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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2017

10.08.2017 | Original Contribution

Stable aqueous dispersion of polymer functionalized graphene sheets from electrochemical exfoliation for anticorrosion application

verfasst von: Jun Chen, Haiyan Lu, Yu Chen, Zhenzhen Tao, Minjie Shao

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2017

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Abstract

A green approach of achieving stable aqueous dispersion of graphene by noncovalent functionalization using hydrolyzed styrene-maleic anhydride copolymer has been successfully accomplished. The alkaline solution of hydrolyzed styrene-maleic anhydride copolymer was used as the electrolyte during the electrochemical exfoliation of graphite and simultaneously functionalized the exfoliated graphene sheets. The formation of single-layer graphene was confirmed by X-ray diffraction, atomic force microscopy, and transmission electron microscopy analyses. Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analyses confirm the existence of hydrolyzed styrene-maleic anhydride copolymer on the surface of graphene via noncovalent interaction. The results of electrochemical measurements performed in 3.5 wt% NaCl solution indicated that the addition of well-dispersed hydrolyzed styrene-maleic anhydride copolymer functionalized graphene (SMA-graphene) into waterborne organic silicone resin system remarkably improved anticorrosion performance compared with pure waterborne organic silicone resin coating. This significantly enhanced corrosion protection is mainly due to the longer and circuitous diffusion pathway of the corrosive medium derived from highly dispersed SMA-graphene sheets in the composite coating.
Vorheriger Artikel Preparation and characterization of poly(o-anisidine)/SiC composites and study of their corrosion resistances blended with epoxy resin
Nächster Artikel Ionic release behavior of polymer-coated and uncoated metal nanoparticles (MNPs) in various conditions: effects of particle shape, size, and natural media reactivity

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Literatur
1.
Brassard JD, Sarkar DK, Perron J, Audibert-Hayet A, Melot D (2015) Nano-micro structured superhydrophobic zinc coating on steel for prevention of corrosion and ice adhesion. J Colloid Interface Sci 447:240–247CrossRef
2.
Ren JF, Qian B, Li JZ, Song ZW, Hao L, Shi JS (2016) Highly efficient polypyrrole sensitized TiO2 nanotube films for photocathodic protection of Q235 carbon steel. Corros Sci 111:596–601CrossRef
3.
Pagotto JF, Recio FJ, Motheo AJ, Herrasti P (2016) Multilayers of PAni/n-TiO2 and PAni on carbon steel and welded carbon steel for corrosion protection. Surf Coat Technol 289:23–28CrossRef
4.
M'Hiri N, Veys-Renaux D, Rocca E, Ioannou I, Boudhrioua NM, Ghoul M (2016) Corrosion inhibition of carbon steel in acidic medium by orange peel extract and its main antioxidant compounds. Corros Sci 102:55–62CrossRef
5.
Kuila T, Bose S, Mishra AK, Khanra P, Kim NH, Lee JH (2012) Chemical functionalization of graphene and its applications. Prog Mater Sci 57:1061–1105CrossRef
6.
Huang X, Qi X, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41:666–686CrossRef
7.
Wan XJ, Huang Y, Chen YS (2012) Focusing on energy and optoelectronic applications: a journey for graphene and graphene oxide at large scale. Acc Chem Res 45:598–607CrossRef
8.
Liu Y, Dong X, Chen P (2012) Biological and chemical sensors based on graphene materials. Chem Soc Rev 41:2283–2307CrossRef
9.
Novoselov KS, Geim AK, Morozov SV, et al. (2004) Electric field effect in atomically thin carbon films. Science 306:666–669CrossRef
10.
Prasai D, Tuberquia JC, Harl RR, Jennings GK, Bolotin KI (2012) Graphene: corrosion-inhibiting coating. ACS Nano 6:1102–1108CrossRef
11.
Raman RKS, Banerjee PC, Lobo DE, et al. (2012) Protecting copper from electrochemical degradation by graphene coating. Carbon 50:4040–4045CrossRef
12.
Kousalya AS, Kumar A, Paul R, Zemlyanov D, Fisher TS (2013) Graphene: an effective oxidation barrier coating for liquid and two-phase cooling systems. Corros Sci 69:5–10CrossRef
13.
Krishnamurthy A, Gadhamshetty V, Mukherjee R, et al. (2013) Passivation of microbial corrosion using a graphene coating. Carbon 56:45–49CrossRef
14.
Kang D, Kwon JY, Cho H, et al. (2012) Oxidation resistance of iron and copper foils coated with reduced graphene oxide multilayers. ACS Nano 6:7763–7769CrossRef
15.
Sun W, Wang L, Wu T, Pan Y, Liu G (2015) Inhibited corrosion-promotion activity of graphene encapsulated in nanosized silicon oxide. J Mater Chem A 3:16843–16848CrossRef
16.
Yi M, Shen Z, Zhao X, Liu L, Liang S, Zhang X (2014) Exploring few-layer graphene and graphene oxide as fillers to enhance the oxygen-atom corrosion resistance of composites. Phys Chem Chem Phys 16:11162–11167CrossRef
17.
Singh BP, Nayak S, Nanda KK, Jena BK, Bhattacharjee S, Besra L (2013) The production of a corrosion resistant graphene reinforced composite coating on copper by electrophoretic deposition. Carbon 61:47–56CrossRef
18.
Dennis RV, Viyannalage LT, Gaikwad AV, Rout TK, Banerjee S (2013) Graphene nanocomposite coatings for protecting low-alloy steels from corrosion. Am Ceram Soc Bull 92:18–24
19.
Chang C-H, Huang T-C, Peng C-W, et al. (2012) Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon 50:5044–5051CrossRef
20.
Georgakilas V, Otyepka M, Bourlinos AB, et al. (2012) Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications. Chem Rev 112:6156–6214CrossRef
21.
Qi K, Sun Y, Duan H, Guo X (2015) A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite. Corros Sci 98:500–506CrossRef
22.
Gu L, Liu S, Zhao HC, Yu HB (2015) Facile preparation of water-dispersible graphene sheets stabilized by Carboxylated Oligoanilines and their anticorrosion coatings. Acs Appl Mater Interfaces 7:17641–17648CrossRef
23.
Sun W, Wang LD, Wu TT, et al. (2015) Inhibiting the corrosion-promotion activity of graphene. Chem Mater 27:2367–2373CrossRef
24.
Yu Z, Lv L, Ma Y, Di H, He Y (2016) Covalent modification of graphene oxide by metronidazole for reinforced anti-corrosion properties of epoxy coatings. RSC Adv 6:18217–18226CrossRef
25.
Ramezanzadeh B, Niroumandrad S, Ahmadi A, Mahdavian M, Moghadam MHM (2016) Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide. Corros Sci 103:283–304CrossRef
26.
Liu S, Gu L, Zhao HC, Chen JM, Yu HB (2016) Corrosion resistance of graphene-reinforced waterborne epoxy coatings. J Mater Sci Technol 32:425–431CrossRef
27.
Yu Z, Di H, Ma Y, et al. (2015) Fabrication of graphene oxide–alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings. Appl Surf Sci 351:986–996CrossRef
28.
Ramezanzadeh B, Haeri Z, Ramezanzadeh M (2016) A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO2-GO); fabrication of SiO2-GO/epoxy composite coating with superior barrier and corrosion protection performance. Chem Eng J 303:511–528CrossRef
29.
Ma Y, Di HH, Yu ZX, et al. (2016) Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research. Appl Surf Sci 360:936–945CrossRef
30.
Yu Z, Di H, Ma Y, et al. (2015) Preparation of graphene oxide modified by titanium dioxide to enhance the anti-corrosion performance of epoxy coatings. Surf Coat Technol 276:471–478CrossRef
31.
Di HH, Yu ZX, Ma Y, et al. (2016) Anchoring calcium carbonate on graphene oxide reinforced with anticorrosive properties of composite epoxy coatings. Polym Adv Technol 27:915–921CrossRef
32.
Alanyalioglu M, Segura JJ, Oro-Sole J, Casan-Pastor N (2012) The synthesis of graphene sheets with controlled thickness and order using surfactant-assisted electrochemical processes. Carbon 50:142–152CrossRef
33.
Wang GX, Wang B, Park J, Wang Y, Sun B, Yao J (2009) Highly efficient and large-scale synthesis of graphene by electrolytic exfoliation. Carbon 47:3242–3246CrossRef
34.
Yu P, Lowe SE, Simon GP, Zhong YL (2015) Electrochemical exfoliation of graphite and production of functional graphene. Curr Opin Colloid Interface Sci 20:329–338CrossRef
35.
Parvez K, Wu Z-S, Li R, et al. (2014) Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. J Am Chem Soc 136:6083–6091CrossRef
36.
Hu FQ, Jiang SP, Du YZ, Yuan H, Ye YQ, Zeng S (2005) Preparation and characterization of stearic acid nanostructured lipid carriers by solvent diffusion method in an aqueous system. Colloids Surf B Biointerfaces 45:167–173CrossRef
37.
Bose S, Kuila T, Mishra AK, Kim NH, Lee JH (2011) Preparation of non-covalently functionalized graphene using 9-anthracene carboxylic acid. Nanotechnology 22:405603CrossRef
38.
Mensing JP, Kerdcharoen T, Sriprachuabwong C, et al. (2012) Facile preparation of graphene–metal phthalocyanine hybrid material by electrolytic exfoliation. J Mater Chem 22:17094–17099CrossRef
39.
Khanra P, Kuila T, Bae SH, Kim NH, Lee JH (2012) Electrochemically exfoliated graphene using 9-anthracene carboxylic acid for supercapacitor application. J Mater Chem 22:24403CrossRef
40.
Lee JW, Kim M, Na W, Hong SM, Koo CM (2015) Fabrication of high quality graphene nanosheets via a spontaneous electrochemical reaction process. Carbon 91:527–534CrossRef
41.
Sheng X, Cai W, Zhong L, Xie D, Zhang X (2016) Synthesis of functionalized graphene/polyaniline nanocomposites with effective synergistic reinforcement on anticorrosion. Ind Eng Chem Res 55:8576–8585CrossRef
42.
Zhu H, Yue L, Zhuang C, et al. (2016) Fabrication and characterization of self-assembled graphene oxide/silane coatings for corrosion resistance. Surf Coat Technol 304:76–84CrossRef
43.
Hang TTX, Truc TA, Duong NT, Pébère N, Olivier M-G (2012) Layered double hydroxides as containers of inhibitors in organic coatings for corrosion protection of carbon steel. Prog Org Coat 74:343–348CrossRef
44.
Li J, Cui JC, Yang JY, Li YY, Qiu HX, Yang JH (2016) Reinforcement of graphene and its derivatives on the anticorrosive properties of waterborne polyurethane coatings. Compos Sci Technol 129:30–37CrossRef
Metadaten
Titel
Stable aqueous dispersion of polymer functionalized graphene sheets from electrochemical exfoliation for anticorrosion application
verfasst von
Jun Chen
Haiyan Lu
Yu Chen
Zhenzhen Tao
Minjie Shao
Publikationsdatum
10.08.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4173-y

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