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Colloid and Polymer Science

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10-08-2017 | Original Contribution

Stable aqueous dispersion of polymer functionalized graphene sheets from electrochemical exfoliation for anticorrosion application

Authors: Jun Chen, Haiyan Lu, Yu Chen, Zhenzhen Tao, Minjie Shao

Published in: Colloid and Polymer Science | Issue 10/2017

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Abstract

A green approach of achieving stable aqueous dispersion of graphene by noncovalent functionalization using hydrolyzed styrene-maleic anhydride copolymer has been successfully accomplished. The alkaline solution of hydrolyzed styrene-maleic anhydride copolymer was used as the electrolyte during the electrochemical exfoliation of graphite and simultaneously functionalized the exfoliated graphene sheets. The formation of single-layer graphene was confirmed by X-ray diffraction, atomic force microscopy, and transmission electron microscopy analyses. Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analyses confirm the existence of hydrolyzed styrene-maleic anhydride copolymer on the surface of graphene via noncovalent interaction. The results of electrochemical measurements performed in 3.5 wt% NaCl solution indicated that the addition of well-dispersed hydrolyzed styrene-maleic anhydride copolymer functionalized graphene (SMA-graphene) into waterborne organic silicone resin system remarkably improved anticorrosion performance compared with pure waterborne organic silicone resin coating. This significantly enhanced corrosion protection is mainly due to the longer and circuitous diffusion pathway of the corrosive medium derived from highly dispersed SMA-graphene sheets in the composite coating.

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Title: Stable aqueous dispersion of polymer functionalized graphene sheets from electrochemical exfoliation for anticorrosion application
Authors: Jun Chen
Haiyan Lu
Yu Chen
Zhenzhen Tao
Minjie Shao
Publication date: 10-08-2017
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 10/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-017-4173-y

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