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Polymer Bulletin

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19-12-2019 | Original Paper

TEMPO-oxidized cellulose nanofibers/TiO₂ nanocomposite as new adsorbent for Brilliant Blue dye removal

Authors: Zehbah Ali Al-Ahmed, Abeer A. Hassan, Sahar M. El-Khouly, Shaymaa E. El-Shafey

Published in: Polymer Bulletin | Issue 12/2020

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Abstract

In this article, TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) prepared from bagasse was described and utilized as a sustainable material for the preparation of new nanocomposites. TiO₂ nanoparticles were synthesized by in situ precipitation in the presence of TEMPO-CNF. The prepared nanocomposite, TEMPO-CNF/TiO₂, was characterized by using FT-IR, XRD, TGA, SEM, and EDX analysis. The results proved that homogenous spherical TiO₂ nanoparticles were formed with the particles of TEMPO-CNF. TEMPO-CNF/TiO₂ nanocomposite was examined as an adsorbent for Brilliant Blue (BB) adsorption. The highest BB removal efficiency was observed at pH 7, the adsorption process is well described by pseudo-second-order and Langmuir adsorption model, and the maximum adsorption capacity is 162 mg/g. Our results proved that the TEMPO-CNF/TiO₂ nanocomposite could be used for the removal of BB from aqueous solutions.

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Title: TEMPO-oxidized cellulose nanofibers/TiO2 nanocomposite as new adsorbent for Brilliant Blue dye removal
Authors: Zehbah Ali Al-Ahmed
Abeer A. Hassan
Sahar M. El-Khouly
Shaymaa E. El-Shafey
Publication date: 19-12-2019
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 12/2020
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-03068-4

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