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Published in: Tribology Letters 2/2015

01-02-2015 | Original Paper

Tribological Behavior of Sandwich-Like Self-Assembled Films Containing Silver Nanoparticles: The Influence of Outer Molecular Structure and Chain Length

Authors: Guangbin Yang, Fengjie Jin, Laigui Yu, Pingyu Zhang

Published in: Tribology Letters | Issue 2/2015

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Abstract

Alkanethiols with different chain length, composition and structure were grafted onto the surface of 3-mercaptopropyl trimethoxy silane (MPTS)–Ag dual-layer film consisting of Ag outerlayer and MPTS underlayer, thereby generating self-assembled trilayer films with “sandwich” structure on Si substrate. As-prepared films were characterized by atomic force microscopy and X-ray photoelectron spectroscopy. Moreover, the tribological behavior of as-prepared films was evaluated with an atomic force microscope and a ball-on-plate tribometer as well. It was found that as-prepared MPTS–Ag–C12 (C12 refer to 12 carbon chain of alkyl mercaptan; the same hereafter) film possesses excellent friction-reducing and antiwear properties. Particularly, MPTS–Ag–C8F (C8F refers to perfluorooctanethiol) film with lower interfacial energy exhibits a longer antiwear life than MPTS–Ag–C8 film.

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Literature
1.
go back to reference Burton, Z., Bhushan, B.: Hydrophobicity, adhesion, and friction properties of nanopatterned polymers and scale dependence for micro- and nanoelectromechanical systems. Nano Lett. 5, 1607–1613 (2005)CrossRef Burton, Z., Bhushan, B.: Hydrophobicity, adhesion, and friction properties of nanopatterned polymers and scale dependence for micro- and nanoelectromechanical systems. Nano Lett. 5, 1607–1613 (2005)CrossRef
2.
go back to reference Bhushan, B., Palacio, M., Kinzig, B.: AFM-based nanotribological and electrical characterization of ultrathin wear-resistant ionic liquid films. J. Colloid Interface Sci. 317, 275–287 (2008)CrossRef Bhushan, B., Palacio, M., Kinzig, B.: AFM-based nanotribological and electrical characterization of ultrathin wear-resistant ionic liquid films. J. Colloid Interface Sci. 317, 275–287 (2008)CrossRef
3.
go back to reference Tao, Z., Bhushan, B.: Surface modification of AFM Si3N4 probes for adhesion/friction reduction and imaging improvement. J. Tribol. 128, 865–875 (2006)CrossRef Tao, Z., Bhushan, B.: Surface modification of AFM Si3N4 probes for adhesion/friction reduction and imaging improvement. J. Tribol. 128, 865–875 (2006)CrossRef
4.
go back to reference Chai, Z., Liu, Y., Lu, X., He, D.: Nanotribological behavior of ultra-thin Al2O3 films prepared by atomic layer deposition. Tribol. Lett. 55, 143–149 (2014)CrossRef Chai, Z., Liu, Y., Lu, X., He, D.: Nanotribological behavior of ultra-thin Al2O3 films prepared by atomic layer deposition. Tribol. Lett. 55, 143–149 (2014)CrossRef
5.
go back to reference Bhushan, B.: Modern tribology handbook, vol. 2, pp. 909–929. CRC Press, Boca Raton (2001) Bhushan, B.: Modern tribology handbook, vol. 2, pp. 909–929. CRC Press, Boca Raton (2001)
6.
go back to reference Ren, S.L., Yang, S.R., Wang, J.Q., Liu, W.M., Zhao, Y.P.: Preparation and tribological studies of stearic acid self-assembled monolayers on polymer-coated silicon surface. Chem. Mater. 16, 428–434 (2004)CrossRef Ren, S.L., Yang, S.R., Wang, J.Q., Liu, W.M., Zhao, Y.P.: Preparation and tribological studies of stearic acid self-assembled monolayers on polymer-coated silicon surface. Chem. Mater. 16, 428–434 (2004)CrossRef
7.
go back to reference Maboudian, R., Howe, R.T.: Critical review: adhesion in surface micromechanical structure. J. Vac. Sci. Technol., B 15, 1–20 (1997)CrossRef Maboudian, R., Howe, R.T.: Critical review: adhesion in surface micromechanical structure. J. Vac. Sci. Technol., B 15, 1–20 (1997)CrossRef
8.
go back to reference Houston, J.E., Kim, H.I.: Adhesion, friction, and mechanical properties of functionalized alkanethiol self-assembled monolayers. Acc. Chem. Res. 35, 547–553 (2002)CrossRef Houston, J.E., Kim, H.I.: Adhesion, friction, and mechanical properties of functionalized alkanethiol self-assembled monolayers. Acc. Chem. Res. 35, 547–553 (2002)CrossRef
9.
go back to reference Cheng, H., Hu, Y.: Influence of chain ordering on frictional properties of self-assembled monolayers (SAMs) in nano-lubrication. Adv. Colloid Interface Sci. 171–172, 53–65 (2012)CrossRef Cheng, H., Hu, Y.: Influence of chain ordering on frictional properties of self-assembled monolayers (SAMs) in nano-lubrication. Adv. Colloid Interface Sci. 171–172, 53–65 (2012)CrossRef
10.
go back to reference Ma, J.Q., Pang, C.J., Mo, Y.F., Bai, M.W.: Preparation and tribological properties of multiply-alkylated cyclopentane (MAC)–octadecyltrichlorosilane (OTS) double-layer film on silicon. Wear 263, 1000–1007 (2007)CrossRef Ma, J.Q., Pang, C.J., Mo, Y.F., Bai, M.W.: Preparation and tribological properties of multiply-alkylated cyclopentane (MAC)–octadecyltrichlorosilane (OTS) double-layer film on silicon. Wear 263, 1000–1007 (2007)CrossRef
11.
go back to reference Song, S., Zhou, J., Qu, M., Yang, S., Zhang, J.: Preparation and tribological behaviors of an amide-containing stratified self-assembled monolayers on silicon surface. Langmuir 24, 105–109 (2008)CrossRef Song, S., Zhou, J., Qu, M., Yang, S., Zhang, J.: Preparation and tribological behaviors of an amide-containing stratified self-assembled monolayers on silicon surface. Langmuir 24, 105–109 (2008)CrossRef
12.
go back to reference Ou, J., Wang, J., Liu, S., Zhou, J., Yang, S.: Self-assembly and tribological property of a novel 3-layer organic film on silicon wafer with polydopamine coating as the interlayer. J. Phys. Chem. C 113, 20429–20434 (2009)CrossRef Ou, J., Wang, J., Liu, S., Zhou, J., Yang, S.: Self-assembly and tribological property of a novel 3-layer organic film on silicon wafer with polydopamine coating as the interlayer. J. Phys. Chem. C 113, 20429–20434 (2009)CrossRef
13.
go back to reference Ou, J., Wang, J., Liu, S., Mu, B., Ren, J., Wang, H., Yang, S.: Tribology study of reduced graphene oxide sheets on silicon substrate synthesized via covalent assembly. Langmuir 26, 15830–15836 (2010)CrossRef Ou, J., Wang, J., Liu, S., Mu, B., Ren, J., Wang, H., Yang, S.: Tribology study of reduced graphene oxide sheets on silicon substrate synthesized via covalent assembly. Langmuir 26, 15830–15836 (2010)CrossRef
14.
go back to reference Ou, J., Wang, Y., Wang, J., Liu, S., Li, Z., Yang, S.: Self-assembly of octadecyltrichlorosilane on graphene oxide and the tribological performances of the resultant film. J. Phys. Chem. C 115, 10080–10086 (2011)CrossRef Ou, J., Wang, Y., Wang, J., Liu, S., Li, Z., Yang, S.: Self-assembly of octadecyltrichlorosilane on graphene oxide and the tribological performances of the resultant film. J. Phys. Chem. C 115, 10080–10086 (2011)CrossRef
15.
go back to reference Wang, Y., Pu, J., Xia, L., Ding, J., Yuan, N., Zhu, Y., Cheng, G.: Fabrication and tribological study of graphene oxide/multiply-alkylated cyclopentanes multilayer lubrication films on Si substrates. Tribol. Lett. 53, 207–214 (2014)CrossRef Wang, Y., Pu, J., Xia, L., Ding, J., Yuan, N., Zhu, Y., Cheng, G.: Fabrication and tribological study of graphene oxide/multiply-alkylated cyclopentanes multilayer lubrication films on Si substrates. Tribol. Lett. 53, 207–214 (2014)CrossRef
16.
go back to reference Guo, Y.B., Wang, D.G., Liu, S.H., Zhang, S.W.: Fabrication and tribological properties of polyelectrolyte multilayers containing in situ gold and silver nanoparticles. Coll. Surf. A 417, 1–9 (2013)CrossRef Guo, Y.B., Wang, D.G., Liu, S.H., Zhang, S.W.: Fabrication and tribological properties of polyelectrolyte multilayers containing in situ gold and silver nanoparticles. Coll. Surf. A 417, 1–9 (2013)CrossRef
17.
go back to reference Guo, Y.B., Wang, D.G., Liu, S.H.: Tribologica behavior of in situ Ag nanoparticels/polyelectrolyte composite molecular deposition films. Appl. Surf. Sci. 256, 1714–1719 (2010)CrossRef Guo, Y.B., Wang, D.G., Liu, S.H.: Tribologica behavior of in situ Ag nanoparticels/polyelectrolyte composite molecular deposition films. Appl. Surf. Sci. 256, 1714–1719 (2010)CrossRef
18.
go back to reference Zhang, S., Hu, L., Wang, H., Feng, D.: The anti-seizure effect of Ag nanoparticles additive in multialkylated cyclopentanes oil under vacuum condition. Tribol. Int. 55, 1–6 (2012)CrossRef Zhang, S., Hu, L., Wang, H., Feng, D.: The anti-seizure effect of Ag nanoparticles additive in multialkylated cyclopentanes oil under vacuum condition. Tribol. Int. 55, 1–6 (2012)CrossRef
19.
go back to reference Shi, X., Xu, Z., Wang, M., Zhai, W., Yao, J., Song, S., Din, A.Q., Zhang, Q.: Tribological behavior of TiAl matrix self-lubricating composites containing silver from 25 to 800°C. Wear 303, 486–494 (2013)CrossRef Shi, X., Xu, Z., Wang, M., Zhai, W., Yao, J., Song, S., Din, A.Q., Zhang, Q.: Tribological behavior of TiAl matrix self-lubricating composites containing silver from 25 to 800°C. Wear 303, 486–494 (2013)CrossRef
20.
go back to reference Yang, G., Zhang, C., Zhang, S., Yu, L., Zhang, P.: Preparation of sandwich-like self-assembled n-octanethiol film containing doped silver nanoparticles on silicon wafer and evaluation of its tribological properties. Mater. Res. Bull. 55, 88–94 (2014)CrossRef Yang, G., Zhang, C., Zhang, S., Yu, L., Zhang, P.: Preparation of sandwich-like self-assembled n-octanethiol film containing doped silver nanoparticles on silicon wafer and evaluation of its tribological properties. Mater. Res. Bull. 55, 88–94 (2014)CrossRef
21.
go back to reference Wang, Y., Biradar, A.V., Wang, G., Sharma, K.K., Duncan, C.T., Rangan, S., Asefa, T.: Controlled synthesis of water-dispersible faceted crystalline copper nanoparticles and their catalytic properties. Chem. Eur. J. 16, 10735–10743 (2010)CrossRef Wang, Y., Biradar, A.V., Wang, G., Sharma, K.K., Duncan, C.T., Rangan, S., Asefa, T.: Controlled synthesis of water-dispersible faceted crystalline copper nanoparticles and their catalytic properties. Chem. Eur. J. 16, 10735–10743 (2010)CrossRef
22.
go back to reference Hu, S.W., Yang, L.W., Tian, Y., Wei, X.L., Ding, J.W., Zhong, J.X., Chu, P.K.: Simultaneous nanostructure and heterojunction engineering of graphitic carbon nitride via in situ Ag doping for enhanced photoelectrochemical activity. Appl. Catal. B: Environ. 163, 611–622 (2015)CrossRef Hu, S.W., Yang, L.W., Tian, Y., Wei, X.L., Ding, J.W., Zhong, J.X., Chu, P.K.: Simultaneous nanostructure and heterojunction engineering of graphitic carbon nitride via in situ Ag doping for enhanced photoelectrochemical activity. Appl. Catal. B: Environ. 163, 611–622 (2015)CrossRef
23.
go back to reference Yang, G., Yu, L., Chen, X., Zhang, P.: Hydrophobic surfaces of spin-assisted layer-by-layer assembled polyelectrolyte multilayers doped with copper nanoparticles and modified by fluoroalkylsilane. Appl. Surf. Sci. 255, 4097–4101 (2009)CrossRef Yang, G., Yu, L., Chen, X., Zhang, P.: Hydrophobic surfaces of spin-assisted layer-by-layer assembled polyelectrolyte multilayers doped with copper nanoparticles and modified by fluoroalkylsilane. Appl. Surf. Sci. 255, 4097–4101 (2009)CrossRef
24.
go back to reference Ahn, H.S., Cuong, P.D., Park, S., Kim, Y.W., Lim, J.C.: Effect of molecular structure of self-assembled monolayers on their tribological behaviors in nano- and microscales. Wear 255, 819–825 (2003)CrossRef Ahn, H.S., Cuong, P.D., Park, S., Kim, Y.W., Lim, J.C.: Effect of molecular structure of self-assembled monolayers on their tribological behaviors in nano- and microscales. Wear 255, 819–825 (2003)CrossRef
25.
go back to reference Ou, J., Wang, Y., Li, C., Wang, F., Xue, M., Wang, J.: Tribological behaviors of a novel trilayer nanofilm: the influence of outer chain length and interlayer thickness. Surf. Interface Anal. 45, 1182–1187 (2013)CrossRef Ou, J., Wang, Y., Li, C., Wang, F., Xue, M., Wang, J.: Tribological behaviors of a novel trilayer nanofilm: the influence of outer chain length and interlayer thickness. Surf. Interface Anal. 45, 1182–1187 (2013)CrossRef
26.
go back to reference Hoque, E., DeRose, J.A., Bhushan, B., Hipps, K.W.: Low adhesion, non-wetting phosphonate self-assembled monolayer films formed on copper oxide surfaces. Ultramicroscopy 109, 1015–1022 (2009)CrossRef Hoque, E., DeRose, J.A., Bhushan, B., Hipps, K.W.: Low adhesion, non-wetting phosphonate self-assembled monolayer films formed on copper oxide surfaces. Ultramicroscopy 109, 1015–1022 (2009)CrossRef
27.
go back to reference Bhushan, B., Kasai, T., Kulik, G., Barbieri, L., Hoffmann, P.: AFM study of perfluoroalkylsilane and alkylsilane self-assembled monolayers for anti-stiction in MEMS/NEMS. Ultramicroscopy 105, 176–188 (2005)CrossRef Bhushan, B., Kasai, T., Kulik, G., Barbieri, L., Hoffmann, P.: AFM study of perfluoroalkylsilane and alkylsilane self-assembled monolayers for anti-stiction in MEMS/NEMS. Ultramicroscopy 105, 176–188 (2005)CrossRef
28.
go back to reference Chambers, R.D.: Fluorine in organic chemistry. Wiley, New York (1973) Chambers, R.D.: Fluorine in organic chemistry. Wiley, New York (1973)
29.
go back to reference Yang, G.B., Chen, X.H., Zhang, Z.M., Song, S.Y., Yu, L.G., Zhang, P.Y.: Adhesion and tribological property of Cu nanoparticles-doped hydrophobic polyelectrolyte multilayers. Lubr. Sci. 24, 313–323 (2012)CrossRef Yang, G.B., Chen, X.H., Zhang, Z.M., Song, S.Y., Yu, L.G., Zhang, P.Y.: Adhesion and tribological property of Cu nanoparticles-doped hydrophobic polyelectrolyte multilayers. Lubr. Sci. 24, 313–323 (2012)CrossRef
30.
go back to reference Álvarez-Asencio, R., Pan, J., Thormann, E., Rutland, M.W.: Tribological properties mapping: local variation in friction coefficient and adhesion. Tribol. Lett. 50, 387–395 (2013)CrossRef Álvarez-Asencio, R., Pan, J., Thormann, E., Rutland, M.W.: Tribological properties mapping: local variation in friction coefficient and adhesion. Tribol. Lett. 50, 387–395 (2013)CrossRef
31.
go back to reference Bhushan, B.: Handbook of micro/nano tribology, 2nd edn. CRC Press LLC, Boca Raton (1999) Bhushan, B.: Handbook of micro/nano tribology, 2nd edn. CRC Press LLC, Boca Raton (1999)
32.
go back to reference Song, Y., Xia, Y., Liu, H., Jia, Z.: Tribological properties of alkyl and hydroxyl groups on the imidazolium tetrafluoroborate ionic liquids. Lubr. Sci. 25, 413–427 (2013)CrossRef Song, Y., Xia, Y., Liu, H., Jia, Z.: Tribological properties of alkyl and hydroxyl groups on the imidazolium tetrafluoroborate ionic liquids. Lubr. Sci. 25, 413–427 (2013)CrossRef
33.
go back to reference Jahanmir, S.: Chain length effects in boundary lubrication. Wear 102, 331–349 (1985)CrossRef Jahanmir, S.: Chain length effects in boundary lubrication. Wear 102, 331–349 (1985)CrossRef
34.
go back to reference Song, S., Chu, R., Zhou, J., Yang, S., Zhang, J.: Formation and tribology study of amide-containing stratified self-assembled monolayers: influences of the underlayer structure. J. Phys. Chem. C 112, 3805–3810 (2008)CrossRef Song, S., Chu, R., Zhou, J., Yang, S., Zhang, J.: Formation and tribology study of amide-containing stratified self-assembled monolayers: influences of the underlayer structure. J. Phys. Chem. C 112, 3805–3810 (2008)CrossRef
35.
go back to reference Song, Y., Premachandran, N.R., Zou, M., Wang, Y.A.: Adhesion and friction properties of micro/nano-engineered superhydrophobic/hydrophobic surfaces. Thin Solid Films 518, 3801–3807 (2010)CrossRef Song, Y., Premachandran, N.R., Zou, M., Wang, Y.A.: Adhesion and friction properties of micro/nano-engineered superhydrophobic/hydrophobic surfaces. Thin Solid Films 518, 3801–3807 (2010)CrossRef
36.
go back to reference Liu, Y.H., Wang, X.K., Luo, J.B., Lu, X.C.: Fabrication and tribological properties of super-hydrophobic surfaces based on porous silicon. Appl. Surf. Sci. 255, 9430–9438 (2009)CrossRef Liu, Y.H., Wang, X.K., Luo, J.B., Lu, X.C.: Fabrication and tribological properties of super-hydrophobic surfaces based on porous silicon. Appl. Surf. Sci. 255, 9430–9438 (2009)CrossRef
Metadata
Title
Tribological Behavior of Sandwich-Like Self-Assembled Films Containing Silver Nanoparticles: The Influence of Outer Molecular Structure and Chain Length
Authors
Guangbin Yang
Fengjie Jin
Laigui Yu
Pingyu Zhang
Publication date
01-02-2015
Publisher
Springer US
Published in
Tribology Letters / Issue 2/2015
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-014-0459-0

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