Top

Published in:

20-05-2023 | ORIGINAL PAPER

Solid polymer electrolyte membranes of trimethylsulfonium bis(trifluoromethylsulfonyl)imide/NaClO₄/PEO for Na-ion batteries

Authors: Jesús Guzmán-Torres, Arturo G. Sánchez-Valdez, Lorena L. Garza-Tovar, Luis C. Torres-González, Edgar González-Juárez, Ignacio González-Martinez, Arián Espinosa-Roa, Eduardo M. Sánchez-Cervantes

Published in: Polymer Bulletin | Issue 3/2024

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Ionic liquid trimethylsulfonium bis(trifluoromethylsulfonyl)imide (M₃STFSI) was synthesized to obtain solid polymer electrolyte (SPE) membranes by mixing it with polyethylene oxide and sodium perchlorate (NaClO₄). Nine membranes were prepared with varying concentrations of high, medium, and low polymer content. X-ray diffraction, differential scanning calorimetry, scanning electron microscopy, Fourier transform infrared spectroscopy and Raman spectroscopy techniques were used to characterize both the products and the raw materials. Ionic conductivity was determined using electrochemical impedance spectroscopy (EIS), and redox phenomena were studied by cyclic voltammetry. To calculate the total ion transference number and Na⁺ ion transference number, chronoamperometry (CA) with EIS was employed. Additionally, the electrochemical stability in SPE (M1) was measured through linear sweep voltammetry (LSV). The NaFe(SO₄)₂ compound, known as Eldfellite, was utilized as a cathode in Na-ion battery tests. A Na||M1||NaFe(SO₄)₂ cell was prepared to determine the battery performance via galvanostatic charge/discharge profiles. Thus, the theoretical specific capacity of Eldfellite for Na⁺ insertion is 99 mAh g⁻¹, and after 70 cycles at a C/10 rate vs. Na⁰ metallic as an anode, the specific discharge capacity was 75 mAh g⁻¹, with a coulombic efficiency above 99%.

previous article Facile application of terahertz spectroscopy in UV-coated and phase change material loaded MPS

next article Thermal, crystallization, and mechanical properties of polylactic acid (PLA)/poly(butylene succinate) (PBS) blends

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Duy TV, Hoang ND, Thien TN, Thi THN, Van MT, Shigeto O, My LPL (2019) Sodium ion conducting gel polymer electrolyte using poly(vinylidene fluoride hexafluoropropylene). Mater Sci Eng B 241:27–35. https://doi.org/10.1016/j.mseb.2019.02.007CrossRef

Yuqi L, Yaxiang L, Liquan C, Yong SH (2020) Building safer Na-ion batteries with a focus on thermal aspect. Chin Phys B 29:048201. https://doi.org/10.1088/1674-1056/ab7906CrossRef

Hong YS, Li N, Chen H, Wang P, Song WL, Fang D (2018) In operando observation of chemical and mechanical stability of Li and Na dendrites under quasi-zero electrochemical field. Energy Stor Mater 11:118–126. https://doi.org/10.1016/j.ensm.2017.10.007CrossRef

Song S, Kotobuki M, Zheng F, Xu C, Savilov SV, Hu N, Lu L, Wang Y, Li WDZ (2017) A hybrid polymer/oxide/ionic-liquid solid electrolyte for Na-metal batteries. J Mater Chem A 5:6424–6431. https://doi.org/10.1039/C6TA11165CCrossRef

Famprikis T, Canepa P, Dawson JA, Islam MS, Masquelier C (2019) Fundamentals of inorganic solid-state electrolytes for batteries. Nat Mater 18:1278–1291. https://doi.org/10.1038/s41563-019-0431-3CrossRefPubMed

Kim H, Hong J, Park YU, Kim J, Hwang I, Kang K (2015) Sodium storage behavior in natural graphite using ether-based electrolyte systems. Adv Funct Mater 25:534–541. https://doi.org/10.1002/adfm.201402984CrossRef

Koduru HK, Iliev MT, Kondamareddy KK, Karashanova D, Vlakhov T, Zhao XZ, Scaramuzza N (2016) Investigations on Poly (ethylene oxide) (PEO) - blend based solid polymer electrolytes for sodium ion batteries. J Phys Conf Ser 764:012006. https://doi.org/10.1088/1742-6596/764/1/012006CrossRef

Kim SK, Kim SY, Lee JY, Nam J, Lee WB, Kim S, Hyun K (2022) Effects of ionic liquids and silica nanoparticles on the ionic conductivities, mechanical properties, and rheological properties of sodium-containing solid polymer electrolytes. J Power Sources 518:230748. https://doi.org/10.1016/j.jpowsour.2021.230748CrossRef

Araque JC, Hettige JJ, Margulis CJ (2015) Modern room temperature ionic liquids, a simple guide to understand their structure and how it may relate to dynamics. J Phys Chem B 119:12727–12740. https://doi.org/10.1021/acs.jpcb.5b05506CrossRefPubMed

10.

Varun KS, Shalu SKC, Rajendra KS (2016) Development of ionic liquid mediated novel polymer electrolyte membranes for application in Na-ion batteries. RSC Adv 6:40199–40210. https://doi.org/10.1039/C6RA06047ACrossRef

11.

Gebert F, Knott J, Gorkin R, Chou SL, Dou SX (2021) Polymer electrolytes for sodium-ion batteries. Energy Stor Mater 36:10–30. https://doi.org/10.1016/j.ensm.2020.11.030CrossRef

12.

Anouti M, Timperman L, el hilali M, Boisset A, Galiano H, (2012) Sulfonium bis(trifluorosulfonimide) plastic crystal ionic liquid as an electrolyte at elevated temperature for high-energy supercapacitors. J Phys Chem C 116:9412–9418. https://doi.org/10.1021/jp3012987CrossRef

13.

Singh P, Shiva K, Celio H, Goodenough JB (2015) Eldfellite, NaFe(SO₄)₂: an intercalation cathode host for low-cost na-ion batteries. Energy Environ Sci 8:3000–3005. https://doi.org/10.1039/C5EE02274FCrossRef

14.

Kenneth JS, Jun L (2014) Methods for production of hydrocarbons and oxygen-containing hyridrocarbons. Patent number: US 2014/0200318 A1

15.

Nowinski JL, Lightfoot P, Bruce PG (1994) Structure of LiN(CF₃S0₂)₂, a novel salt for electrochemistry. J Mater Chem 4:1579–1580. https://doi.org/10.1039/JM9940401579CrossRef

16.

Boultif A, Louër D (2004) Powder pattern indexing with the dichotomy method. J Appl Crystallogr 37:724–731. https://doi.org/10.1107/S0021889804014876CrossRef

17.

Altomare A, Cuocci C, Giacovazzo C, Moliterni A, Rizzi R, Corriero N, Falcicchio A (2013) EXPO2013: a kit of tools for phasing crystal structures from powder data. J Appl Crystallogr 46:1–5. https://doi.org/10.1107/S0021889813013113CrossRef

18.

Jesús GT, Dalmy LOG, Lorena LGT, Luis CTG, Salomé MPA, Edgar GJ, Idalia G, Eduardo MS (2022) Magnesium bis(oxalate)borate as a potential electrolyte for rechargeable magnesium ion batteries. J Electron Mater 52:1250–1257. https://doi.org/10.1007/s11664-022-10073-3CrossRef

19.

Nakamura K, Ariyama (1959) H Infrared spectra of some derivatives of methionine. Tohoku J Agric Res 9: 269–273. http://hdl.handle.net/10097/29257

20.

Creighton JA, Green JHS, Harrison DJ, Waller SM (1967) The vibrational spectra of some trimethylsulphonium and trimethylsulphoxonium compounds. Spectrochim Acta A Mol Biomol Spectrosc 23A:2973–2979. https://doi.org/10.1016/0584-8539(67)80193-4CrossRef

21.

Cui Y, Zhang J, Wang P, Zhang X, Zheng J, Sun Q, Feng J, Zhu Y (2012) Improved performance using a plasticized polymer electrolyte for quasi-solid state dye-sensitized solar cells. Electrochim Acta 74:194–200. https://doi.org/10.1016/j.electacta.2012.04.061CrossRef

22.

Tao C, Gao MH, Yin BH, Li B, Huang YP, Xu G, Bao JJ (2017) A promising TPU/PEO blend polymer electrolyte for all-solid-state lithium ion batteries. Electrochim Acta 257:31–39. https://doi.org/10.1016/j.electacta.2017.10.037CrossRef

23.

Wang W, Alexandridis P (2016) Composite polymer electrolytes: nanoparticles affect structure and properties. Polymers 8:387. https://doi.org/10.3390/polym8110387CrossRefPubMedPubMedCentral

24.

Abdullah AM, Aziz SB, Saeed SR (2021) Structural and electrical properties of polyvinyl alcohol (PVA): Methyl cellulose (MC) based solid polymer blend electrolytes inserted with sodium iodide (NaI) salt. Arab J Chem 14:103388. https://doi.org/10.1016/j.arabjc.2021.103388CrossRef

25.

Wu F, Zhang K, Liu Y, Gao H, Bai Y, Wang X, Wu C (2020) Polymer electrolytes and interfaces toward solid-state batteries: recent advances and prospects. Energy Stor Mater 33:26–54. https://doi.org/10.1016/j.ensm.2020.08.002CrossRef

26.

Chandra A, Chandra A, Thakur K (2015) Synthesis and characterization of hot pressed ion conducting solid polymer electrolytes: (1–x) PEO: x NaClO4. EPJ Appl Phys 69:20901. https://doi.org/10.1051/epjap/2015140352CrossRef

27.

Sheeba DJ, Sivasankaran BR (2019) Characteristic studies on PEO-based thin nanocomposite polymer electrolytes. Ionics 25:2627–2631. https://doi.org/10.1007/s11581-018-2799-5CrossRef

28.

Elashmawi IS, Gaabour LH (2015) Raman, morphology and electrical behavior of nanocomposites based on PEO/PVDF with multi-walled carbon nanotubes. Results Phys 5:105–110. https://doi.org/10.1016/j.rinp.2015.04.005CrossRef

29.

Li ZY, Li Z, Fu JL, Guo X (2023) Sodium-ion conducting polymer electrolytes. Rare Met 42:1–16. https://doi.org/10.1007/s12598-022-02132-9CrossRef

30.

Yatim LN, Mohamat AES, Suprapto S, Hamzah F, Putu S, Achmad S, Sylvia AP (2022) The fabrication of solid polymer electrolyte from CS/PEO/NaClO₄/Fly ash composite. Polymers 14:4792. https://doi.org/10.3390/polym14224792CrossRef

31.

Sudharshan V, Sushmita D, Palani B (2023) Overview and perspectives of solid electrolytes for sodium batteries. Int J Appl Ceram Technol 20:563–584. https://doi.org/10.1111/ijac.14267CrossRef

32.

De Anastro AF, Lago N, Berlanga C, Galcerán M, Hilder M, Forsyth M, Mecerreyes D (2019) Poly(ionic liquid) iongel membranes for all solid-state rechargeable sodium-ion battery. J Membr Sci 582:435–441. https://doi.org/10.1016/j.memsci.2019.02.074CrossRef

33.

Wang Y, Song S, Xu C, Hu N, Molenda J, Lu L (2019) Development of solid-state electrolytes for sodium-ion battery–a short review. Nano Mat Sci 1:91–100. https://doi.org/10.1016/j.nanoms.2019.02.007CrossRef

34.

Li K, Zhang J, Lin D, Wang DW, Li B, Lv W, Sun S, He YB, Kang F, Yang QH, Zhou L, Zhang TY (2019) Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes. Nat Commun 10:725. https://doi.org/10.1038/s41467-019-08506-5CrossRefPubMedPubMedCentral

35.

Singh VK, Singh SK, Gupta H, Shalu BL, Tripathi AK, Verma YL (2018) Singh, R. K., Electrochemical investigations of Na_0.7CoO₂ cathode with PEO-NaTFSI-BMIMTFSI electrolyte as promising material for Na-rechargeable battery. J Solid State Electrochem 22:1909–1919. https://doi.org/10.1007/s10008-018-3891-5CrossRef

36.

Harshlata MK, Rai DK (2021) Studies on ionic liquid based nanocomposite gel polymer electrolyte and its application in sodium battery. Mater Sci Eng B 267:115098. https://doi.org/10.1016/j.mseb.2021.115098CrossRef

37.

Chen G, Bai Y, Gao Y, Wang Z, Zhang K, Ni Q, Wu F, Xu H, Wu C (2019) ACS Appl Mater Interfaces 11:43252–43260. https://doi.org/10.1021/acsami.9b16294CrossRefPubMed

38.

Singh SK, Gupta H, Balo L, Shalu SVK, Tripathi AK, Verma YL, Singh RK (2018) Electrochemical characterization of ionic liquid based gel polymer electrolyte for lithium battery application. Ionics 24:1895–1906. https://doi.org/10.1007/s11581-018-2458-xCrossRef

Title: Solid polymer electrolyte membranes of trimethylsulfonium bis(trifluoromethylsulfonyl)imide/NaClO4/PEO for Na-ion batteries
Authors: Jesús Guzmán-Torres
Arturo G. Sánchez-Valdez
Lorena L. Garza-Tovar
Luis C. Torres-González
Edgar González-Juárez
Ignacio González-Martinez
Arián Espinosa-Roa
Eduardo M. Sánchez-Cervantes
Publication date: 20-05-2023
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 3/2024
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-023-04844-z

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 3/2024

Development of bovine elastin/tannic acid bioactive conjugate: physicochemical, morphological, and wound healing properties

Enhanced antifouling and surface properties of polymeric membrane via surface modification for treatment of oily wastewater

Denim fabric-reinforced unsaturated polyester: effect of different fabrication methods on mechanical properties and water absorption properties

Remote interaction effect of industrial ion exchangers on the electrochemical and sorption equilibrium in scandium sulfate solution

Effect of post-processing on the mechanical properties of polymers printed by the fused filament fabrication method used as prosthodontic materials and dental biomaterials: a systematic review

Thermal, crystallization, and mechanical properties of polylactic acid (PLA)/poly(butylene succinate) (PBS) blends

Premium Partners