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04-01-2022 | Original Paper

Ag₃O₄ embedded fibre reinforced polyaniline nanocomposite as an electrode material for supercapacitors

Authors: Bela Purty, Ram Bilash Choudhary

Published in: Polymer Bulletin | Issue 11/2022

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Abstract

Synergetic impact of metal inorganic into conducting polymer is an efficient way to enhance the energy storage capacity and tailor surface property of the product. Therefore, a novel composite of Ag₃O₄/polyaniline has synthesized via a facile chemical oxidative polymerization method with varying concentration of inorganic filler. Mesoporous Ag₃O₄ nanoflakes decorated polyaniline fibres like architecture help to achieve better capacitance and electrical conductivity. A binder-free pure electrode material of Ag₃O₄/polyaniline was prepared and analyzed in a three-electrode cell system using 1 M H₂SO₄ electrolyte. Electrochemical measurements had performed to optimize the concentration of Ag₃O_4, with the increasing amount of Ag₃O₄ into PANI. Ag₃O₄ /polyaniline (AGP 2.0) nanocomposite led to highest gravimetric and volumetric capacitance of 1735 F g⁻¹ and 562.2 F cm⁻³ associated with 94% specific capacitance retention and 84% coulombic efficiency. The equivalent series resistance with 2.2 Ω provides good electrical conductivity. The mentioned outcomes suggest that Ag₃O₄/polyaniline nanocomposites can be used as a potential electrode material for supercapacitors.

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Title: Ag3O4 embedded fibre reinforced polyaniline nanocomposite as an electrode material for supercapacitors
Authors: Bela Purty
Ram Bilash Choudhary
Publication date: 04-01-2022
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 11/2022
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-021-03971-9

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