Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 5/2018

11-04-2018

The Effect of Mo Particles Addition in Ag-Cu-Ti Filler Alloy on Ti(C,N)-Based Cermet/45 Steel-Brazed Joints

Authors: Hu He, Xueming Du, Xiaokai Huang, Weijian Xu, Zhenhua Yao

Published in: Journal of Materials Engineering and Performance | Issue 5/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Reliable brazing of Ti(C,N)-based cermet and 45 steel was successfully achieved by using the Mo-particle-reinforced Ag-Cu-Ti composite filler. The effects of Mo content on the interfacial microstructure and mechanical properties of Ti(C,N)-based cermet/45 steel joints were analyzed. The results showed that the joint microstructure was primarily composed of Ni3Ti+Cu3Ti2, Ag(s,s)+Cu(s.s), CuTi+Mo, Ti-based solid solution, and FeTi+Fe2Ti. With the increase in Mo content in filler, the thickness of the Ni3Ti+Cu3Ti2 layer adjacent to the Ti(C,N)-based cermet decreases, while more blocky Ti-Cu intermetallic were observed in the brazing seam. The shear strength of the joint could be significantly improved by adding suitable amounts of Mo into the Ag-Cu-Ti filler, and the peak value of 263 MPa was achieved when the alloys were brazed with Ag-Cu-Ti+8wt.%Mo composite filler at 920 °C for 20 min.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference P. Ettmayer, H. Kolaska, W. Lengauer et al., Ti(C,N) Cermets—Metallurgy and Properties, Int. J. Refract. Metal Hard Mater., 1995, 13(6), p 343–351CrossRef P. Ettmayer, H. Kolaska, W. Lengauer et al., Ti(C,N) Cermets—Metallurgy and Properties, Int. J. Refract. Metal Hard Mater., 1995, 13(6), p 343–351CrossRef
2.
go back to reference L. Tang, J. Xiong, Z. Guo et al., Effect of WC/Mo 2 C Ratio on the Erosion Behavior of Ti(C,N)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2014, 45, p 102–108CrossRef L. Tang, J. Xiong, Z. Guo et al., Effect of WC/Mo 2 C Ratio on the Erosion Behavior of Ti(C,N)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2014, 45, p 102–108CrossRef
3.
go back to reference D. Ye, W. Xiong, X. Zhang et al., Microstructure and Shear Strength of the Brazed Joint of Ti(C,N)-Based Cermet to Steel, Rare Met., 2010, 29(1), p 72–77CrossRef D. Ye, W. Xiong, X. Zhang et al., Microstructure and Shear Strength of the Brazed Joint of Ti(C,N)-Based Cermet to Steel, Rare Met., 2010, 29(1), p 72–77CrossRef
4.
go back to reference H. Chen, K. Feng, J. Xiong, et al. Vacuum Brazing of Ti(C,N)-Based Cermets and 3Cr13 Stainless Steel. J. Sichuan Univ. (Eng. Sci. Ed.), 2012: S1 H. Chen, K. Feng, J. Xiong, et al. Vacuum Brazing of Ti(C,N)-Based Cermets and 3Cr13 Stainless Steel. J. Sichuan Univ. (Eng. Sci. Ed.), 2012: S1
5.
go back to reference M.W. Finnis, The Theory of Metal–Ceramic Interfaces, J. Phys. Condens. Matter, 1996, 8(32), p 5811CrossRef M.W. Finnis, The Theory of Metal–Ceramic Interfaces, J. Phys. Condens. Matter, 1996, 8(32), p 5811CrossRef
6.
go back to reference G.B. Niu, D.P. Wang, Z.W. Yang et al., Microstructure and Mechanical Properties of Al2O3 Ceramic and TiAl Alloy Joints Brazed with Ag-Cu-Ti Filler Metal, Ceram. Int., 2016, 42(6), p 6924–6934CrossRef G.B. Niu, D.P. Wang, Z.W. Yang et al., Microstructure and Mechanical Properties of Al2O3 Ceramic and TiAl Alloy Joints Brazed with Ag-Cu-Ti Filler Metal, Ceram. Int., 2016, 42(6), p 6924–6934CrossRef
7.
go back to reference J.C. Feng and L.X. Zhang, Interface Structure and Mechanical Properties of the Brazed Joint of TiC Cermet and Steel, J. Eur. Ceram. Soc., 2006, 26, p 1287CrossRef J.C. Feng and L.X. Zhang, Interface Structure and Mechanical Properties of the Brazed Joint of TiC Cermet and Steel, J. Eur. Ceram. Soc., 2006, 26, p 1287CrossRef
8.
go back to reference N. Wang, D.P. Wang, Z.W. Yang et al., Zirconia Ceramic and Nb Joints Brazed with Mo-Particle-Reinforced Ag-Cu-Ti Composite Fillers: Interfacial Microstructure and Formation Mechanism, Ceram. Int., 2017, 43, p 9636–9643CrossRef N. Wang, D.P. Wang, Z.W. Yang et al., Zirconia Ceramic and Nb Joints Brazed with Mo-Particle-Reinforced Ag-Cu-Ti Composite Fillers: Interfacial Microstructure and Formation Mechanism, Ceram. Int., 2017, 43, p 9636–9643CrossRef
9.
go back to reference D. Fan, J. Huang, Y. Wang et al., Active Brazing of Carbon Fiber Reinforced SiC Composite and 304 Stainless Steel with Ti-Zr-Be, Mater. Sci. Eng. A, 2014, 617, p 66–72CrossRef D. Fan, J. Huang, Y. Wang et al., Active Brazing of Carbon Fiber Reinforced SiC Composite and 304 Stainless Steel with Ti-Zr-Be, Mater. Sci. Eng. A, 2014, 617, p 66–72CrossRef
10.
go back to reference G.B. Lin, J.H. Huang, and H. Zhang, Joints of Carbon Fiber-Reinforced SiC Composites to Ti-Alloy Brazed by Ag-Cu-Ti Short Carbon Fibers, J. Mater. Process. Technol., 2007, 189, p 256–261CrossRef G.B. Lin, J.H. Huang, and H. Zhang, Joints of Carbon Fiber-Reinforced SiC Composites to Ti-Alloy Brazed by Ag-Cu-Ti Short Carbon Fibers, J. Mater. Process. Technol., 2007, 189, p 256–261CrossRef
11.
go back to reference Y.X. Zhao, M.R. Wang, J. Cao et al., Brazing TC4 Alloy to Si3N4 Ceramic Using Nano-Si3N4 Reinforced AgCu Composite Filler, Mater. Des., 2015, 76, p 40–46CrossRef Y.X. Zhao, M.R. Wang, J. Cao et al., Brazing TC4 Alloy to Si3N4 Ceramic Using Nano-Si3N4 Reinforced AgCu Composite Filler, Mater. Des., 2015, 76, p 40–46CrossRef
12.
go back to reference X.G. Song, J. Cao, Y.F. Wang et al., Effect of Si3N4-Particles Addition in Ag-Cu-Ti Filler Alloy on Si3N4/TiAl Brazed Joint, Mater. Sci. Eng. A, 2011, 528(15), p 5135–5140CrossRef X.G. Song, J. Cao, Y.F. Wang et al., Effect of Si3N4-Particles Addition in Ag-Cu-Ti Filler Alloy on Si3N4/TiAl Brazed Joint, Mater. Sci. Eng. A, 2011, 528(15), p 5135–5140CrossRef
13.
go back to reference Y. Qin, Z. Yu, Joining of C/C Composite to TC4 Using SiC Particle-Reinforced Brazing Alloy, Mater. Charact., 2010, 61(6), p 635–639.CrossRef Y. Qin, Z. Yu, Joining of C/C Composite to TC4 Using SiC Particle-Reinforced Brazing Alloy, Mater. Charact., 2010, 61(6), p 635–639.CrossRef
14.
go back to reference W. Ding, J. Xu, Z. Chen et al., A Study on Effects of TiB2 Contents on Reactive Products and Compressive Strength of Brazed CBN Grains, Surf. Interface Anal., 2009, 41(3), p 238–243CrossRef W. Ding, J. Xu, Z. Chen et al., A Study on Effects of TiB2 Contents on Reactive Products and Compressive Strength of Brazed CBN Grains, Surf. Interface Anal., 2009, 41(3), p 238–243CrossRef
15.
go back to reference W.F. Ding, J.H. Xu, Z.Z. Chen et al., Microstructure Characteristics of CBN/Steel Joints Brazed with TiB2 Modified Active Filler, Mater. Sci. Technol., 2009, 25(12), p 1448–1452CrossRef W.F. Ding, J.H. Xu, Z.Z. Chen et al., Microstructure Characteristics of CBN/Steel Joints Brazed with TiB2 Modified Active Filler, Mater. Sci. Technol., 2009, 25(12), p 1448–1452CrossRef
16.
go back to reference N. Wang, D.P. Wang, Z.W. Yang et al., Interfacial Microstructure and Mechanical Properties of Zirconia Ceramic and Niobium Joints Vacuum Brazed with Two Ag-Based Active Filler Metals, Ceram. Int., 2016, 42(11), p 12815–12824CrossRef N. Wang, D.P. Wang, Z.W. Yang et al., Interfacial Microstructure and Mechanical Properties of Zirconia Ceramic and Niobium Joints Vacuum Brazed with Two Ag-Based Active Filler Metals, Ceram. Int., 2016, 42(11), p 12815–12824CrossRef
17.
go back to reference Y. He, J. Zhang, Y. Sun et al., Microstructure and Mechanical Properties of the Si3N4/42CrMo Steel Joints Brazed with Ag-Cu-Ti + Mo Composite Filler, J. Eur. Ceram. Soc., 2010, 30(15), p 3245–3251CrossRef Y. He, J. Zhang, Y. Sun et al., Microstructure and Mechanical Properties of the Si3N4/42CrMo Steel Joints Brazed with Ag-Cu-Ti + Mo Composite Filler, J. Eur. Ceram. Soc., 2010, 30(15), p 3245–3251CrossRef
18.
go back to reference M. Naidoo, O. Johnson, I. Sigalas et al., Influence of Tantalum on the Microstructure and Properties of Ti(C,N)-Ni Cermets, Int. J. Refract. Metal Hard Mater., 2014, 42, p 97–102CrossRef M. Naidoo, O. Johnson, I. Sigalas et al., Influence of Tantalum on the Microstructure and Properties of Ti(C,N)-Ni Cermets, Int. J. Refract. Metal Hard Mater., 2014, 42, p 97–102CrossRef
19.
go back to reference Y. Zhang, Y. Zheng, J. Zhong et al., Effect of Carbon Content and Cooling Mode on the Microstructure and Properties of Ti(C,N)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2009, 27(6), p 1009–1013CrossRef Y. Zhang, Y. Zheng, J. Zhong et al., Effect of Carbon Content and Cooling Mode on the Microstructure and Properties of Ti(C,N)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2009, 27(6), p 1009–1013CrossRef
20.
go back to reference Y. Zheng, J. Zhong, X. Lv et al., Microstructure and Performance of Functionally Graded Ti(C,N)-Based Cermets Prepared by Double-Glow Plasma Carburization, Int. J. Refract. Metal Hard Mater., 2014, 44, p 109–112CrossRef Y. Zheng, J. Zhong, X. Lv et al., Microstructure and Performance of Functionally Graded Ti(C,N)-Based Cermets Prepared by Double-Glow Plasma Carburization, Int. J. Refract. Metal Hard Mater., 2014, 44, p 109–112CrossRef
21.
go back to reference B. Huang, W. Xiong, Q. Yang et al., Preparation, Microstructure and Mechanical Properties of Multicomponent Ni3Al-Bonded Cermets, Ceram. Int., 2014, 40(9), p 14073–14081CrossRef B. Huang, W. Xiong, Q. Yang et al., Preparation, Microstructure and Mechanical Properties of Multicomponent Ni3Al-Bonded Cermets, Ceram. Int., 2014, 40(9), p 14073–14081CrossRef
22.
go back to reference S.Y. Ahn and S. Kang, Formation of Core/Rim Structures in Ti(C,N)-WC-Ni Cermets via a Dissolution and Precipitation Process, J. Am. Ceram. Soc., 2000, 83(6), p 1489–1494CrossRef S.Y. Ahn and S. Kang, Formation of Core/Rim Structures in Ti(C,N)-WC-Ni Cermets via a Dissolution and Precipitation Process, J. Am. Ceram. Soc., 2000, 83(6), p 1489–1494CrossRef
23.
go back to reference L.X. Zhang, J.H. Yang, Z. Sun et al., Vacuum Brazing Nb and BN-SiO2 Ceramic Using a Composite Interlayer with Network Reinforcement Architecture, Ceram. Int., 2017, 43(11), p 8126–8132CrossRef L.X. Zhang, J.H. Yang, Z. Sun et al., Vacuum Brazing Nb and BN-SiO2 Ceramic Using a Composite Interlayer with Network Reinforcement Architecture, Ceram. Int., 2017, 43(11), p 8126–8132CrossRef
24.
go back to reference Q. Miao, W. Ding, Y. Zhu et al., Joining Interface and Compressive Strength of Brazed Cubic Boron Nitride Grains with Ag-Cu-Ti/TiX Composite Fillers, Ceram. Int., 2016, 42(12), p 13723–13737CrossRef Q. Miao, W. Ding, Y. Zhu et al., Joining Interface and Compressive Strength of Brazed Cubic Boron Nitride Grains with Ag-Cu-Ti/TiX Composite Fillers, Ceram. Int., 2016, 42(12), p 13723–13737CrossRef
25.
go back to reference Q. Miao, W. Ding, Y. Zhu et al., Brazing of CBN Grains with Ag-Cu-Ti/TiX Composite Filler—The Effect of TiX Particles on Microstructure and Strength of Bonding Layer, Mater. Des., 2016, 98, p 243–253CrossRef Q. Miao, W. Ding, Y. Zhu et al., Brazing of CBN Grains with Ag-Cu-Ti/TiX Composite Filler—The Effect of TiX Particles on Microstructure and Strength of Bonding Layer, Mater. Des., 2016, 98, p 243–253CrossRef
26.
go back to reference J.Y. Liu, T.P. Wang, C.F. Liu et al., Microstructure and Mechanical Properties of Porous Si3N4/Invar Joints Brazed with Ag-Cu-Ti+Mo/Cu/Ag-Cu Multi-layered Composite Filler, Ceram. Int., 2017, 33, p 98–103 J.Y. Liu, T.P. Wang, C.F. Liu et al., Microstructure and Mechanical Properties of Porous Si3N4/Invar Joints Brazed with Ag-Cu-Ti+Mo/Cu/Ag-Cu Multi-layered Composite Filler, Ceram. Int., 2017, 33, p 98–103
27.
go back to reference Y. Jing, Q. Yang, W. Xiong et al., Microstructure and Shear Strength of Brazed Joints Between Ti(C,N)-Based Cermet and Steel with CuAgTi Filler Metal, J. Alloys Compd., 2016, 682, p 525–530CrossRef Y. Jing, Q. Yang, W. Xiong et al., Microstructure and Shear Strength of Brazed Joints Between Ti(C,N)-Based Cermet and Steel with CuAgTi Filler Metal, J. Alloys Compd., 2016, 682, p 525–530CrossRef
28.
go back to reference J.L. Murray, The Cu−Ti (Copper-Titanium) System, J. Phase Equilib., 1983, 4(1), p 81–95 J.L. Murray, The Cu−Ti (Copper-Titanium) System, J. Phase Equilib., 1983, 4(1), p 81–95
29.
go back to reference P. Li, J. Ye, Y. Liu et al., Study on the Formation of Core–Rim Structure in Ti(CN)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2012, 35, p 27–31CrossRef P. Li, J. Ye, Y. Liu et al., Study on the Formation of Core–Rim Structure in Ti(CN)-Based Cermets, Int. J. Refract. Metal Hard Mater., 2012, 35, p 27–31CrossRef
30.
go back to reference K.P. Gupta, The Cu-Ni-Ti (Copper-Nickel-Titanium) System, Journal of Phase Equilibria and Diffusion, 2002, 23(6), p 541CrossRef K.P. Gupta, The Cu-Ni-Ti (Copper-Nickel-Titanium) System, Journal of Phase Equilibria and Diffusion, 2002, 23(6), p 541CrossRef
31.
go back to reference G.B. Niu, D.P. Wang, Z.W. Yang et al., Microstructure and Mechanical Properties of Al2O3/TiAl Joints Brazed with B Powders Reinforced Ag-Cu-Ti Based Composite Fillers, Ceram. Int., 2017, 43(1), p 439–450CrossRef G.B. Niu, D.P. Wang, Z.W. Yang et al., Microstructure and Mechanical Properties of Al2O3/TiAl Joints Brazed with B Powders Reinforced Ag-Cu-Ti Based Composite Fillers, Ceram. Int., 2017, 43(1), p 439–450CrossRef
32.
Metadata
Title
The Effect of Mo Particles Addition in Ag-Cu-Ti Filler Alloy on Ti(C,N)-Based Cermet/45 Steel-Brazed Joints
Authors
Hu He
Xueming Du
Xiaokai Huang
Weijian Xu
Zhenhua Yao
Publication date
11-04-2018
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 5/2018
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-018-3339-1

Other articles of this Issue 5/2018

Journal of Materials Engineering and Performance 5/2018 Go to the issue

Premium Partners