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Polymer Science, Series C
Published in: Polymer Science, Series C 1/2019

01-09-2019

Synthesis, Molecular, and Gas-Transport Properties of Homopolymers Based on 5-Ethylidene-2-norbornene and 5-Vinyl-2-norbornene

Authors: E. V. Bermesheva, A. I. Wozniak, I. L. Borisov, N. P. Yevlampieva, O. S. Vezo, G. O. Karpov, M. V. Bermeshev, A. F. Asachenko, M. A. Topchiy, P. S. Gribanov, M. S. Nechaev, V. V. Volkov, E. Sh. Finkelshtein

Published in: Polymer Science, Series C | Issue 1/2019

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Abstract—

Using the commercial derivative of norbornene—5-ethylidene-2-norbornene—a series of three isomeric homopolymers with different structure of the backbone is synthesized, and the effect of the chain structure on the gas-transport behavior of polynorbornenes is studied. The gas-transport characteristics of the polymers are presented together with data on the conformation properties of molecules of addition and metathesis polynorbornenes. The effect of the structure of side substituents on the equilibrium rigidity of addition polynorbornenes is confirmed by the example of poly(5-ethylidene-2-norbornene) and poly(5-vinyl-2-norbornene).
previous article Synthesis, Structure and Properties of Poly(1-trimethylsilyl-1-propyne) Obtained with NbBr5- and TaBr5-Based Catalytic Systems
next article Stereoselective synthesis and metathesis polymerization of exo-5-(Pentamethyldisiloxanyl) norbornene

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Footnotes
1
Static light scattering and refractive index increments were measured using equipment of the Resource Center for Diagnostics of Functional Materials for Medicine, Pharmacology, and Nanoelectronics, St. Petersburg State University.
 
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Metadata
Title
Synthesis, Molecular, and Gas-Transport Properties of Homopolymers Based on 5-Ethylidene-2-norbornene and 5-Vinyl-2-norbornene
Authors
E. V. Bermesheva
A. I. Wozniak
I. L. Borisov
N. P. Yevlampieva
O. S. Vezo
G. O. Karpov
M. V. Bermeshev
A. F. Asachenko
M. A. Topchiy
P. S. Gribanov
M. S. Nechaev
V. V. Volkov
E. Sh. Finkelshtein
Publication date
01-09-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series C / Issue 1/2019
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI
https://doi.org/10.1134/S181123821901003X

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