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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 11/2017

08-02-2017

A novel orange-red emitting phosphor Sr3Lu(PO4)3:Sm3+ for near UV-pumped white light-emitting diodes

Authors: Jiangnan Du, Denghui Xu, Xuedong Gao, Zaifa Yang, Jiayue Sun

Published in: Journal of Materials Science: Materials in Electronics | Issue 11/2017

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Abstract

A series of Sr3Lu1 − x (PO4)3:xSm3+phosphors were synthesized via a conventional solid-state reaction method. The prepared phosphors were investigated using X-ray diffraction and Scanning electron microscopy. The excitation and emission spectra, concentration quenching mechanism, and fluorescence decays of the phosphors were also measured and discussed. Under 403 nm excitation, the 4G5/2 → 6HJ (J = 5/2, 7/2, 9/2, and 11/2) emissions of Sm3+ were obviously observed with peaks located at 564, 599, 646 and 705 nm, respectively. The optimum dopant concentration of Sm3+ ions in Sr3Lu(PO4)3 is 3 mol% and the corresponding Commission Internationale deL’Eclairage chromaticity coordinate of the Sr3Lu0.97(PO4)3:0.03Sm3+ phosphor was located in the orange reddish region. In addition, the temperature dependent luminescence and the absolute quantum efficiency of the typical sample was also investigated. The results confirmed that the as-synthesized Sr3Lu(PO4)3:Sm3+ phosphors can act as a suitable candidate of the warm components of near-ultraviolet white light-emitting diodes.
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Metadata
Title
A novel orange-red emitting phosphor Sr3Lu(PO4)3:Sm3+ for near UV-pumped white light-emitting diodes
Authors
Jiangnan Du
Denghui Xu
Xuedong Gao
Zaifa Yang
Jiayue Sun
Publication date
08-02-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 11/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6520-7

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