nach oben

Erschienen in:

2016 | OriginalPaper | Buchkapitel

4. Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

verfasst von : Christian Julien, Alain Mauger, Ashok Vijh, Karim Zaghib

Erschienen in: Lithium Batteries

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Numerous layered structured compounds are interesting materials in which lithium intercalation occurs primarily without destruction of the host lattice. In many cases a rigid band model is a useful first approximation for describing the changes in electronic properties of the host material with intercalation. We observed, nevertheless, that the rigid-band model is not applicable to all of the layered compounds. One may argue that the applicability of the rigid-band model may be taken as a test for the properties most desirable in a good intercalation material. This needs yet to be more extensively documented for their promising applications as insertion electrode in rechargeable lithium batteries. This chapter presents the applicability of the rigid-band model on intercalation compounds with a layered structure namely the transition-metal chalcogenides MX ₂ (X = S, Se) and the transition-metal oxides LiMO₂ (M = Co, Ni) as well.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Principles of Intercalation

Nächstes Kapitel Cathode Materials with Two-Dimensional Structure

Liang WY (1989) Electronic properties of intercalation compounds. Mater Sci Eng B 3:139–143CrossRef

Wilson JA (1977) Concerning the semimetallic characters of TiS₂ and TiSe₂. Solid State Commun 22:551–553CrossRef

Laubach S, Schmidt PC, Ensling D, Schmid S, Jaegermann W, Thisen A, Nikolowskid K, Ehrenberg H (2009) Changes in the crystal and electronic structure of LiCoO₂ and LiNiO₂ upon Li intercalation and de-intercalation. Phys Chem Chem Phys 11:3278–3289CrossRef

Sellmyer DJ (1978) Electronic structure of metallic compounds and alloys. Solid State Phys 33:83–248

Jones H (1934) The theory of alloys in the γ-phase. Proc R Soc London Ser A 144:225–234CrossRef

Friedel J (1954) Electronic structure of primary solid solutions in metals. Adv Phys 3:446–507CrossRef

Goodenough JB, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603CrossRef

Wilson JA, Yoffe AD (1969) The transition metal dichalcogenides discussion and interpretation of the observed optical, electrical and structural properties. Adv Phys 18:193–335CrossRef

Huisman R, de Jong R, Haas C (1971) Trigonal-prismatic coordination in solid compounds of transition metals. J Solid State Chem 3:56–66CrossRef

10.

Williams PM (1976) Photoemission studies of materials with layered structures. In: Lee PA (ed) Physics and chemistry of materials with layered structure, vol 4. Reidel, Dordrecht, pp 273–341

11.

Brown BE, Beerntsen DJ (1965) Layer structure polytypism among niobium and tantalum selenides. Acta Crystallogr 18:31–36CrossRef

12.

Hibma TJ (1982) Structural aspects of monovalent cation intercalates of layered dichacogenides. In: Whittingham MS, Jacobson AJ (eds) Intercalation chemistry. Academic, New York, pp 285–313

13.

Julien C, Balkanski M (1993) Is the rigid band model applicable in lithium intercalation compounds? Mater Res Soc Symp Proc 293:27–37CrossRef

14.

Julien C, Samaras I, Gorochov O, Ghorayeb AM (1992) Optical and electrical-transport studies on lithium-intercalated TiS₂. Phys Rev B 45:13390–13395CrossRef

15.

Klipstein PC, Pereira CM, Friend RH (1984) Transport and Raman investigation of the group IV layered compounds and their lithium intercalates. In: Acrivos JV, Mott NF, Yoffe AD (eds) Physics and chemistry of electrons and ions in condensed matter, NATO-ASI Series, Ser. C 130. Reidel, Dordrecht, pp 549–559CrossRef

16.

Klipstein PC, Friend RH (1987) Transport properties of Li_xTiS₂ (0 < x < 1): a metal with a tunable Fermi level. J Phys C 20:4169–4180CrossRef

17.

Ghorayeb AM, Friend RH (1987) Transport and optical properties of the hydrazine intercalation complexes of TiS₂, TiSe₂ and ZrS₂. J Phys C 20:4181–4200CrossRef

18.

Beal AR, Nulsen S (1981) Transmission spectra of lithium intercalation complexes of some layered transition-metal dichalcogenides. Phil Mag B 43:965–983CrossRef

19.

Isomaki H, von Boehm J, Krusius P (1979) Band structure of group IVA transition-metal dichacogenides. J Phys C 12:3239–3252CrossRef

20.

Julien C, Ruvalds J, Virosztek A, Gorochov O (1991) Fermi liquid reflectivity of TiS₂. Solid State Commun 79:875–878CrossRef

21.

Virosztek A, Ruvalds J (1990) Nested-Fermi-liquid theory. Phys Rev B 42:4064–4072CrossRef

22.

Scholz GA, Frindt RF (1983) Transmission spectra of silver intercalated 2H-TaS₂ and 1T-TiS₂. Can J Phys 61:965–970CrossRef

23.

Broadhead J, Butherus AD (1972) Rechargeable nonaqueous battery. US Patent 3,791,867, Accessed 12 Feb 1974

24.

Ghorayeb AM, Liang WY, Yoffe AD (1986) Band structure changes upon lithium intercalation. In: Dresselhaus MS (ed) Intercalation in layered compounds, NATO-ASI Series, Ser B 148. Plenum, New York, pp 135–138

25.

Liang WY (1986) Electronic properties of transition metal dichalcogenides and their intercalation complexes. In: Dresselhaus MS (ed) Intercalation in layered compounds, NATO-ASI Series, Ser. B 148. Plenum, New York, pp 31–73

26.

Py MA, Haering RR (1983) Structural destabilization induced by lithium intercalation in MoS₂ and related compounds. Can J Phys 61:76–84CrossRef

27.

Selwyn LS, McKinnon WR, von Sacken U, Jones CA (1987) Lithium electrochemical cells at low voltage. Decomposition of Mo and W dichalcogenides. Solid State Ionics 22:337–344CrossRef

28.

Samaras I, Saikh I, Julien C, Balkanski M (1989) Lithium insertion in layered materials as battery cathodes. Mater Sci Eng B 3:209–214CrossRef

29.

Julien CM (2002) Lithium intercalated compounds: charge transfer and related properties. Mater Sci Eng R 40:47–102CrossRef

30.

Hearing RR, Stiles JAR, Brandt Klaus (1979) Lithium molybdenum disulphide battery cathode. US Patent 4,224,390, Accessed 23 Sep 1980

31.

Chrissafis K, Zamani M, Kambas K, Stoemenos J, Economou NA, Samaras I, Julien C (1989) Structural studies of MoS₂ intercalated by lithium. Mater Sci Eng B 3:145–151CrossRef

32.

Sekine T, Julien C, Samaras I, Jouanne M, Balkanski M (1989) Vibrational modifications on lithium intercalation in MoS₂. Mater Sci Eng B 3:153–158CrossRef

33.

Julien C, Sekine T, Balkanski M (1991) Lattice dynamics of lithium intercalated MoS₂. Solid State Ionics 48:225–229CrossRef

34.

Mattheis LF (1973) Band structure of transition-metal-dichalcogenide layer compounds. Phys Rev B 8:3719–3740CrossRef

35.

Tsai HL, Heising J, Schindler JL, Kannewurf CT, Kanatzidis MG (1997) Exfoliated-restacked phase of WS₂. Chem Mater 9:879–882CrossRef

36.

Rüdorff W (1966) Reaktionen stark elktropositiver metalle mit graphit und mit metalldichalcogeniden. Angew Chem 78:948CrossRef

37.

Somoano RB, Hadek V, Rembaum A (1973) Alkali metal intercalates of molybdenum disulphide. J Chem Phys 58:697–701CrossRef

38.

Omloo WPF, Jellinek F (1970) Intercalation compounds of alkali metals with niobium and tantalum dichalcogenides. J Less Common Metals 20:121–129CrossRef

39.

Julien C, Yebka B (1996) Studies of lithium intercalation in 3R-WS₂. Solid State Ionics 90:141–149CrossRef

40.

DiSalvo FJ, Bagley BG, Voorhoeve JM, Waszczak JV (1973) Preparation and properties of a new polytype of tantalum disulfide (4Hb-TaS₂). J Phys Chem Solids 34:1357–1362CrossRef

41.

Julien C (1990) Technological applications of solid state ionics. Mater Sci Eng B 6:9–28CrossRef

42.

Julien C, Yebka B, Porte C (1998) Effects of the lithium intercalation on the optical band edge of WS₂. Solid State Ionics 110:29–34CrossRef

43.

Likforman A, Carre D, Etienne J, Bachet B (1975) Structure cristalline du monoséléniure d’indium InSe. Acta Crystallogr B 31:1252–1254CrossRef

44.

Ikari T, Shigetomi S, Hashimoto K (1982) Crystal structure and Raman spectra of InSe. Phys Status Sol (b) 111:477–481CrossRef

45.

Levy-Clement C, Rioux J, Dahn JR, McKinnon WR (1984) In-situ X-ray characterization of the reaction of lithium with InSe. Mater Res Bull 19:1629–1634CrossRef

46.

Schellenberger A, Lehman J, Pettenkofer C, Jaegermann W (1994) Electronic structure of in-situ (in UHV) prepared Li/InSe insertion compounds. Solid State Ionics 74:255–262CrossRef

47.

Schellenberger A, Jaegermann W, Pettenkofer C, Tomm Y (1995) Electronic structure and electrochemical potential of electrons during alkali intercalation in layered materials. Ionics 1:115–124CrossRef

48.

Julien C, Jouanne M, Burret PA, Balkanski M (1989) Effects of lithium intercalation on the optical properties of InSe. Mater Sci Eng B 3:39–44CrossRef

49.

Burret PA, Jouanne M, Julien C (1989) Theoretical calculations and Raman spectrum of intercalation modes in Li_xInSe. Z Phys B Condensed Matter 76:451–455CrossRef

50.

Kuroda N, Nishina Y (1978) Resonant Raman scattering at higher M₀ exciton edge in layer compound InSe. Solid State Commun 28:439–443CrossRef

51.

Julien C, Nazri GA (2001) Intercalation compounds for advanced lithium batteries. In: Nalwa HS (ed) Handbook of advanced electronic and photonic materials, vol 10. Academic Press, San Diego, pp 99–184CrossRef

Titel: Reliability of the Rigid-Band Model in Lithium Intercalation Compounds
verfasst von: Christian Julien
Alain Mauger
Ashok Vijh
Karim Zaghib
Verlag: Springer International Publishing
Buch: Lithium Batteries
Print ISBN: 978-3-319-19107-2

Electronic ISBN: 978-3-319-19108-9

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-319-19108-9_4