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Journal of Materials Engineering and Performance

Published in:

01-07-2012

The Estimation of Localized Corrosion Behavior of Ni-Based Dental Alloys Using Electrochemical Techniques

Authors: Daniel Mareci, Romeu Chelariu, Sorin Iacoban, Corneliu Munteanu, Georgiana Bolat, Daniel Sutiman

Published in: Journal of Materials Engineering and Performance | Issue 7/2012

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Abstract

The aim of this study is to investigate the electrochemical behavior of the five non-precious Ni-based dental casting alloys in acidified artificial saliva. For comparison, nickel was also investigated. In order to study the localized corrosion resistance, the cyclic potentiodynamic polarization (CCP) and electrochemical impedance spectroscopy were performed. Scanning electron microscopy (SEM) observations were made after the CCP tests. The Ni-Cr alloys with chromium (14-18%) contents were susceptible to localized corrosion. The Ni-Cr-Mo alloy with contents of chromium (≈13%) and molybdenum (9%) presents a dangerous breakdown, but have a zero corrosion potential so that the difference between them is around 650 mV. The Ni-Cr-Mo alloys with higher chromium (22-25%) and molybdenum (9-11%) contents had a much larger passive range in the polarization curve and were immune to pitting corrosion. Pitting resistance equivalent (PRE) of about ≈54 could provide the Ni-based alloy with a good pitting corrosion resistance.

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Title: The Estimation of Localized Corrosion Behavior of Ni-Based Dental Alloys Using Electrochemical Techniques
Authors: Daniel Mareci
Romeu Chelariu
Sorin Iacoban
Corneliu Munteanu
Georgiana Bolat
Daniel Sutiman
Publication date: 01-07-2012
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 7/2012
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-011-0014-1

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