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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2016

01-08-2016 | Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Superhydrophobic adhesive surface on titanate nanotube brushes through surface modification by capric acid

Authors: Kenji Okada, Yasuaki Tokudome, Masahide Takahashi

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2016

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Abstract

A superhydrophobic adhesive surface is applied to titanate nanotube (TNT) brushes through surface modification using capric acid. Hydroxyl groups on the TNT brushes are reacted with carboxylic acids via esterification using a chemical vapor deposition method at 110 °C. The alignment of the titanate nanostructures and the surface modification with capric acid resulted in a hydrophobic surface. The hydrophobicity increases with surface modification time; the contact angle, θ CA, increases from 0° to 152°. After 4 h modification, the surface shows superhydrophobicity with water adhesion ability. The use of carboxylic acids as modifiers offers advantages that include low cost, environmental compatibility, and non-toxicity and is capable of adapting TNT-based functional interfaces toward a variety of applications.

Graphical Abstract

previous article Improvements in photostability and sensing properties of EuVO4 nanoparticles by microwave-assisted sol–gel route for detection of H2O2 vapors
next article Magnetic core–shell nanoparticles coated with a molecularly imprinted organogel for organophosphate hydrolysis

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Metadata
Title
Superhydrophobic adhesive surface on titanate nanotube brushes through surface modification by capric acid
Authors
Kenji Okada
Yasuaki Tokudome
Masahide Takahashi
Publication date
01-08-2016
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2016
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4106-0

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