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Journal of Sol-Gel Science and Technology

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01-07-2021 | Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Synthesis, structural characteristics, and thermal expansion behavior of zirconium phosphate ceramics with d-transition metals

Authors: Irina Glukhova, Elena Asabina, Vladimir Pet’kov, Andrey Kovalsky, Konstantin Pokholok

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2021

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Abstract

The series M_0.5(1+x)Fe_xZr_2−x(PO₄)₃ (M—Ni, Cu, Mn) with Sc₂(WO₄)₃-related structure (SW) were prepared using Pechini technique and characterized by powder X-ray diffraction analysis, SEM, EDX, IR, and Mössbauer spectroscopy. The concentration and temperature limits of solid solution formation were determined, lattice parameters were calculated, and their dependencies on the phosphate’s composition were studied. The crystal structure of the phosphate Mn_0.65Fe_0.3Zr_1.7(PO₄)₃ (x = 0.3) was refined by the Rietveld method basing on the powder X-ray diffraction data. The compound crystallizes in monoclinic symmetry (space group P2₁/n) with lattice parameters: a = 8.7941(12), b = 8.9379(16), c = 12.4353(21) Å, β = 90.126(24)°, V = 977.49(27) Å³. Thermal expansion coefficients of the ceramics Cu_0.5(1+x)Fe_xZr_2−x(PO₄)₃ were determined. The volume expansion coefficients of the compounds vary in the range (4.4–10.8)∙10⁻⁵ K ⁻¹.

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Title: Synthesis, structural characteristics, and thermal expansion behavior of zirconium phosphate ceramics with d-transition metals
Authors: Irina Glukhova
Elena Asabina
Vladimir Pet’kov
Andrey Kovalsky
Konstantin Pokholok
Publication date: 01-07-2021
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 2/2021
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-021-05577-z

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