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Journal of Materials Science
Erschienen in: Journal of Materials Science 11/2016

18.02.2016 | Original Paper

Synthesis of monodisperse poly(styrene-co-divinylbenzene) microspheres with binary porous structures and application in high-performance liquid chromatography

verfasst von: Bing Yu, Chao Tian, Hailin Cong, Tao Xu

Erschienen in: Journal of Materials Science | Ausgabe 11/2016

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Abstract

Monodisperse poly(styrene-co-divinylbenzene) (PS-DVB) microspheres with binary porous structures were synthesized using a modified seeded polymerization method. The microspheres had small pores on the surface and big pores in the middle. Using the binary porous PS-DVB (BPPSD) microspheres as packing materials for high-performance liquid chromatography, several benzene analogs were effectively separated in a column as short as 75 mm due to the high surface areas of the stationary phase. Because of the π–π affinity interaction between BPPSD particles and analytes, the separation performance of the BPPSD column was better than commercialized C18 column at the same conditions. Compared to column filled with non-porous PS-DVB particles, the back pressure of BPPSD column could be maintained at especially low level even at high flow rates due to the excellent permeability of the fillers. In addition, approximate baseline separation of C60 and C70 was also achieved in the 75 mm BPPSD column.
Vorheriger Artikel Compressive mechanical property of porous magnesium composites reinforced by carbon nanotubes
Nächster Artikel Synthesis of type-II CdSe(S)/Fe2O3 core/shell quantum dots: the effect of shell on the properties of core/shell quantum dots

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Metadaten
Titel
Synthesis of monodisperse poly(styrene-co-divinylbenzene) microspheres with binary porous structures and application in high-performance liquid chromatography
verfasst von
Bing Yu
Chao Tian
Hailin Cong
Tao Xu
Publikationsdatum
18.02.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9826-6

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