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Published in: Rare Metals 6/2020

22-05-2020 | Highlight

Tracking dynamic evolution of catalytic active sites in photocatalytic CO2 reduction by in situ time-resolved spectroscopy

Authors: Guo-Zhu Chen, Ke-Jun Chen, Jun-Wei Fu, Min Liu

Published in: Rare Metals | Issue 6/2020

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Excerpt

In situ time-resolved spectroscopy is an effective method to monitor the catalysis reaction in real time and reveal the catalytic mechanistic pathway. The dynamic evolution of coordination and electronic structures of catalytic active sites during the CO2 reduction reaction is still a “black box,” impeding the design of high-efficiency catalysts. In a recent report published in J. Am. Chem. Soc., by multiple in situ time-resolved spectroscopy, Xiong and co-workers successfully detected the dynamic evolution and photoinduced charge transfer process of terpyridine nickel(II) complex catalysts in photocatalytic CO2 reduction reactions. …

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Metadata
Title
Tracking dynamic evolution of catalytic active sites in photocatalytic CO2 reduction by in situ time-resolved spectroscopy
Authors
Guo-Zhu Chen
Ke-Jun Chen
Jun-Wei Fu
Min Liu
Publication date
22-05-2020
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 6/2020
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01416-2

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