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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 5/2014

01-05-2014

Structural and optical properties of Co-doped ZnS nanoparticles synthesized by a capping agent

Authors: Jamil K. Salem, Talaat M. Hammad, S. Kuhn, Mohammed Abu Draaz, Naser K. Hejazy, R. Hempelmann

Published in: Journal of Materials Science: Materials in Electronics | Issue 5/2014

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Abstract

Cobalt-doped Zinc sulfide (ZnS) nanoparticles were prepared by a simple chemical method using alkyl hydroxyl ethyl dimethyl ammonium chloride (YH) as capping agent. The structural and optical properties of prepared cobalt-doped ZnS nanoparticles have been characterized. X-ray diffraction patterns and transmission electron microscope images reveal pure cubic ZnS phase with size of about 5–2 nm for all cobalt-doped ZnS nanoparticles. The lattice constant of the samples decreases slightly by the introduction of Co2+ The absorption edge of the ZnS:Co2+ nanoparticles is blue-shifted as compared with that of bulk ZnS, indicating the quantum confinement effect. The photoluminescence emission band exhibits a blue shift for Co-doped ZnS nanoparticles as compared to the ZnS nanoparticles.
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Metadata
Title
Structural and optical properties of Co-doped ZnS nanoparticles synthesized by a capping agent
Authors
Jamil K. Salem
Talaat M. Hammad
S. Kuhn
Mohammed Abu Draaz
Naser K. Hejazy
R. Hempelmann
Publication date
01-05-2014
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 5/2014
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-014-1856-8

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