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Journal of Materials Science

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18-02-2016 | Original Paper

Synthesis of monodisperse poly(styrene-co-divinylbenzene) microspheres with binary porous structures and application in high-performance liquid chromatography

Authors: Bing Yu, Chao Tian, Hailin Cong, Tao Xu

Published in: Journal of Materials Science | Issue 11/2016

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Abstract

Monodisperse poly(styrene-co-divinylbenzene) (PS-DVB) microspheres with binary porous structures were synthesized using a modified seeded polymerization method. The microspheres had small pores on the surface and big pores in the middle. Using the binary porous PS-DVB (BPPSD) microspheres as packing materials for high-performance liquid chromatography, several benzene analogs were effectively separated in a column as short as 75 mm due to the high surface areas of the stationary phase. Because of the π–π affinity interaction between BPPSD particles and analytes, the separation performance of the BPPSD column was better than commercialized C₁₈ column at the same conditions. Compared to column filled with non-porous PS-DVB particles, the back pressure of BPPSD column could be maintained at especially low level even at high flow rates due to the excellent permeability of the fillers. In addition, approximate baseline separation of C₆₀ and C₇₀ was also achieved in the 75 mm BPPSD column.

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Title: Synthesis of monodisperse poly(styrene-co-divinylbenzene) microspheres with binary porous structures and application in high-performance liquid chromatography
Authors: Bing Yu
Chao Tian
Hailin Cong
Tao Xu
Publication date: 18-02-2016
Publisher: Springer US
Published in: Journal of Materials Science / Issue 11/2016
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-9826-6

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