Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 9/2010

01-12-2010 | Original paper

Synthesis and metal ion uptake properties of water-insoluble functional copolymers: removal of metal ions with environmental impact

Authors: Bernabé L. Rivas, Iván M. Perič, Sandra Villegas

Published in: Polymer Bulletin | Issue 9/2010

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

New adsorbents, poly(N-(3-dimethylamino)propylmethacrylamide-co-acrylic acid), P(NDAPA-AA), poly(N-(3-dimethylamino)propylmethacrylamide-co-4-acryloylmorpholine), P(NDAPA-AMo), and poly(N-(3-dimethylamino)propylmethacrylamide-co-2-acrylamidoglycolic acid), P(NDAPA-AAg) were obtained by radical polymerization and characterized by Fourier transform infrared spectroscopy and thermogravimetry. The uptake metal ion properties of cadmium(II), zinc(II), lead(II), mercury(II), and chromium(III) were examined by batch-equilibrium technique with respect to the initial pH, temperature, and initial metal ion concentration under competitive and noncompetitive conditions. Maximum adsorption capacity was determined. Acid and basic regeneration was tested in order to restore the adsorbent to initial conditions. Resins P(NDAPA-AA) and P(NDAPA-AMo) showed a great ability to retain Cr(III), whereas P(NDAPA-co-AAg) to retain Hg(II).
previous article Synthesis and characterization of side-chain poly(methacrylate)s bearing new azo-moieties
next article Preparation of PP-g-PEG by using partial pre-irradiated polypropylene as initiator and its properties

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Nriagu JO, Pacyna JM (1988) Quantitaive assessment of worldwide contamination of air, water and soils by trace-metals. Nature 333:134–139CrossRef
2.
Bayramoglu G, Arica MY (2005) Ethylenediamine grafted poly(glycidylmethacrylate-co-methylmethacrylate) adsorbent for removal of chromate anions. Sep Purif Technol 45:192–199CrossRef
3.
Lee MS, Ahn JG, Ahn JW (2005) A novel amine-shielded surface cross-linking of chitosan hydrogel beads for enhanced metal adsorption performance. Ind Eng Chem Res 44:6692–6700CrossRef
4.
Starvin AM, Prasada Rao T (2004) Removal and recovery of mercury(II) from hazardous wastes using 1-(2-thiazolylazo)-2-naphtol functionalized activated carbon as solid phase extractant. J Hazard Mater 113:75–79CrossRef
5.
Chandra D, Yokoi T, Tatsumi T, Bhaumik A (2007) Highly luminescent organic-inorganic hybrid mesoporous silicas containing tunable chemosensor inside the pore wall. Chem Mater 19:5347–5354CrossRef
6.
Chandra D, Kumar Das S, Bhaumik A (2010) A fluorophore grafted 2D-hexagonal mesoporous organosilica: excellent ion exchanger for the removal of heavy metal ions from wastewater. Micropor Mesopor Mater 128:34CrossRef
7.
Jing X, Liu F, Yang X, Ling P, Li L, Long C, Li A (2009) Adsorption performances and mechanisms of the newly synthesized N,N'-di(carboymethyl)dithiocarbamate chelating resin toward divalent heavy metal ions from aqueous media. J Hazard Mater 167:589–596CrossRef
8.
Moyers EM, Fritz JS (1976) Separation of metal ions using a hexylthioglycolate resin. Anal Chem 48:1117–1120CrossRef
9.
Chen YY, Chen XW (1988) Synthesis of functional resins containing heterocyclic rings and their sorption properties for noble metal ions. J Macromol Sci Chem A25:1443–1454CrossRef
10.
Polakovicova J, Medved J, Stresko V, Kubokova J, Celkova A (1996) Spectrographic determination of gold in geological material after preconcentration on spheron thiol. Anal Chim Acta 320:145CrossRef
11.
Shah R, Devi S (1998) Chelating resin containing s-bonded dithizone for the separation of copper(II), nickel(II) and zinc(II). Talanta 45:1089–1096CrossRef
12.
Ji C, Qu R, Sun C, Wang C, Xu Q, Sun Y, Li C, Guo S (2007) Macroporous chelating resins incorporating heterocyclic functional groups via hydrophilic PEG spacer arms. I. Synthesis and characterization. J Appl Polym Sci 103:3220–3227CrossRef
13.
Kavakli C, Malci S, Tuncel SA, Salih B (2006) Selective adsorption and recovery of precious metal ions from geological samples by 1,5,9,13-tetrathiacyclohexadecane-3,11-diol anchored poly(p-CMS-DVB) microbeds. React Funct Polym 66:275CrossRef
14.
Drutsa R, Gutsanu V, Rusu V (2006) Sorption of CMID-containing cations on strongly basic anion exchangers. J Appl Polym Sci 102:3978–3982CrossRef
15.
Sun C, Qu R, Ji C, Wang Q, Wang C, Sun Y, Cheng GA (2006) A chelating resin containing S, N and O atoms: synthesis and adsorption properties for Hg(II). Eur Polym J 42:188–194
16.
Dinu MV, Dragan ES (2008) Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters. React Funct Polym 68:1346–1354CrossRef
17.
Zhang Y, Qu R, Sun C, Chen H, Wang C, Ji C, Yin P, Sun Y, Zhang H, Niu Y (2009) Comparison of synthesis of chelating resin silica-gel-supported diethylenetriamine and its removal properties for transition metal ions. J Hazard Mater 163:127–135CrossRef
18.
Dinu MV, Dragan ES, Trochimczuk AW (2009) Sorption of Pb(II), Cd(II) and Zn(II) by iminodiacetate chelating resins in non-competitive and competitive conditions. Desalination 249:374–379CrossRef
19.
Rivas BL, Villegas S, Ruf B, Perič IM (2007) Removal of metal ions with impact on the environment by water-insoluble functional copolymers: synthesis and metal ion uptake properties. J Chil Chem Soc 52:1164–1168
20.
Rivas BL, Muñoz C (2007) Removal of environmentally impacting metal ions using functional resin poly(4-styrene sulfonate-co-4-vinylpyridine): synthesis and metal ion retention properties. J Appl Polym Sci 104:1769–1774CrossRef
21.
Rivas BL, Villegas S (2004) Water-insoluble polymers with ability to remove metal ions. J Appl Polym Sci 91:3679–3685CrossRef
22.
Rivas BL, Muñoz C (2009) Synthesis and metal ion adsorption properties of poly(4-sodium styrene sulfonate-co-acrylic acid) resin. J Appl Polym Sci 114:1587–1592CrossRef
23.
Silverstein RM, Webster FX, Kiemle David (2005) Spectrometric identification of organic compounds, 7th edn. Wiley, New York, pp 120–124
24.
Elliot HA, Huang CP (1981) Adsorption characteristics of some Cu(II) complexes on aluminosilicates. Water Res 15:849–855CrossRef
25.
Bullock JI, Tuck DG (1965) Some oxyanion complexes of mercury(II). J Chem Soc 1877
26.
Dogan M, Turhan Y, Alkan M, Namli H, Turan P, Demirbas O (2008) Functionalized sepiolite for heavy metal ions adsorption. Desalination 230:248–268CrossRef
Metadata
Title
Synthesis and metal ion uptake properties of water-insoluble functional copolymers: removal of metal ions with environmental impact
Authors
Bernabé L. Rivas
Iván M. Perič
Sandra Villegas
Publication date
01-12-2010
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 9/2010
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0304-z

Other articles of this Issue 9/2010

Polymer Bulletin 9/2010 Go to the issue

Original Paper

Sonochemical synthesis of polymethylmethacrylate to be used as biomaterial

Original Paper

Synthesis and characterization of star-shaped block copolymers with polyhedral oligomeric silsesquioxane (POSS)core via ATRP

Original Paper

Thermally decomposable phosphonate ester polymer gels

Original Paper

Synthesis and characterization of star-shaped poly(d,l-lactide)-block-poly(ethylene glycol) copolymers

Original Paper

Adsorption of cationic dye on N,O-carboxymethyl-chitosan from aqueous solutions: equilibrium, kinetics, and adsorption mechanism

Original Paper

Esterification of cellulose with acyl-1H-benzotriazole

Premium Partners

    Image Credits