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Polymer Bulletin
Published in: Polymer Bulletin 5/2020

27-06-2019 | Original Paper

Synthesis and characterization of graphene nanoplate-incorporated PVA mixed matrix membrane for improved separation of CO2

Author: Filiz Ugur Nigiz

Published in: Polymer Bulletin | Issue 5/2020

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Abstract

In this study, graphene nanoplate (GNP)-incorporated poly(vinyl alcohol) dense membrane was developed, characterized and used for selective separation of carbon dioxide from methane. The effects of graphene incorporation on crystallinity, mechanical strength, thermal degradation, morphology and CO2 gas separation performance of membrane were investigated. GNPs improved both mechanical and chemical properties of the membrane when the graphene concentration was below 1.5 wt%. The CO2 permselectivity of the membrane was also improved by graphene incorporation. The highest CO2 permeability of 81.45 Barrer and the highest CO2/CH4 ideal selectivity of 41.9 were achieved by using the 1.5 wt% graphene-loaded membrane.
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Literature
1.
Scholes CA, Kanehashi S (2018) Polymeric membrane gas separation performance improvements through supercritical CO2 treatment. J Membr Sci 566:239CrossRef
2.
Xie K, Fu Q, Qiao GG, Webley PA (2019) Recent progress on fabrication methods of polymeric thin film gas separation membranes for CO2 capture. J Membr Sci 572:38CrossRef
3.
Baker RW, Low BT (2014) Gas separation membrane materials: a perspective. Macromolecules 47(20):6999–7013CrossRef
4.
Paul DR, Yampolskii YP (2013) Polymeric gas separation membranes. CRC Press, Boca Raton, p 5
5.
Ismail AF, Khulbe KC, Matsuura T (2015) Gas separation membranes: polymeric and inorganic. Springer, Cham, p 5
6.
Galizia M, Chi WS, Smith ZP, Merkel TC, Baker RW, Freeman BD (2017) 50th anniversary perspective: polymers and mixed matrix membranes for gas and vapor separation: a review and prospective opportunities. Macromolecules 50(20):7809–7843CrossRef
7.
Behnia N, Pirouzfar V (2018) Effect of operating pressure and pyrolysis conditions on the performance of carbon membranes for CO2/CH4 and O2/N2 separation derived from polybenzimidazole/Matrimid and UIP-S precursor blends. Polym Bull 75(10):4341–4358CrossRef
8.
Kosinov N, Gascon J, Kapteijn F, Hensen EJM (2016) Recent developments in zeolite membranes for gas separation. J Membr Sci 499:65–79CrossRef
9.
Saufi SM, Ismail AF (2004) Fabrication of carbon membranes for gas separation—a review. Carbon 42(2):241–259CrossRef
10.
Chiu WV, Park IS, Shqau K, White JC, Schillo MC, Hoa WSW, Dutta PK, Verweij H (2011) Post-synthesis defect abatement of inorganic membranes for gas separation. J Membr Sci 377:182CrossRef
11.
Bernardo P, Drioli E, Golemme G (2009) Membrane gas separation: 1 review of state of the art. Ind Chem Eng 48(1):4638–4663CrossRef
12.
Fu H, Yang D, Zhang S, Jian X (2007) Preparation of poly(phthalazinone ether sulfone ketone) hollow fiber membrane for gas separation. J Appl Polym Sci 105:405CrossRef
13.
Armstrong SR, Offord GT, Paul DR, Freeman BD, Hiltner A, Baer E (2014) Co-extruded polymeric films for gas separation membranes. Appl Polym Sci 131:39765CrossRef
14.
Yoshioka T, Kojima K, Shindo R, Nagai K (2017) Gas-separation properties of amine-crosslinked polyimide membranes modified by amine vapor. J Appl Polym Sci 134:44569CrossRef
15.
Robeson LM, Dose ME, Freeman BD, Paul DR (2017) Analysis of the transport properties of thermally rearranged (TR) polymers and polymers of intrinsic microporosity (PIM) relative to upper bound performance. J Membr Sci 525:18CrossRef
16.
Wang S, Li X, Wu H, Tian Z, Xin Q, He G, Peng D, Chen S, Yin Y, Jiang Z, Guive MD (1863) Advances in high permeability polymer-based membrane materials for CO2 separations. Energy Environ Sci 2016:9
17.
Kim S, Lee YM (2015) Rigid and microporous polymers for gas separation membranes. Prog Polym Sci 43:1CrossRef
18.
Kalantari K, Moradihamedani P, Ibrahim NA, Halim Bin Abdullah A, Binti Muhammad Afifi A (2018) Polysulfone mixed-matrix membrane incorporating talc clay particles for gas separation. Polym Bull 75:3723CrossRef
19.
20.
Bastani D, Esmaeili N, Asadollahi M (2013) Polymeric mixed matrix membranes containing zeolites as a filler for gas separation applications: a review. J Ind Eng Chem 19:375CrossRef
21.
Olivieri L, Ligi S, De Angelis MG, Cucca G, Pettinau A (2015) Effect of graphene and graphene oxide nanoplatelets on the gas permselectivity and aging behavior of poly(trimethylsilyl propyne) (PTMSP). Ind Eng Chem Res 54:11199CrossRef
22.
Dilshad MR, Islam A, Sabir A, Shafiq M, Butt MTZ, Ijaz A, Jamil T (2017) Fabrication and performance characterization of novel zinc oxide filled cross-linked PVA/PEG 600 blended membranes for CO2/N2 separation. J Ind Eng Chem 55:65CrossRef
23.
Mondal A, Mandal B (2014) Novel CO2-selective cross-linked poly(vinyl alcohol)/polyvinylpyrrolidone blend membrane containing amine carrier for CO2–N2 separation: synthesis, characterization, and gas permeation study. Ind Eng Chem Res 53:19736CrossRef
24.
Mondal A, Mandal B (2014) CO2 separation using thermally stable crosslinked poly(vinyl alcohol) membrane blended with polyvinylpyrrolidone/polyethyleneimine/tetraethylenepentamine. J Membr Sci 460:126CrossRef
25.
Saeed M, Rafiq S, Bergersen LH, Deng L (2017) Tailoring of water swollen PVA membrane for hosting carriers in CO2 facilitated transport membranes. Sep Purif Technol 179:550CrossRef
26.
Kurşun F, Işıklan N (2016) Development of thermo-responsive poly(vinyl alcohol)-g-poly(N-isopropylacrylamide) copolymeric membranes for separation of isopropyl alcohol/water mixtures via pervaporation. J Ind Eng Chem 41:91CrossRef
27.
Jahan Z, Niazi MBK, Gregersen W (2018) Mechanical, thermal and swelling properties of cellulose nanocrystals/PVA nanocomposites membranes. J Ind Eng Chem 57:113CrossRef
28.
Niazi MBK, Jahan Z, Berg SS, Gregersen ØW (2017) Mechanical, thermal and swelling properties of phosphorylated nanocellulose fibrils/PVA nanocomposite membranes. Carbohydr Polym 177:258CrossRef
29.
Zamani-Pedram M, Omidkhah M, Ebadi-Amooghin A (2014) Synthesis and characterization of diethanolamine-impregnated cross-linked polyvinylalcohol/glutaraldehyde membranes for CO2/CH4 separation. J Ind Eng Chem 20:74CrossRef
30.
Xing R, Ho WSW (2009) Synthesis and characterization of crosslinked polyvinylalcohol/polyethyleneglycol blend membranes for CO2/CH4 separation. J Taiwan Inst Chem Eng 40:654CrossRef
31.
Deng L, Hägg MB (2014) Carbon nanotube reinforced PVAm/PVA blend FSC nanocomposite membrane for CO2/CH4 separation. Int J Greenh Gas Control 26:127CrossRef
32.
Ebrahimi S, Mollaiy-Berneti S, Asadi H, Peydayesh M, Akhlaghian F, Mohammadi T (2016) PVA/PES-amine-functional graphene oxide mixed matrix membranes for CO2/CH4 separation: experimental and modeling. Chem Eng Res Des 109:647CrossRef
33.
Mittal G, Dhand V, Rhee KY, Park SJ, Lee WR (2015) A review on carbon nanotubes and graphene as fillers in reinforced polymer nanocomposites. J Ind Eng Chem 21:11CrossRef
34.
Dizaji AK, Mortaheb HR, Mokhtarani B, Rahmani S (2017) Pervaporative performance of polydimethylsiloxane–graphene/polyethersolfune hybrid membrane: effects of graphene structure and surface properties. Chem Eng Res Des 124:181CrossRef
35.
Huang K, Liu G, Shen J, Chu Z, Zhou H, Gu X, Jin W, Xu N (2015) High-efficiency water-transport channels using the synergistic effect of a hydrophilic polymer and graphene oxide laminates. Adv Funct Mater 25:5809CrossRef
36.
Krishna R (2018) The Maxwell–Stefan description of mixture permeation across nanoporous graphene membranes. Chem Eng Res Des 133:316CrossRef
37.
Surudžić R, Jankovic A, Mitric M, Matić I, Juranic ZD, Živković L, Miskovic-Stankovic V, Rhee KY, Park SJ, Hui D (2016) The effect of graphene loading on mechanical, thermal and biological properties of poly(vinyl alcohol)/graphene nanocomposites. J Ind Eng Chem 34:250CrossRef
38.
Shen Y, Wang H, Liu J, Zhang Y (1819) Enhanced performance of a novel polyvinyl amine/chitosan/graphene oxide mixed matrix membrane for CO2 capture. ACS Sustain Chem Eng 2015:3
39.
Feijani EA, Tavassoli A, Mahdavi H, Molavi H (2018) Effective gas separation through graphene oxide containing mixed matrix membranes. J Appl Polym Sci 135:46271CrossRef
40.
Li X, Cheng Y, Zhang H, Wang S, Jiang Z, Guo R, Wu H (2015) Efficient CO2 capture by functionalized graphene oxide nanosheets as fillers to fabricate multi-permselective mixed matrix membranes. ACS Appl Mater Interfaces 7:5528CrossRef
41.
Baldino L, Sarno M, Cardea S, Irusta S, Ciambelli P, Santamaria J, Reverchon E (2015) Formation of cellulose acetate-graphene oxide nanocomposites by supercritical CO2 assisted phase inversion. Ind Eng Chem Res 54:8147CrossRef
42.
Nigiz FU, Dogan H, Hilmioglu ND (2012) Pervaporation of ethanol/water mixtures using clinoptilolite and 4A filled sodium alginate membranes. Desalination 300:42CrossRef
43.
Bao C, Guo Y, Song L, Hu Y (2011) Poly(vinyl alcohol) nanocomposites based on graphene and graphite oxide: a comparative investigation of property and mechanism. J Mater Chem 21:13942CrossRef
44.
Thayumanavan N, Tambe P, Joshi G, Shukla M (2014) Effect of sodium alginate modification of graphene (by anion- π type of interaction) on the mechanical and thermal properties of polyvinyl alcohol (PVA) nanocomposites. Compos Interfaces 21:487CrossRef
45.
Ma J, Li Y, Yin X, Xu Y, Yue J, Bao J, Zhou T (2016) Poly(vinyl alcohol)/graphene oxide nanocomposites prepared by in situ polymerization with enhanced mechanical properties and water vapor barrier properties. RSC Adv 6:49448CrossRef
46.
Feng H, Li Y, Li J (2012) Strong reduced graphene oxide–polymer composites: hydrogels and wires. RSC Adv 2:6988CrossRef
47.
Liang J, Zhang L, Wang Y, Ma Y, Guo T, Chen Y (2009) Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites. Adv Funct Mater 19:2297CrossRef
48.
Ismail Z, Abdullah AH, Zainal Abidin AS, Yusoh K (2017) Application of graphene from exfoliation in kitchen mixer allows mechanical reinforcement of PVA/graphene film. Appl Nanosci 7:317CrossRef
49.
Stipniece L, Salma-Ancane K, Rjabovs V, Juhnevica I, Turks M, Narkevica I, Berzina-Cimdina L (2016) Development of functionalized hydroxyapatite/poly(vinyl alcohol) composites. J Cryst Growth 444:14CrossRef
50.
Shehata N, Madi N, Al-Maadeed M, Hassounah I, Ashraf A (2015) Improved electrical conductivity of carbon/polyvinyl alcohol electrospun nanofibers. J Nanomater August, Paper ID: 812481:1
51.
Diouri N, Baitoul M (2014) Effect of carbon nanotubes dispersion on morphology, internal structure and thermal stability of electrospun poly(vinyl alcohol)/carbon nanotubes nanofibers. Opt Quantum Electron 46:259CrossRef
52.
May P, Khan U, O’Neill A, Coleman JN (2012) Approaching the theoretical limit for reinforcing polymers with graphene. J Mater Chem 22:1278CrossRef
53.
Peng D, Wang S, Tian Z, Wu X, Wu Y, Wu H, Xin Q, Chen J, Cao X, Jiang Z (2017) Facilitated transport membranes by incorporating graphene nanosheets with high zinc ion loading for enhanced CO2 separation. J Membr Sci 522:351CrossRef
54.
Li X, Jiang Z, Wu Y, Zhang H, Cheng Y, Guo R, Wu H (2015) High-performance composite membranes incorporated with carboxylic acid nanogels for CO2 separation. J Membr Sci 495:72CrossRef
55.
Ismail AF, Yaacob N (2006) Performance of treated and untreated asymmetric polysulfone hollow fiber membrane in series and cascade module configurations for CO2/CH4 gas separation system. J Membr Sci 275:151CrossRef
56.
Sridhar S, Suryamurali R, Smitha B, Aminabhavi T (2007) Development of crosslinked poly (ether-block-amide) membrane for CO2/CH4 separation. Colloid Surf A Physicochem Eng Asp 297:267CrossRef
Metadata
Title
Synthesis and characterization of graphene nanoplate-incorporated PVA mixed matrix membrane for improved separation of CO2
Author
Filiz Ugur Nigiz
Publication date
27-06-2019
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 5/2020
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02851-7

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