Top

Journal of Materials Science

Published in:

17-06-2021 | Chemical routes to materials

Tetraphenylporphyrin-modified perovskite nanocrystals enable ratiometric fluorescent determination of sulfide ion in water samples

Authors: Hongbo Wang, Qian Li, Xiaomeng Niu, Jianxiu Du

Published in: Journal of Materials Science | Issue 27/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

A simple and feasible approach was constructed for preparation of all inorganic cesium lead bromide perovskite nanocrystals (CsPbBr₃ NCs) modified with tetraphenylporphyrin tetrasulfonic acid (TPPS). The CsPbBr₃/TPPS nanocomposite has good water stability and exhibits a dual-emission property. Adopting the CsPbBr₃/TPPS nanocomposite as a nanoprobe, a rapid, selective and sensitive ratiometric fluorescent method was developed for determination of sulfide ion. When sulfide ion was added into the CsPbBr₃/TPPS nanocomposite, the bright green fluorescence of CsPbBr₃ NCs at 520 nm was sharply quenched, whereas the red fluorescence of TPPS at 650 nm was hardly influenced. The quenching is possibly attributed to destruction of CsPbBr₃ NCs via the formation of more stable PbS. This nanoprobe can determine sulfide ion over the range of 0.2–15.0 nmol·L⁻¹ with a detection limit as low as 0.05 nmol·L⁻¹. The relative standard deviation is 3.3% at 10.0 nmol·L⁻¹ concentration level (n = 11). Sulfide ion content was successfully determined in different water samples by this nanoprobe.

Graphical abstract

previous article Promotion effect of rare earth elements (Ce, Nd, Pr) on physicochemical properties of M-Al mixed oxides (M = Cu, Ni, Co) and their catalytic activity in N2O decomposition

next article Self-lubricating triboactive (Cr,Al)N+Mo:S coatings for fluid-free applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Akkerman QA, Raino G, Kovalenko MV, Manna L (2018) Genesis, Challenges and opportunities for colloidal lead halide perovskite nanocrystals. Nat Mater 17:394–405. https://doi.org/10.1038/s41563-018-0018-4CrossRef

Zhang Q, Yin YD (2018) All-inorganic metal halide perovskite nanocrystals: Opportunities and challenges. ACS Central Sci 4:668–679. https://doi.org/10.1021/acscentsci.8b00201CrossRef

Cheng X, Yang S, Cao BQ, Tao XT, Chen ZL (2019) Single crystal perovskite solar cells: development and perspectives. Adv Funct Mater 30:1905021. https://doi.org/10.1002/adfm.201905021CrossRef

Zhang Q, Su R, Du WN, Liu XF, Zhao LY, Ha ST, Xiong QH (2017) Advances in small perovskite-based lasers. Small Methods 1:1700163. https://doi.org/10.1002/smtd.201700163CrossRef

Ashar AZ, Ganesh N, Narayan KS (2018) Hybrid perovskite-based position-sensitive detectors. Adv Electron Mater 4:1700362. https://doi.org/10.1002/aelm.201700362CrossRef

Chiba T, Kido J (2018) Lead halide perovskite quantum dots for light-emitting devices. J Mater Chem C 6:11868–11877. https://doi.org/10.1039/c8tc03561jCrossRef

George KJ, Halali VV, Sanjayan CG, Suvina V, Sakar M, Balakrishna RG (2020) Perovskite nanomaterials as optical and electrochemical sensors. Inorg Chem Front 7:2702–2725. https://doi.org/10.1039/d0qi00306aCrossRef

Shellaiah M, Sun KW (2020) Review on sensing applications of perovskite nanomaterials. Chemosensors 8:55. https://doi.org/10.3390/chemosensors8030055CrossRef

Huang YP, Wang SY, Zhu YM, Li FM, Jin JW, Dong J, Lin FY, Wang YR, Chen X (2020) Dual-mode of fluorescence turn-on and wavelength-shift for methylamine gas sensing based on space-confined growth of methylammonium lead tribromide perovskite nanocrystals. Anal Chem 92:5661–5665. https://doi.org/10.1021/acs.analchem.0c00698CrossRef

10.

Yin W, Li H, Chesman ASR, Tadgell B, Senlly AD, Wang M, Huang W, McNeill CP, Wong WH, Medhekar MP, Jasieniak JJ (2021) Detection of halomethanes using cesium lead halide perovskite nanocrystals. ACS Nano 15:1454–1464. https://doi.org/10.1021/acsnano.0c08794CrossRef

11.

Li Q, Wang HB, Yue XF, Du JX (2020) Perovskite nanocrystals fluorescence nanosensor for ultrasensitive detection of trace melamine in dairy products by the manipulation of inner filter effect of gold nanoparticles. Talanta 211:12075. https://doi.org/10.1016/j.talanta.2019.120705CrossRef

12.

Park SH, Kwon N, Lee JH, Yoon J, Shin I (2020) Synthetic ratiometric fluorescent probes for detection of ions. Chem Soc Rev 49:143–179. https://doi.org/10.1039/c9cs00243jCrossRef

13.

Bigdeli A, Ghasemi F, Abbasi-Moayed S, Shahrajabian M, Fahimi-Kashani N, Jafarinejad S, Nejad MAF, Hormozi-Nezhad MR (2019) Ratiometric fluorescent nanoprobes for visual detection: design principles and recent advances-A review. Anal Chim Acta 1079:30–58. https://doi.org/10.1016/j.aca.2019.06.035CrossRef

14.

Habeeb OA, Kanthasamy R, Ali GAM, Sethupathi S, Yunus RB (2018) Hydrogen sulfide emission sources, regulations, and removal techniques: a review. Rev Chem Eng 34:837–854. https://doi.org/10.1515/revce-2017-0004CrossRef

15.

Stein A, Bailey SM (2013) Redox biology of hydrogen sulfide: Implications for physiology, pathophysiology, and pharmacology. Redox Biol 1:32–39. https://doi.org/10.1016/j.redox.2012.11.006CrossRef

16.

Wang X, Feng SY, He DP, Jiang P (2020) Porous manganese-cobalt oxide microspheres with tunable oxidase mimicking activity for sulfide ion colorimetric detection. Chem Commun 56:14098–14101. https://doi.org/10.1039/d0cc06209jCrossRef

17.

Kubendhiran S, Rajkumar C, Chen SM, Yeah QJ, Thirumalraj B (2018) Charge based electrochemical determination of sulfide ions in water samples using poly-L-lysine modified electrode. J Electrochem Soc 165:B268–B274. https://doi.org/10.1149/2.0241807jesCrossRef

18.

Zgagacz W, Zakrzewski R, Urbaniak K, Chwatko G, Nowicki A (2020) The use of high-performance liquid chromatography with diode array detector for the determination of sulfide ions in human urine samples using pyrylium salts. J Chromatogr B 1157:122309. https://doi.org/10.1016/j.jchromb.2020.122309CrossRef

19.

Leal VG, Batista AD, Petruci JFD (2021) 3D-printed and fully portable fluorescent-based platform for sulfide determination in waters combing vapor generation extraction and digital images treatment. Talanta 222:121558. https://doi.org/10.1016/j.talanta.2020.121558CrossRef

20.

Sinduja B, John SA (2019) Silver nanoparticles capped with carbon dots as a fluorescent probe for the highly sensitive “off-on” sensing of sulfide ions in water. Anal Bioanal Chem 411:12. https://doi.org/10.1007/s00216-019-01697-2CrossRef

21.

Liu JS, Bao HJ, Ma DL, Leung CH (2019) Silver nanoclusters functionalized with Ce(III) ions are a viable “turn-on-off” fluorescent probe for sulfide. Microchim Acta 186:16. https://doi.org/10.1007/s00604-018-3149-zCrossRef

22.

Sammi H, Kukkar D, Singh J, Kukkar P, Kaur R, Rawat M, Singh G, Kim KH (2018) Serendipity in solution-GQDs zeolitic imidazole frameworks nanocomposites for highly sensitive detection of sulfide ions. Sensor Actuat B-Chem 255:3047–3056. https://doi.org/10.1016/j.snb.2017.09.129CrossRef

23.

Chen CQ, Cai Q, Luo F, Dong N, Guo LH, Qiu B, Lin ZY (2019) Sensitive fluorescent sensor for hydrogen sulfide in rat brain microdialysis via CsPbBr₃ quantum dots. Anal Chem 91:15915–15921. https://doi.org/10.1021/acs.analchem.9b04387CrossRef

24.

Li Z, Hu QS, Tan ZF, Yang Y, Leng MY, Liu XL, Ge C, Niu GD, Tang J (2018) Aqueous synthesis of lead halide perovskite nanocrystals with high water stability and bright photoluminescence. ACS Appl Mater Interfaces 10:43915–43922. https://doi.org/10.1021/acsami.8b16471CrossRef

25.

Guo YX, Lin RY, Jiao Z, Qian WS, Liu SC, Ou YH (2011) Inorganic chemicals for industrial use. Preparation of standard and reagent solutions for chemical analysis. Part 2: Preparations of standard solutions for impurity. HG/T3696.2–2011.

26.

Jiang MW, Hu ZH, Liu ZH, Wu ZF, Ono LK, Qi YB (2019) Engineering green-to-blue emitting CsPbBr₃ quantum-dot films with efficient ligand passivation. ACS Energy Lett 4:2731–2738. https://doi.org/10.1021/acsenergylett.9b02032CrossRef

27.

Gao YF, Liu M, Yue XF, Du JX (2019) Ratiometric fluorometric determination ofmercury(II) by exploiting its quenching effect on glutathione-stabilized and tetraphenylporphyrin modified gold nanoclusters. Microchim Acta 186:5. https://doi.org/10.1007/s00604-019-3405-xCrossRef

28.

Chang JH, Dong QG (2012) Spectral principles and analysis, 3rd edn. Science Press, Beijing, p 81

29.

Peng D, Zhang L, Liang RP, Qiu JD (2018) Rapid detection of mercury ions based on nitrogen-doped grapheme quantum dots accelerating formation of manganeseporphyrin. ACS Sens 3:1040–1047. https://doi.org/10.1021/acssensors.8b00203CrossRef

30.

Sun SB, Yuan D, Xu Y, Wang AF, Deng ZT (2016) Ligand-mediated synthesis of shape-controlled cesium lead halide perovskite nanocrystals via reprecipitation process at room temperature. ACS Nano 10:3648–3657. https://doi.org/10.1021/acsnano.5b08193CrossRef

31.

Liang ZQ, Zhao SL, Xu Z, Qiao B, Song PJ, Gao D, Xu XR (2016) Shape-controlled synthesis of all-inorganic CsPbBr₃ perovskite nanocrystals with bright blue emission. ACS Appl Mater Interfaces 8:28824–28830. https://doi.org/10.1021/acsami.6b08528CrossRef

32.

Cant DJH, Syres KL, Lunt PJB, Radtke H, Treacy J, Thomas PJ, Lewis EA, Haigh SJ, O’Brien P, Schulte K, Bondino F, Magnano E, Flavell WR (2015) Surface properties of nanocrystalline PbS films deposited at the water-oil interface: A study of atmospheric aging. Langmuir 31:1445–1453. https://doi.org/10.1021/la504779hCrossRef

33.

Swarnkar A, Chulliyil R, Ravi VK, Irfanullah C, Nag A (2015) Colloidal CsPbB₃ perovskite nanocrystals: Luminescence beyond traditional quantum dots. Angew Chem Int Ed 54:15424–15428. https://doi.org/10.1002/anie.201508276CrossRef

34.

Ni PJ, Chen CX, Jiang YY, Zhao ZL, Lu YZ (2018) Fluorometric determination of sulfides ions via its inhibitory effect on the oxidation of thiamine by Cu(II) ions. Mircrohim Acta 185:8. https://doi.org/10.1007/s00604-018-2906-3CrossRef

35.

Lin GH, Lewandowska M (2019) Plasmon-enhanced fluorescence provided by silver nanoprisms for sensitive detection of sulfide. Sens Actuat B Chem 292:241–246. https://doi.org/10.1016/j.snb.2019.04.054CrossRef

36.

Wen ZQ, Song SL, Hu TT, Wang CX, Qu FD, Wang P, Yang MH (2019) A dual emission nanocomposite prepared from copper nanoclusters and carbon dots as a ratiometric fluorescent probe for sulfide and gaseous H₂S. Microchim Acta 258:186. https://doi.org/10.1007/s00604-019-3295-yCrossRef

Title: Tetraphenylporphyrin-modified perovskite nanocrystals enable ratiometric fluorescent determination of sulfide ion in water samples
Authors: Hongbo Wang
Qian Li
Xiaomeng Niu
Jianxiu Du
Publication date: 17-06-2021
Publisher: Springer US
Published in: Journal of Materials Science / Issue 27/2021
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06253-x

Springer Professional

Abstract

Graphical abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 27/2021

Z-scheme Bi2MoO6 nanoplate-decorated flower-like Bi12SiO20 for efficient photocatalytic degradation of organic pollutants

Superamphiphobic triple-scale micro-/nanostructured aluminum surfaces with self-cleaning and anti-icing properties

A review on the direct electroplating of polymeric materials

Effect of silicon and partitioning temperature on the microstructure and mechanical properties of high-carbon steel in a quenching and partitioning heat treatment

Electroactive dielectric polymer gels as new-generation soft actuators: a review

Corrosion and wear resistance of micro-arc oxidation coating on glass microsphere reinforced Mg alloy composite

Premium Partners