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Polymer Science, Series D

Published in:

01-12-2022

The Influence of Association of Reagents on the Polycondensation of Epichlorhydrin and 1,3-Bis(dimethylamino)propanol-2 in Water

Authors: O. A. Kazantsev, K. V. Shirshin, D. S. Baruta, E. A. Bolshakova, M. V. Savinova, I. R. Arifullin

Published in: Polymer Science, Series D | Issue 4/2022

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Abstract

In the preparation of polyammonium resin by polycondensation of equimolar amounts of epichlorohydrin and 1,3-bis(dimethylamino)propanol-2 in aqueous solutions, a nonstandard concentration effect was revealed, which manifested itself in a sharp increase in the reduced reaction rate, equilibrium conversion, and achievable molecular weight of the polymer at initial concentrations of reagents close to 2.0 mmol/g (the concentration range of 0.5–3.5 mmol/g was studied). The data obtained can be used in the search for additional economical resources to improve the technical and economic indicators of organic synthesis processes.

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Title: The Influence of Association of Reagents on the Polycondensation of Epichlorhydrin and 1,3-Bis(dimethylamino)propanol-2 in Water
Authors: O. A. Kazantsev
K. V. Shirshin
D. S. Baruta
E. A. Bolshakova
M. V. Savinova
I. R. Arifullin
Publication date: 01-12-2022
Publisher: Pleiades Publishing
Published in: Polymer Science, Series D / Issue 4/2022
Print ISSN: 1995-4212
Electronic ISSN: 1995-4220
DOI: https://doi.org/10.1134/S1995421222040323

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