.34Fe0.822+O28, a homologue of the aenigmatite structure type, and new crystal structure refinements of beta-CFF, Ca2.99Fe14.303+Fe0.552+O25 and Mg-free SFCA, Ca2.45Fe9.043+Al1.74Fe0.162+Si0.6O20. Neues Jahrb Mineral Abh 173(1):93–117 Mumme WG, Clout JMF, Gable RW (1998) The crystal structure of SFCA-I, Ca3.18Fe14.663+Al1.34Fe0.822+O28, a homologue of the aenigmatite structure type, and new crystal structure refinements of beta-CFF, Ca2.99Fe14.303+Fe0.552+O25 and Mg-free SFCA, Ca2.45Fe9.043+Al1.74Fe0.162+Si0.6O20. Neues Jahrb Mineral Abh 173(1):93–117
5.
go back to reference Hida Y, Okazaki J, Itoh K (1987) Formation mechanism of acicular calcium ferrite of iron ore sinter. Tetsu-to-Hagané 73:1893CrossRef Hida Y, Okazaki J, Itoh K (1987) Formation mechanism of acicular calcium ferrite of iron ore sinter. Tetsu-to-Hagané 73:1893CrossRef
6.
go back to reference Zhang SJ, Wang ST (1992) Formation mechanism of acicular calcium ferrite. Iron Steel 27(7):7–12 Zhang SJ, Wang ST (1992) Formation mechanism of acicular calcium ferrite. Iron Steel 27(7):7–12
7.
go back to reference Grew ES, Halenius U, Pasero M (2008) Recommended nomenclature for the sapphirine and surinamite groups (sapphirine supergroup). Mineral Mag 72(4):839–876CrossRef Grew ES, Halenius U, Pasero M (2008) Recommended nomenclature for the sapphirine and surinamite groups (sapphirine supergroup). Mineral Mag 72(4):839–876CrossRef
8.
go back to reference Webster N, Churchill J, Tufalle F (2016) Fundamentals of silico-ferrite of calcium and aluminium (SFCA) and SFCA-I iron ore sinter bonding phase formation: effects of titanomagnetite-based ironsand and titanium addition. ISIJ Int 56(10):1715–1722CrossRef Webster N, Churchill J, Tufalle F (2016) Fundamentals of silico-ferrite of calcium and aluminium (SFCA) and SFCA-I iron ore sinter bonding phase formation: effects of titanomagnetite-based ironsand and titanium addition. ISIJ Int 56(10):1715–1722CrossRef
9.
go back to reference Webster N, Pownceby M, Madsen I (2014) Fundamentals of silico-ferrite of calcium and aluminum (SFCA) and SFCA-I iron ore sinter bonding phase formation: effects of CaO:SiO2 ratio. Metall Mater Trans B 45(6):2097–2105CrossRef Webster N, Pownceby M, Madsen I (2014) Fundamentals of silico-ferrite of calcium and aluminum (SFCA) and SFCA-I iron ore sinter bonding phase formation: effects of CaO:SiO2 ratio. Metall Mater Trans B 45(6):2097–2105CrossRef
10.
go back to reference Webster N, Pownceby M, Madsen I (2013) In situ X-ray diffraction investigation of the formation mechanisms of silico-ferrite of calcium and aluminium-I-type (SFCA-I-type) complex calcium ferrites. ISIJ Int 53(8):1334–1340CrossRef Webster N, Pownceby M, Madsen I (2013) In situ X-ray diffraction investigation of the formation mechanisms of silico-ferrite of calcium and aluminium-I-type (SFCA-I-type) complex calcium ferrites. ISIJ Int 53(8):1334–1340CrossRef
11.
go back to reference Webster N, O’Dea D, Elllis B (2017) Effects of gibbsite, kaolinite and Al-rich goethite as alumina sources on silico-ferrite of calcium and aluminium (SFCA) and SFCA-I iron ore sinter bonding phase formation. ISIJ Int 57(1):41–47CrossRef Webster N, O’Dea D, Elllis B (2017) Effects of gibbsite, kaolinite and Al-rich goethite as alumina sources on silico-ferrite of calcium and aluminium (SFCA) and SFCA-I iron ore sinter bonding phase formation. ISIJ Int 57(1):41–47CrossRef
12.
go back to reference Li G, Chen D, You Y (2022) Andradite titanium: preparation, characterization and metallurgical performance. J Am Ceram Soc 105(3):2209–2220CrossRef Li G, Chen D, You Y (2022) Andradite titanium: preparation, characterization and metallurgical performance. J Am Ceram Soc 105(3):2209–2220CrossRef
13.
go back to reference Ding CY, Lv XW, Xuan SY (2017) Powder reduction kinetics of dicalcium ferrite, calcium ferrite, and hematite: measurement and modeling. Adv Powder Technol 28(10):2503–2513CrossRef Ding CY, Lv XW, Xuan SY (2017) Powder reduction kinetics of dicalcium ferrite, calcium ferrite, and hematite: measurement and modeling. Adv Powder Technol 28(10):2503–2513CrossRef
14.
go back to reference Li G (2022) Research on sintering technology of vanadium titanomagnetite with the preformed calcium ferrite. PhD thesis, Chongqing University Li G (2022) Research on sintering technology of vanadium titanomagnetite with the preformed calcium ferrite. PhD thesis, Chongqing University
15.
go back to reference Ding CY, Lv XW, Xuan SY (2017) Effect of silica on reduction of calcium ferrite with CO-N2 gas mixtures. ISIJ Int 57(4):634–642CrossRef Ding CY, Lv XW, Xuan SY (2017) Effect of silica on reduction of calcium ferrite with CO-N2 gas mixtures. ISIJ Int 57(4):634–642CrossRef
16.
go back to reference Pei GS, Xiang JY, Lv XW (2019) High-temperature heat capacity and phase transformation kinetics of NaVO3. J Alloys Compd 794:465–472CrossRef Pei GS, Xiang JY, Lv XW (2019) High-temperature heat capacity and phase transformation kinetics of NaVO3. J Alloys Compd 794:465–472CrossRef
Metadata
Title
Preparation, Structure, and Characterization of SFCA-I
Authors
Yongda Li
Junjie Zeng
Ningyu Zhang
Yuxiao Xue
Yong Hou
Xuewei Lv
Copyright Year
2024
DOI
https://doi.org/10.1007/978-3-031-50349-8_159

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