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Cellulose
Published in: Cellulose 3/2007

01-06-2007 | Original Paper

The role of mild TEMPO–NaBr–NaClO oxidation on the wet adhesion of regenerated cellulose membranes with polyvinylamine

Authors: John-Louis DiFlavio, Robert Pelton, Marc Leduc, Simon Champ, Manfred Essig, Tomas Frechen

Published in: Cellulose | Issue 3/2007

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Abstract

X-ray Photoelectron Spectroscopy (XPS) was used to characterize the functional groups present on regenerated cellulose films after mild oxidation with TEMPO–NaBr–NaClO and the results were correlated with the adhesion forces holding together two wet cellulose films laminated with a thin (i.e. less than 10 mg/m2) layer of polyvinylamine (PVAm). There was no correlation between adhesion and carboxyl content, whereas wet adhesion was proportional to the total content of aldehyde and hemiacetal groups on the cellulose. It is proposed that aldehyde groups react with neighboring cellulose chains to form hemiacetals which serve as crosslinks strengthening the cellulose surface. The hemiacetals can also be attacked by primary amines to give imine and aminal covalent linkages to the PVAm adhesive layer.
previous article Coupled acid and enzyme mediated production of microcrystalline cellulose from corn cob and cotton gin waste
next article Conversion of cellulose materials into nanostructured ceramics by biomineralization

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Metadata
Title
The role of mild TEMPO–NaBr–NaClO oxidation on the wet adhesion of regenerated cellulose membranes with polyvinylamine
Authors
John-Louis DiFlavio
Robert Pelton
Marc Leduc
Simon Champ
Manfred Essig
Tomas Frechen
Publication date
01-06-2007
Publisher
Kluwer Academic Publishers
Published in
Cellulose / Issue 3/2007
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-006-9104-x

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