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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 1/2015

01-10-2015 | Original Paper

Synthesis, spectral characterization and crystal structure of a new precursor [(CH3COCHCOCH3)2Zr{C6H4(N=CHC6H4O)2}] for nano-zirconia: an investigation on the wettability of polyvinylidene fluoride–nano-zirconia composite material

Authors: Vuppalapati Giri Prasanth, Gajula Prasad, Tummalapalli Kiran, Ravindranath S. Rathore, Madhvesh Pathak, Kulathu Iyer Sathiyanarayanan

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2015

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Abstract

A new octa-coordinated metallo-organic complex of zirconium (IV) [(CH3COCHCOCH3)2Zr{C6H4(N=CHC6H4O)2}] was synthesized quantitatively by treating Zr(OPri)4·PriOH with CH3COCH2COCH3 and tetradentate Schiff’s base ligand (L) [where L = {C6H4(N=CHC6H4OH)2}] in 1:2:1 stoichiometry in anhydrous refluxing toluene. The yellow solid complex was characterized by elemental analysis, FTIR, UV–visible, fluorescence and NMR (1H and 13C) spectra as well as by single-crystal XRD. The complex was processed to obtain nano-structured zirconia (ZrO2) by sol–gel technique, and oxide ceramic was subjected to powder XRD, TEM and EDX analyses. Further, the same zirconia was employed in preparing superhydrophobic PVDF–nano-ZrO2 composite coatings by spray coating method, and the effect of nano-oxide ceramic on the wettability of PVDF–nano-ZrO2 composite coatings was studied systematically. The composite material was also characterized by FTIR and powder XRD.

Graphical abstract

previous article Enhanced photocatalytic activity of mesoporous SiO2/TiO2 sol–gel coatings doped with Ag nanoparticles
next article Effects of PVA content on the synthesis of Y2NiMnO6 by sol–gel method

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Appendix
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Metadata
Title
Synthesis, spectral characterization and crystal structure of a new precursor [(CH3COCHCOCH3)2Zr{C6H4(N=CHC6H4O)2}] for nano-zirconia: an investigation on the wettability of polyvinylidene fluoride–nano-zirconia composite material
Authors
Vuppalapati Giri Prasanth
Gajula Prasad
Tummalapalli Kiran
Ravindranath S. Rathore
Madhvesh Pathak
Kulathu Iyer Sathiyanarayanan
Publication date
01-10-2015
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 1/2015
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3766-5

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