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Colloid and Polymer Science
Published in: Colloid and Polymer Science 10/2023

04-07-2023 | Original Contribution

Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol

Authors: Ruiqi Han, Takumitsu Kida, Masayuki Yamaguchi

Published in: Colloid and Polymer Science | Issue 10/2023

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Abstract

Viscoelastic properties of copolycarbonate materials comprising isosorbide (ISB) and cyclohexanedimethanol (CHDM) were studied as a function of the ISB content. In the glassy state, β dispersion was clearly detected in the dynamic mechanical spectra. The tensile storage modulus E′ at room temperature increased with the ISB content, and the glass transition temperature Tg, i.e., peak temperature of α dispersion, increased with the ISB content. It was found from oscillatory shear modulus that the rubbery plateau modulus GN0 decreased with the ISB content. The entanglement molecular weights Me were found to be 2330–3640, which were slightly higher than that of bisphenol-A polycarbonate and much lower than those of poly(methyl methacrylate) and polystyrene. The onset shear stress of shark-skin failure at capillary extrusion was evaluated and found to increase with the ISB content.
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Metadata
Title
Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol
Authors
Ruiqi Han
Takumitsu Kida
Masayuki Yamaguchi
Publication date
04-07-2023
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 10/2023
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-023-05143-9

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