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Basic Elements for Energy Storage and Conversion Read chapter Read first chapter

2016 | OriginalPaper | Chapter

4. Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Authors : Christian Julien, Alain Mauger, Ashok Vijh, Karim Zaghib

Published in: Lithium Batteries

Publisher: Springer International Publishing

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Abstract

Numerous layered structured compounds are interesting materials in which lithium intercalation occurs primarily without destruction of the host lattice. In many cases a rigid band model is a useful first approximation for describing the changes in electronic properties of the host material with intercalation. We observed, nevertheless, that the rigid-band model is not applicable to all of the layered compounds. One may argue that the applicability of the rigid-band model may be taken as a test for the properties most desirable in a good intercalation material. This needs yet to be more extensively documented for their promising applications as insertion electrode in rechargeable lithium batteries. This chapter presents the applicability of the rigid-band model on intercalation compounds with a layered structure namely the transition-metal chalcogenides MX 2 (X = S, Se) and the transition-metal oxides LiMO2 (M = Co, Ni) as well.

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previous chapter Principles of Intercalation
next chapter Cathode Materials with Two-Dimensional Structure
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Metadata
Title
Reliability of the Rigid-Band Model in Lithium Intercalation Compounds
Authors
Christian Julien
Alain Mauger
Ashok Vijh
Karim Zaghib
Copyright Year
2016
Book
Lithium Batteries

Print ISBN: 978-3-319-19107-2

Electronic ISBN: 978-3-319-19108-9

Copyright Year: 2016

DOI
https://doi.org/10.1007/978-3-319-19108-9_4