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Journal of Materials Science: Materials in Electronics

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24-03-2021

The effect of electrodeposition applied potential on the electrochemical performance of polyaniline films

Authors: Abdelfetteh Sayah, Farid Habelhames, Ahmed Bahloul, Abdelhamid Boudjadi

Published in: Journal of Materials Science: Materials in Electronics | Issue 8/2021

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Abstract

Polyaniline (PANI) has been widely studied and used for the energy storage applications, especially in supercapacitors, this is due to their good pseudocapacitance properties, and it is easy for synthesis. In this study, we describe the effects of the electrodeposition applied potential on the electrochemical performance of polyaniline films. The electrodeposition of PANI films on fluorine-doped tin oxide (FTO) glass substrate is released by chronoamperometry technique using an electrolytic solution containing 0.3 M of aniline in 1 M H₂SO₄ at different applied potentials (i.e., + 0.8 V, + 0.9 V and + 1 V vs. SCE) for 300 sin time. All prepared films are characterized by different techniques scanning electronic microscopy, infrared spectroscopy, thermogravimetric analysis, and electrical conductivity measurement. For the application, the FTO/PANI films are used as material electrode in supercapacitor. The electrochemical performances are evaluated by cyclic voltammetry, galvanostatic charge–discharge tests, and electrochemical impedance spectroscopy. An important increase in specific capacitances is observed at 0.2 A g⁻¹ from 54.8 F g⁻¹ for FTO/PANI 0.8 film to 157.42 F g⁻¹ for FTO/PANI 0.9 and 195.94 F g⁻¹ for FTO/PANI 1.

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Title: The effect of electrodeposition applied potential on the electrochemical performance of polyaniline films
Authors: Abdelfetteh Sayah
Farid Habelhames
Ahmed Bahloul
Abdelhamid Boudjadi
Publication date: 24-03-2021
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 8/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-021-05725-9

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