Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 7/2017

19-06-2017

Research on Photocatalytic Properties of TiO2-Graphene Composites with Different Morphologies

Authors: Guang Hu, Jian Yang, Dong Zhao, Ying Chen, Yan Cao

Published in: Journal of Materials Engineering and Performance | Issue 7/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The TiO2-graphene (TiO2-GR) composites have been successfully synthesized through the hydrothermal reaction. Different structures of TiO2-GR composites were modified using graphene oxide (GO) and different titanium sources in hydrothermal conditions. The structure and properties of the photocatalysts have been characterized by field emission scanning electron microscope (FESEM), x-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS), photoluminescence spectra (PL), UV–vis diffuse reflectance spectra (DRS), and Brunauer–Emmett–Teller (BET). The results showed that due to the larger interfacial contact between TiO2 and graphene, and its greater surface area, the poriferous TiO2-GR composite exhibited the best photocatalytic properties and adsorption performance compared with the other nanocomposites.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference G.M. Wang, H.Y. Wang, Y.C. Ling, Y.C. Tang, X.Y. Yang, R.C. Fitzmorris, C.C. Wang, J.Z. Zhang, and Y. Li, Hydrogen-Treated TiO2 Nanowire Arrays for Photoelectrochemical Water Splitting, Nano Lett., 2011, 11(7), p 3026–3033CrossRef G.M. Wang, H.Y. Wang, Y.C. Ling, Y.C. Tang, X.Y. Yang, R.C. Fitzmorris, C.C. Wang, J.Z. Zhang, and Y. Li, Hydrogen-Treated TiO2 Nanowire Arrays for Photoelectrochemical Water Splitting, Nano Lett., 2011, 11(7), p 3026–3033CrossRef
2.
go back to reference R. Leary and A. Westwood, Carbonaceous Nanomaterials for the Enhancement of TiO2 Photocatalysis, Carbon, 2011, 49(3), p 741–772CrossRef R. Leary and A. Westwood, Carbonaceous Nanomaterials for the Enhancement of TiO2 Photocatalysis, Carbon, 2011, 49(3), p 741–772CrossRef
3.
go back to reference Q.L. Jin, M. Fujishima, and H. Tada, Visible-Light-Active Iron Oxide-Modified Anatase Titanium(IV) Dioxide, J. Phys. Chem. C, 2011, 115(14), p 6478–6483CrossRef Q.L. Jin, M. Fujishima, and H. Tada, Visible-Light-Active Iron Oxide-Modified Anatase Titanium(IV) Dioxide, J. Phys. Chem. C, 2011, 115(14), p 6478–6483CrossRef
4.
go back to reference S. Chusaksri, J. Lomda, T. Saleepochn, and P. Sutthivaiyakit, Photocatalytic Degradation of 3,4-Dichlorophenylurea in Aqueous Gold Nanoparticles-Modified Titanium Dioxide Suspension Under Simulated Solar Light, J. Hazard. Mater., 2011, 190(1–3), p 930–937CrossRef S. Chusaksri, J. Lomda, T. Saleepochn, and P. Sutthivaiyakit, Photocatalytic Degradation of 3,4-Dichlorophenylurea in Aqueous Gold Nanoparticles-Modified Titanium Dioxide Suspension Under Simulated Solar Light, J. Hazard. Mater., 2011, 190(1–3), p 930–937CrossRef
5.
go back to reference S. Ahmed, M.G. Rasul, R. Brown, and M.A. Hashib, Influence of Parameters on the Heterogeneous Photocatalytic Degradation of Pesticides and Phenolic Contaminants in Wastewater: A Short Review, J. Environ. Manag., 2011, 92(3), p 311–330CrossRef S. Ahmed, M.G. Rasul, R. Brown, and M.A. Hashib, Influence of Parameters on the Heterogeneous Photocatalytic Degradation of Pesticides and Phenolic Contaminants in Wastewater: A Short Review, J. Environ. Manag., 2011, 92(3), p 311–330CrossRef
6.
go back to reference J. Jiang, D.R. Chen, and P. Biswas, Synthesis of Nanoparticles in a Flame Aerosol Reactor with Independent and Strict Control of Their Size, Crystal Phase and Morphology, Nanotechnology, 2007, 18(28) J. Jiang, D.R. Chen, and P. Biswas, Synthesis of Nanoparticles in a Flame Aerosol Reactor with Independent and Strict Control of Their Size, Crystal Phase and Morphology, Nanotechnology, 2007, 18(28)
7.
go back to reference B. Liu, Y. Huang, Y. Wen, L. Du, W. Zeng, Y. Shi, F. Zhang, G. Zhu, X. Xu, and Y. Wang, Highly Dispersive 001 Facets-Exposed Nanocrystalline Tio2 on High Quality Graphene as a High Performance Photocatalyst, J. Mater. Chem., 2012, 22(15), p 7484–7491CrossRef B. Liu, Y. Huang, Y. Wen, L. Du, W. Zeng, Y. Shi, F. Zhang, G. Zhu, X. Xu, and Y. Wang, Highly Dispersive 001 Facets-Exposed Nanocrystalline Tio2 on High Quality Graphene as a High Performance Photocatalyst, J. Mater. Chem., 2012, 22(15), p 7484–7491CrossRef
8.
go back to reference K.F. Zhou, Y.H. Zhu, X.L. Yang, X. Jiang, and C.Z. Li, Preparation of Graphene-TiO2 Composites with Enhanced Photocatalytic Activity, New J. Chem., 2011, 35(2), p 353–359CrossRef K.F. Zhou, Y.H. Zhu, X.L. Yang, X. Jiang, and C.Z. Li, Preparation of Graphene-TiO2 Composites with Enhanced Photocatalytic Activity, New J. Chem., 2011, 35(2), p 353–359CrossRef
9.
go back to reference V. Subramanian, E. Wolf, and P.V. Kamat, Semiconductor-Metal Composite Nanostructures. To What Extent Do Metal Nanoparticles Improve the Photocatalytic Activity of TiO2 Films?, J. Phys. Chem. B, 2001, 105(46), p 11439–11446CrossRef V. Subramanian, E. Wolf, and P.V. Kamat, Semiconductor-Metal Composite Nanostructures. To What Extent Do Metal Nanoparticles Improve the Photocatalytic Activity of TiO2 Films?, J. Phys. Chem. B, 2001, 105(46), p 11439–11446CrossRef
10.
go back to reference C. Ratanatawanate, A. Chyao, and K.J. Balkus, S-Nitrosocysteine-Decorated PbS QDs/TiO2 Nanotubes for Enhanced Production of Singlet Oxygen, J. Am. Chem. Soc., 2011, 133(10), p 3492–3497CrossRef C. Ratanatawanate, A. Chyao, and K.J. Balkus, S-Nitrosocysteine-Decorated PbS QDs/TiO2 Nanotubes for Enhanced Production of Singlet Oxygen, J. Am. Chem. Soc., 2011, 133(10), p 3492–3497CrossRef
11.
go back to reference T. Hirakawa and P.V. Kamat, Charge Separation and Catalytic Activity of Ag@TiO2 Core-Shell Composite Clusters Under UV-Irradiation, J. Am. Chem. Soc., 2005, 127(11), p 3928–3934CrossRef T. Hirakawa and P.V. Kamat, Charge Separation and Catalytic Activity of Ag@TiO2 Core-Shell Composite Clusters Under UV-Irradiation, J. Am. Chem. Soc., 2005, 127(11), p 3928–3934CrossRef
12.
go back to reference R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides, Science, 2001, 293(5528), p 269–271CrossRef R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides, Science, 2001, 293(5528), p 269–271CrossRef
13.
go back to reference S. Park and R.S. Ruoff, Chemical Methods for the Production of Graphenes, Nat. Nanotechnol., 2009, 4(4), p 217–224CrossRef S. Park and R.S. Ruoff, Chemical Methods for the Production of Graphenes, Nat. Nanotechnol., 2009, 4(4), p 217–224CrossRef
14.
go back to reference A.K. Geim, Graphene: Status and Prospects, Science, 2009, 324(5934), p 1530–1534CrossRef A.K. Geim, Graphene: Status and Prospects, Science, 2009, 324(5934), p 1530–1534CrossRef
15.
go back to reference P.V. Kamat, Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support, J. Phys. Chem. Lett., 2009, 1(2), p 520–527CrossRef P.V. Kamat, Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support, J. Phys. Chem. Lett., 2009, 1(2), p 520–527CrossRef
16.
go back to reference H. Zhang, P. Xu, G. Du, Z. Chen, K. Oh, D. Pan, and Z. Jiao, A Facile One-Step Synthesis of TiO2/Graphene Composites for Photodegradation of Methyl Orange, Nano Res., 2010, 4(3), p 274–283CrossRef H. Zhang, P. Xu, G. Du, Z. Chen, K. Oh, D. Pan, and Z. Jiao, A Facile One-Step Synthesis of TiO2/Graphene Composites for Photodegradation of Methyl Orange, Nano Res., 2010, 4(3), p 274–283CrossRef
17.
go back to reference S. Morales-Torres, L.M. Pastrana-Martínez, J.L. Figueiredo, J.L. Faria, and A.M.T. Silva, Graphene Oxide-P25 Photocatalysts for Degradation of Diphenhydramine Pharmaceutical and Methyl Orange Dye, Appl. Surf. Sci., 2013, 275, p 361–368CrossRef S. Morales-Torres, L.M. Pastrana-Martínez, J.L. Figueiredo, J.L. Faria, and A.M.T. Silva, Graphene Oxide-P25 Photocatalysts for Degradation of Diphenhydramine Pharmaceutical and Methyl Orange Dye, Appl. Surf. Sci., 2013, 275, p 361–368CrossRef
18.
go back to reference Q. Zhang, Y. He, X. Chen, D. Hu, L. Li, T. Yin, and L. Ji, Structure and Photocatalytic Properties of TiO2-Graphene Oxide Intercalated Composite, Chin. Sci. Bull., 2011, 56(3), p 331–339CrossRef Q. Zhang, Y. He, X. Chen, D. Hu, L. Li, T. Yin, and L. Ji, Structure and Photocatalytic Properties of TiO2-Graphene Oxide Intercalated Composite, Chin. Sci. Bull., 2011, 56(3), p 331–339CrossRef
19.
go back to reference T.-D. Nguyen-Phan, V.H. Pham, E.W. Shin, H.-D. Pham, S. Kim, J.S. Chung, E.J. Kim, and S.H. Hur, The Role of Graphene Oxide Content on the Adsorption-Enhanced Photocatalysis of Titanium Dioxide/Graphene Oxide Composites, Chem. Eng. J., 2011, 170(1), p 226–232CrossRef T.-D. Nguyen-Phan, V.H. Pham, E.W. Shin, H.-D. Pham, S. Kim, J.S. Chung, E.J. Kim, and S.H. Hur, The Role of Graphene Oxide Content on the Adsorption-Enhanced Photocatalysis of Titanium Dioxide/Graphene Oxide Composites, Chem. Eng. J., 2011, 170(1), p 226–232CrossRef
20.
go back to reference Y. Zhou, Y. Huang, D. Li, and W. He, Three-Dimensional Sea-Urchin-Like Hierarchical TiO2 Microspheres Synthesized by a One-Pot Hydrothermal Method and Their Enhanced Photocatalytic Activity, Mater. Res. Bull., 2013, 48(7), p 2420–2425CrossRef Y. Zhou, Y. Huang, D. Li, and W. He, Three-Dimensional Sea-Urchin-Like Hierarchical TiO2 Microspheres Synthesized by a One-Pot Hydrothermal Method and Their Enhanced Photocatalytic Activity, Mater. Res. Bull., 2013, 48(7), p 2420–2425CrossRef
21.
go back to reference N. Zhang, M.Q. Yang, S. Liu, Y. Sun, and Y.J. Xu, Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts, Chem. Rev., 2015, 115(18), p 10307–10377CrossRef N. Zhang, M.Q. Yang, S. Liu, Y. Sun, and Y.J. Xu, Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts, Chem. Rev., 2015, 115(18), p 10307–10377CrossRef
22.
go back to reference N. Zhang and Y.-J. Xu, The Endeavour to Advance Graphene–Semiconductor Composite-Based Photocatalysis, Cryst. Eng. Commun., 2016, 18(1), p 24–37CrossRef N. Zhang and Y.-J. Xu, The Endeavour to Advance Graphene–Semiconductor Composite-Based Photocatalysis, Cryst. Eng. Commun., 2016, 18(1), p 24–37CrossRef
23.
go back to reference C. Han, N. Zhang, and Y.-J. Xu, Structural Diversity of Graphene Materials and Their Multifarious Roles in Heterogeneous Photocatalysis, Nano Today, 2016, 11(3), p 351–372CrossRef C. Han, N. Zhang, and Y.-J. Xu, Structural Diversity of Graphene Materials and Their Multifarious Roles in Heterogeneous Photocatalysis, Nano Today, 2016, 11(3), p 351–372CrossRef
24.
go back to reference H. Zhang, X.J. Lv, Y.M. Li, Y. Wang, and J.H. Li, P25-Graphene Composite as a High Performance Photocatalyst, ACS Nano, 2010, 4(1), p 380–386CrossRef H. Zhang, X.J. Lv, Y.M. Li, Y. Wang, and J.H. Li, P25-Graphene Composite as a High Performance Photocatalyst, ACS Nano, 2010, 4(1), p 380–386CrossRef
25.
go back to reference J.C. Liu, H.W. Bai, Y.J. Wang, Z.Y. Liu, X.W. Zhang, and D.D. Sun, Self-Assembling TiO2 Nanorods on Large Graphene Oxide Sheets at a Two-Phase Interface and Their Anti-Recombination in Photocatalytic Applications, Adv. Funct. Mater., 2010, 20(23), p 4175–4181CrossRef J.C. Liu, H.W. Bai, Y.J. Wang, Z.Y. Liu, X.W. Zhang, and D.D. Sun, Self-Assembling TiO2 Nanorods on Large Graphene Oxide Sheets at a Two-Phase Interface and Their Anti-Recombination in Photocatalytic Applications, Adv. Funct. Mater., 2010, 20(23), p 4175–4181CrossRef
26.
go back to reference H. Wu, J. Fan, Y. Yang, E. Liu, X. Hu, Y. Ma, X. Fan, and C. Tang, Hydrothermal Synthesis of Graphene-TiO2 Nanowire with An Enhanced Photocatalytic Activity, Russ. J. Phys. Chem. A, 2015, 89(7), p 1189–1194CrossRef H. Wu, J. Fan, Y. Yang, E. Liu, X. Hu, Y. Ma, X. Fan, and C. Tang, Hydrothermal Synthesis of Graphene-TiO2 Nanowire with An Enhanced Photocatalytic Activity, Russ. J. Phys. Chem. A, 2015, 89(7), p 1189–1194CrossRef
27.
go back to reference A. Peter, L. Mihaly-Cozmuta, A. Mihaly-Cozmuta, C. Nicula, A. Jastrzębska, P. Kurtycz, and A. Olszyna, Morphology, Structure, and Photoactivity of Two Types of Graphene Oxide–TiO2 Composites, Chem. Pap., 2015, 69(6), p 839–855CrossRef A. Peter, L. Mihaly-Cozmuta, A. Mihaly-Cozmuta, C. Nicula, A. Jastrzębska, P. Kurtycz, and A. Olszyna, Morphology, Structure, and Photoactivity of Two Types of Graphene Oxide–TiO2 Composites, Chem. Pap., 2015, 69(6), p 839–855CrossRef
28.
go back to reference Z. Qianqian, B. Tang, and H. Guoxin, High Photoactive and Visible-Light Responsive Graphene/Titanate Nanotubes Photocatalysts: Preparation and Characterization, J. Hazard. Mater., 2011, 198, p 78–86CrossRef Z. Qianqian, B. Tang, and H. Guoxin, High Photoactive and Visible-Light Responsive Graphene/Titanate Nanotubes Photocatalysts: Preparation and Characterization, J. Hazard. Mater., 2011, 198, p 78–86CrossRef
29.
go back to reference J.F. Shen, M. Shi, N. Li, B. Yan, H.W. Ma, Y.Z. Hu, and M.X. Ye, Facile Synthesis and Application of Ag-Chemically Converted Graphene Nanocomposite, Nano Res., 2010, 3(5), p 339–349CrossRef J.F. Shen, M. Shi, N. Li, B. Yan, H.W. Ma, Y.Z. Hu, and M.X. Ye, Facile Synthesis and Application of Ag-Chemically Converted Graphene Nanocomposite, Nano Res., 2010, 3(5), p 339–349CrossRef
30.
go back to reference S.D. Perera, R.G. Mariano, K. Vu, N. Nour, O. Seitz, Y. Chabal, and K.J. Balkus, Hydrothermal Synthesis of Graphene-TiO2 Nanotube Composites with Enhanced Photocatalytic Activity, Acs Catal., 2012, 2(6), p 949–956CrossRef S.D. Perera, R.G. Mariano, K. Vu, N. Nour, O. Seitz, Y. Chabal, and K.J. Balkus, Hydrothermal Synthesis of Graphene-TiO2 Nanotube Composites with Enhanced Photocatalytic Activity, Acs Catal., 2012, 2(6), p 949–956CrossRef
31.
go back to reference S.W. Liu, C. Liu, W.G. Wang, B. Cheng, and J.G. Yu, Unique Photocatalytic Oxidation Reactivity and Selectivity of TiO2-Graphene Nanocomposites, Nanoscale, 2012, 4(10), p 3193–3200CrossRef S.W. Liu, C. Liu, W.G. Wang, B. Cheng, and J.G. Yu, Unique Photocatalytic Oxidation Reactivity and Selectivity of TiO2-Graphene Nanocomposites, Nanoscale, 2012, 4(10), p 3193–3200CrossRef
32.
go back to reference K.N. Kudin, B. Ozbas, H.C. Schniepp, R.K. Prud’homme, I.A. Aksay, and R. Car, Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets, Nano Lett., 2008, 8(1), p 36–41CrossRef K.N. Kudin, B. Ozbas, H.C. Schniepp, R.K. Prud’homme, I.A. Aksay, and R. Car, Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets, Nano Lett., 2008, 8(1), p 36–41CrossRef
33.
go back to reference S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, and R.S. Ruoff, Synthesis of Graphene-Based Nanosheets via Chemical Reduction of Exfoliated Graphite Oxide, Carbon, 2007, 45(7), p 1558–1565CrossRef S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, and R.S. Ruoff, Synthesis of Graphene-Based Nanosheets via Chemical Reduction of Exfoliated Graphite Oxide, Carbon, 2007, 45(7), p 1558–1565CrossRef
34.
go back to reference I. Yoon, C.D. Kim, B.K. Min, Y.K. Kim, B. Kim, and W.S. Jung, Characterization of Graphene Sheets Formed by the Reaction of Carbon Monoxide with Aluminum Sulfide, B Korean Chem Soc, 2009, 30(12), p 3045–3048CrossRef I. Yoon, C.D. Kim, B.K. Min, Y.K. Kim, B. Kim, and W.S. Jung, Characterization of Graphene Sheets Formed by the Reaction of Carbon Monoxide with Aluminum Sulfide, B Korean Chem Soc, 2009, 30(12), p 3045–3048CrossRef
35.
go back to reference Y. Zhang, Z.-R. Tang, X. Fu, and Y.-J. Xu, Engineering the Unique 2D Mat of Graphene to Achieve Graphene-TiO2 Nanocomposite for Photocatalytic Selective Transformation: What Advantage Does Graphene Have Over Its Forebear Carbon Nanotube?, ACS Nano, 2011, 5(9), p 7426–7435CrossRef Y. Zhang, Z.-R. Tang, X. Fu, and Y.-J. Xu, Engineering the Unique 2D Mat of Graphene to Achieve Graphene-TiO2 Nanocomposite for Photocatalytic Selective Transformation: What Advantage Does Graphene Have Over Its Forebear Carbon Nanotube?, ACS Nano, 2011, 5(9), p 7426–7435CrossRef
Metadata
Title
Research on Photocatalytic Properties of TiO2-Graphene Composites with Different Morphologies
Authors
Guang Hu
Jian Yang
Dong Zhao
Ying Chen
Yan Cao
Publication date
19-06-2017
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 7/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-2776-6

Other articles of this Issue 7/2017

Journal of Materials Engineering and Performance 7/2017 Go to the issue

Premium Partners