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Tracking dynamic evolution of catalytic active sites in photocatalytic CO₂ reduction by in situ time-resolved spectroscopy

verfasst von: Guo-Zhu Chen, Ke-Jun Chen, Jun-Wei Fu, Min Liu

Erschienen in: Rare Metals | Ausgabe 6/2020

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In situ time-resolved spectroscopy is an effective method to monitor the catalysis reaction in real time and reveal the catalytic mechanistic pathway. The dynamic evolution of coordination and electronic structures of catalytic active sites during the CO₂ reduction reaction is still a “black box,” impeding the design of high-efficiency catalysts. In a recent report published in J. Am. Chem. Soc., by multiple in situ time-resolved spectroscopy, Xiong and co-workers successfully detected the dynamic evolution and photoinduced charge transfer process of terpyridine nickel(II) complex catalysts in photocatalytic CO₂ reduction reactions. …

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[1]

Li H, Zeng Y, Huang T, Piao L, Yan Z, Liu M. Hierarchical TiO₂ nanospheres with dominant {001} facets: facile synthesis, growth mechanism, and photocatalytic activity. Chem A Eur J. 2012;18(24):7525.CrossRef

[2]

Liu M, Qiu X, Miyauchi M, Hashimoto K. Energy-level matching of Fe(III) ions grafted at surface and doped in bulk for efficient visible-light photocatalysts. J Am Chem Soc. 2013;135(27):10064.CrossRef

[3]

Liu M, Inde R, Nishikawa M, Qiu X, Atarashi D, Sakai E, Nosaka Y, Hashimoto K, Miyauchi M. Enhanced photoactivity with nanocluster-grafted titanium dioxide photocatalysts. ACS Nano. 2014;8(7):7229.CrossRef

[4]

Miyauchi M, Irie H, Liu M, Qiu X, Yu H, Sunada K, Hashimoto K. Visible-light-sensitive photocatalysts: nanocluster-grafted titanium dioxide for indoor environmental remediation. J Phys Chem Lett. 2016;7(1):75.CrossRef

[5]

Chong R, Su C, Wang Z, Chang Z, Zhang L, Li D. Enhanced photocatalytic reduction of CO₂ on Rutile TiO₂/MgAl layered double oxides with H₂O under ambient temperature. Catal Lett. 2020;150(4):1061.CrossRef

[6]

Hammad A, Anzai A, Zhu X, Yamamoto A, Ootsuki D, Yoshida T, El-Shazly A, Elkady M, Yoshida H. Photodeposition conditions of silver cocatalyst on titanium oxide photocatalyst directing product selectivity in photocatalytic reduction of carbon dioxide with water. Catal Lett. 2020;150(4):1081.CrossRef

[7]

Xia Y, Cheng B, Fan J, Yu J, Liu G. Near-infrared absorbing 2D/3D ZnIn₂S₄/N-doped graphene photocatalyst for highly efficient CO₂ capture and photocatalytic reduction. Sci China Mater. 2020;63(4):552.CrossRef

[8]

Zhang X, Ren G, Zhang C, Li R, Zhao Q, Fan C. Photocatalytic reduction of CO₂ to CO over 3D Bi₂MoO₆ microspheres: simple synthesis, high efficiency and selectivity reaction mechanism. Catal Lett. 2020. https://doi.org/10.1007/s10562.CrossRef

[9]

Gao C, Wang J, Xu H, Xiong Y. Coordination chemistry in the design of heterogeneous photocatalysts. Chem Soc Rev. 2017;46(10):2799.CrossRef

[10]

Li Y, Chan SH, Sun Q. Heterogeneous catalytic conversion of CO₂: a comprehensive theoretical review. Nanoscale. 2015;7(19):8663.CrossRef

[11]

Handoko AD, Steinmann SN, Seh ZW. Theory-guided materials design: two-dimensional MXenes in electro- and photocatalysis. Nanoscale Horizons. 2019;4(4):809.CrossRef

[12]

Xu S, Carter EA. Theoretical insights into heterogeneous (photo)electrochemical CO₂ reduction. Chem Rev. 2019;119(11):6631.CrossRef

[13]

Kim D, Resasco J, Yu Y, Asiri AM, Yang P. Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold-copper bimetallic nanoparticles. Nat Commun. 2014;5:4948.CrossRef

[14]

Kortlever R, Shen J, Schouten KJ, Calle-Vallejo F, Koper MT. Catalysts and reaction pathways for the electrochemical reduction of carbon dioxide. J Phys Chem Lett. 2015;6(20):4073.CrossRef

[15]

Luo W, Nie X, Janik MJ, Asthagiri A. Facet dependence of CO₂ reduction paths on Cu electrodes. ACS Catalysis. 2016;6(1):219.CrossRef

[16]

Hsiung TL, Wang HP, Wei YL. In situ XANES study of CuO/TiO₂ thin films during photodegradation of methylene blue. AIP Conference Proceedings. 2007;882:556.

[17]

Hu Y, Zhan F, Wang Q, Sun Y, Yu C, Zhao X, Wang H, Long R, Zhang G, Gao C, Zhang W, Jiang J, Tao Y, Xiong Y. Tracking mechanistic pathway of photocatalytic CO₂ reaction at ni sites using operando, time-resolved spectroscopy. J Am Chem Soc. 2020;142(12):5618.CrossRef

[18]

Moonshiram D, Gimbert-Suriñach C, Guda A, Picon A, Lehmann CS, Zhang X, Doumy G, March AM, Benet-Buchholz J, Soldatov A, Llobet A, Southworth SH. Tracking the structural and electronic configurations of a cobalt proton reduction catalyst in water. J Am Chem Soc. 2016;138(33):10586.CrossRef

Titel: Tracking dynamic evolution of catalytic active sites in photocatalytic CO2 reduction by in situ time-resolved spectroscopy
verfasst von: Guo-Zhu Chen
Ke-Jun Chen
Jun-Wei Fu
Min Liu
Publikationsdatum: 22.05.2020
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 6/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-020-01416-2

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