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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2023

04.07.2023 | Original Contribution

Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol

verfasst von: Ruiqi Han, Takumitsu Kida, Masayuki Yamaguchi

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2023

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Abstract

Viscoelastic properties of copolycarbonate materials comprising isosorbide (ISB) and cyclohexanedimethanol (CHDM) were studied as a function of the ISB content. In the glassy state, β dispersion was clearly detected in the dynamic mechanical spectra. The tensile storage modulus E′ at room temperature increased with the ISB content, and the glass transition temperature Tg, i.e., peak temperature of α dispersion, increased with the ISB content. It was found from oscillatory shear modulus that the rubbery plateau modulus GN0 decreased with the ISB content. The entanglement molecular weights Me were found to be 2330–3640, which were slightly higher than that of bisphenol-A polycarbonate and much lower than those of poly(methyl methacrylate) and polystyrene. The onset shear stress of shark-skin failure at capillary extrusion was evaluated and found to increase with the ISB content.
Vorheriger Artikel Mechanism and adsorptive performance of PANI/PTh copolymer as a novel and highly efficient adsorbent for the elimination of textile pollutants from aqueous solutions
Nächster Artikel Synthesis of the solar heat reflecting membrane by duplicating the Saharan silver ant micro-hair structure

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Metadaten
Titel
Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol
verfasst von
Ruiqi Han
Takumitsu Kida
Masayuki Yamaguchi
Publikationsdatum
04.07.2023
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2023
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-023-05143-9

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