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Journal of Materials Science

Published in:

01-09-2014

A lithium poly(pyromellitic acid borate) gel electrolyte membrane for lithium-ion batteries

Authors: Guodong Xu, Yubao Sun, Rupesh Rohan, Yunfeng Zhang, Weiwei Cai, Hansong Cheng

Published in: Journal of Materials Science | Issue 17/2014

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Abstract

Lithium poly(pyromellitic acid borate) (PPAB) was synthesized via polymerization of lithium tetramethanolatoborate and silylated pyromellitic acid. The synthesized material was characterized by Fourier transformation infrared spectroscopy, ¹¹B nuclear magnetic resonance, scanning electron microscopy, and thermogravimetric analysis. And electrochemical characterizations were carried out on the blended PPAB/PVDF-HFP membrane. The PPAB-based composite membrane exhibits high lithium ionic conductivity, a broad electrochemical window and a high lithium-ion transference number. The battery cells assembled with the PPAB/PVDF-HFP/EC:PC composite membrane as the electrolyte perform reasonably well not only at elevated temperature but also at room temperature with good cyclability and discharge capacity, making the material suitable for applications in lithium-ion batteries.

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Title: A lithium poly(pyromellitic acid borate) gel electrolyte membrane for lithium-ion batteries
Authors: Guodong Xu
Yubao Sun
Rupesh Rohan
Yunfeng Zhang
Weiwei Cai
Hansong Cheng
Publication date: 01-09-2014
Publisher: Springer US
Published in: Journal of Materials Science / Issue 17/2014
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-014-8341-x

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