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Polymer Bulletin
Published in: Polymer Bulletin 1/2012

01-01-2012 | Original Paper

Synthesis of small-molecule initiators derived from fluorinated acrylates and their application in atom transfer radical polymerization (ATRP)

Authors: Yue Sun, Weiqu Liu

Published in: Polymer Bulletin | Issue 1/2012

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Abstract

The bromo-terminated small-molecule initiator was prepared by the direct addition reaction of 2,2,3,4,4,4-hexafluorobutyl methacrylate (HFMA) or dodecafluoroheptyl methacrylate (DFMA) with hydrobromic acid in acetic acid under mild conditions. This greatly widened the initiators used for atom transfer radical polymerization (ATRP). The successful polymerization of isobutyl methacrylate (IBMA) or methyl methacrylate (MMA) derived from HFMA-Br or DFMA-Br indicated that fluorinated acrylates could be used as initiators for ATRP. The data of GPC showed the well controlling of the initiator system. FTIR and 1H NMR characterized the structures of the initiators and their polymers. Contact angle measurement indicated that although only one molecule of fluorinated acrylate was introduced, the surface properties of polymers were improved greatly.
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Metadata
Title
Synthesis of small-molecule initiators derived from fluorinated acrylates and their application in atom transfer radical polymerization (ATRP)
Authors
Yue Sun
Weiqu Liu
Publication date
01-01-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 1/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0513-0

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