Top

Cellulose

Published in:

01-08-2019 | Original Research

Synthesis of Ru nanoparticles with hydroxyethyl cellulose as stabilizer for high-efficiency reduction of α-pinene

Authors: Congxia Xie, Li Qu, Hailong Yu, Fengli Yu, Bing Yuan, Shitao Yu, Shuangxi Nie

Published in: Cellulose | Issue 13-14/2019

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Ruthenium (Ru) nanoparticles synthesized using hydroxyethyl cellulose (HEC-Ru) were used to hydrogenate α-pinene in an aqueous medium. The results showed that HEC had a good dispersion effect on Ru nanoparticles and most of the particle sizes were ranged from 4 to 6 nm. The micelles formed with HEC appeared to act as “microreactors” in which the Ru nanoparticles had good stability and uniform distribution. In addition, α-pinene was loaded into the HEC micelles through hydrophobic interaction, resulting in good contact with Ru nanoparticles. Thereby, HEC-Ru nanoparticles significantly improved the hydrogenation of α-pinene, and 99.6% of α-pinene conversion and 98.6% of cis-pinane selectivity were obtained. Compared with the Pd/C, Ru/H₂O, and HEC-Ru/ethanol catalyst systems, the HEC-Ru/H₂O system had the maximum α-pinene conversion. In addition, considerable α-pinene conversion could be obtained after 10 times reuse with no fresh addition.

Graphic abstract

previous article Utilization of deep eutectic solvent as a degumming protocol for Apocynum venetum bast

next article Procion Blue H-5R functionalized cellulose membrane with specific removal of bilirubin

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

An X, Long Y, Ni Y (2017) Cellulose nanocrystal/hexadecyltrimethylammonium bromide/silver nanoparticle composite as a catalyst for reduction of 4-nitrophenol. Carbohydr Polym 156:253–258CrossRefPubMed

Cao A, Lu R, Veser G (2010) Stabilizing metal nanoparticles for heterogeneous catalysis. Phys Chem Chem Phys 12(41):13499–13510CrossRefPubMed

Capek I (2004) Preparation of metal nanoparticles in water-in-oil (w/o) microemulsions. Adv Coll Interface Sci 110(1):49–74CrossRef

Deliy IV, Simakova IL (2008) Catalytic activity of the VIII Group metals in the hydrogenation and isomerization of α- and β-pinenes. Russ Chem Bull 57(10):2056–2064CrossRef

Emam HE, Ahmed HB (2016) Polysaccharides templates for assembly of nanosilver. Carbohydr Polym 135:300–307CrossRefPubMed

Gorgieva S, Kokol V (2011) Synthesis and application of new temperature-responsive hydrogels based on carboxymethyl and hydroxyethyl cellulose derivatives for the functional finishing of cotton knitwear. Carbohydr Polym 85(3):664–673CrossRef

Hebeish A, El-Naggar ME, Fouda MMG, Ramadan MA, Al-Deyab SS, El-Rafie MH (2011) Highly effective antibacterial textiles containing green synthesized silver nanoparticles. Carbohydr Polym 86(2):936–940CrossRef

Hebeish A, Farag S, Sharaf S, Shaheen TI (2014) Development of cellulose nanowhisker-polyacrylamide copolymer as a highly functional precursor in the synthesis of nanometal particles for conductive textiles. Cellulose 21(4):3055–3071CrossRef

Hussain MA, Shah A, Jantan I, Shah MR, Tahir MN, Ahmad R, Bukhari SN (2015) Hydroxypropylcellulose as a novel green reservoir for the synthesis, stabilization, and storage of silver nanoparticles. Int J Nanomedi 2015(default):2079–2088

James OO, Maity S, Mesubi MA, Ogunniran KO, Siyanbola TO, Sahu S, Chaubey R (2011) Towards reforming technologies for production of hydrogen exclusively from renewable resources. Green Chem 13(9):2272–2284CrossRef

Jilal I, El BS, Bahari Z, Sundman O, El IA, Abou-Salama M et al (2018) New quaternized cellulose based on hydroxyethyl cellulose (HEC) grafted EDTA: synthesis, characterization and application for Pb (II) and Cu (II) removal. Carbohydr Polym 180:156–167CrossRefPubMed

Kiran GS, Sabu A, Selvin J (2010) Synthesis of silver nanoparticles by glycolipid biosurfactant produced from marine Brevibacterium casei MSA19. J Biotechnol 148(4):221–225CrossRefPubMed

Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50(24):5438–5466CrossRef

Li J, Li J, Gao Y, Shang S, Song Z, Xiao G (2016) Take an advantage of sustainable forest resource in agriculture: a value-added application of volatile turpentine analogues as botanical pesticides based on amphipathic modification and QSAR study. ACS Sustain Chem Eng 4(9):4685–4691CrossRef

Liu Y, Li L, Xie C, Yu S, Liu S (2016) Synthesis of magnetic Ru/Fe₃O₄@C nanospheres with controlled carbon layer and its high selectivity to prepare cis-pinane. Chem Eng J 303:31–36CrossRef

Martínez-Prieto LM, Chaudret B (2018) Organometallic ruthenium nanoparticles: synthesis, surface chemistry, and insights into ligand coordination. Acc Chem Res 51(2):376–382CrossRefPubMed

Milewska A, Osuna AMB, Fonseca IM, Ponte MND (2005) Biphasic hydrogenation of alpha-pinene in high-pressure carbon dioxide. Green Chem 7(10):726–732CrossRef

Nehru S, Veeralakshmi S, Arunachalam S (2017) Synthesis, characterisation and self-assembly behaviour of emissive surfactant–ruthenium(II) complexes. New J Chem 41:13830–13837CrossRef

Pinto RJB, Neves MC, Neto CP, Trindade T (2012) Composites of cellulose and metal nanoparticles. Nanocompos New Trends Dev 21(1):395–405

Primo A, Concepción P, Corma A (2011) Synergy between the metal nanoparticles and the support for the hydrogenation of functionalized carboxylic acids to diols on Ru/TiO₂. Chem Commun 47(12):3613–3619CrossRef

Qu L, Yu H, Yu F, Yuan B, Xie C, Yu S (2018) Catalytic reduction of α-pinene using Ru nanoparticles stabilized by modified carboxymethyl cellulose. Appl Surf Sci 453:271–279CrossRef

Rauchdi M, Ali MA, Roucoux A, Denicourt-Nowicki A (2017) Novel access to verbenone via ruthenium nanoparticles-catalyzed oxidation of α-pinene in neat water. Appl Catal A 550:266–273CrossRef

Shi Z, Tang J, Chen L, Yan C, Tanvir S, Anderson WA et al (2014) Enhanced colloidal stability and antibacterial performance of silver nanoparticles/cellulose nanocrystal hybrids. J Mater Chem B 3(4):603–611CrossRef

Sorella GL, Strukul G, Scarso A (2015) Recent advances in catalysis in micellar media. Green Chem 17(2):644–683CrossRef

Tummalapalli M, Deopura BL, Alam MS, Gupta B (2015) Facile and green synthesis of silver nanoparticles using oxidized pectin. Mater Sci Eng C 50:31–39CrossRef

Wang W, Zhang P, Zhang S, Li F, Yu J, Lin J (2013) Structure and properties of novel regenerated cellulose fibers prepared in NaOH complex solution. Carbohydr Polym 98(1):1031–1038CrossRefPubMed

Wang Y, Rong Z, Wang Y, Zhang P, Wang Y, Qu J (2015) Ruthenium nanoparticles loaded on multiwalled carbon nanotubes for liquid-phase hydrogenation of fine chemicals: an exploration of confinement effect. J Catal 329(28):95–106CrossRef

Xie H, Yang SJ, Zhang ZJ (2005) Study on hydrogenation of α-pinene to cis-pinane catalyzed by nanometer nickel. Chem Indus For Prod 25(04):56–58

Xie L, Wang X, Yu F, Yuan B, Xie C, Yu S (2017) Preparation of cis-pinane via α-pinene hydrogenation in water by using Ru nanoparticles immobilized in functionalized amphiphilic mesoporous silica. RSC Adv 7(81):51452–51459CrossRef

Yan N, Yuan Y, Dyson PJ (2011) Rhodium nanoparticle catalysts stabilized with a polymer that enhances stability without compromising activity. Chem Commun 47(9):2529CrossRef

Yang Y, Liu X, Yin D, Zhang Z, Lei D, Yang J (2015) A recyclable Pd colloidal catalyst for liquid phase hydrogenation of α-pinene. J Ind Eng Chem 26:333–334CrossRef

Zhao X, Zhou H, Sikarwar VS, Zhao M, Park AHA, Fennell P et al (2017) Biomass-based chemical looping technologies: the good, the bad and the future. Energy Environ Sci 10:1885–1910CrossRef

Zong-liang H, Xin-bin M, Ping N, Zhen-hua L, Liang-long L, Lin-jiu Z (2002) Study on catalytic hydrogenation of the α-pinene to cis-pinane. Chem Ind Eng 19(237):225–228

Title: Synthesis of Ru nanoparticles with hydroxyethyl cellulose as stabilizer for high-efficiency reduction of α-pinene
Authors: Congxia Xie
Li Qu
Hailong Yu
Fengli Yu
Bing Yuan
Shitao Yu
Shuangxi Nie
Publication date: 01-08-2019
Publisher: Springer Netherlands
Published in: Cellulose / Issue 13-14/2019
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02656-x

Springer Professional

Abstract

Graphic abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 13-14/2019

Surface modification of oriented polysaccharide scaffolds using biotic nanofibers for epidermal cell culture

Viscometric behavior of hydroxyethyl cellulose in aqueous solutions of some imidazolium ionic liquids

Self-supporting three-dimensional carboxymethyl cellulose conductive sponges used as electrodes for lithium-ion batteries

Enhancing the redispersibility of TEMPO-mediated oxidized cellulose nanofibrils in N,N-dimethylformamide by modification with cetyltrimethylammonium bromide

Predicting the cell-wall compositions of solid Pinus radiata (radiata pine) wood using NIR and ATR FTIR spectroscopies

Impact of sonication on the rheological and colloidal properties of highly concentrated cellulose nanocrystal suspensions